公开(公告)号：AU2731988A

公开(公告)日：1989-06-22

申请号：AU2731988

申请日：1988-12-20

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  ANTBERG MARTIN ,  ROHRMANN JURGEN

IPC: C08F4/642 ,  C08F4/42 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/00 ,  C08F110/06

Abstract: 1-olefin stereoblock polymer waxes having a very narrow molecular weight distribution are obtained by means of a catalyst which comprises an aluminoxane and a metallocene compound containing cyclopentadienyl radicals which are substituted by chiral groups, in the presence of small amounts of nitrogen during the polymerisation.

公开(公告)号：CA1338333C

公开(公告)日：1996-05-14

申请号：CA614531

申请日：1989-09-29

Applicant: HOECHST AG

Inventor： ANTBERG MARTIN ,  SPALECK WALTER ,  ROHRMANN JUERGEN ,  LUEKER HARTMUT ,  WINTER ANDREAS

IPC: C08F4/642 ,  C07F17/00 ,  C08F2/02 ,  C08F4/58 ,  C08F4/60 ,  C08F4/602 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16 ,  C08F210/06

Abstract: The invention relates to a process for the preparation of a predominantly crystalline ethylene/propylen copolymer having less than 15 mol% of propylene units, which can be carried out in liquid propylene as the suspending agent, if metallocene catalyst components of the formulae I, II or III are employed and the partial pressures of ethylene and propylene have a specific ratio. (I), (II), (III), By means of this process, it is possible to increase the possible uses of polymerization plants which work with liquid propylene.

公开(公告)号：AU666565B2

公开(公告)日：1996-02-15

申请号：AU4459193

申请日：1993-08-13

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  ANTBERG MARTIN ,  BACHMANN BERND ,  DOLLE VOLKER ,  KUBER FRANK ,  ROHRMANN JURGEN ,  SPALECK WALTER

IPC: C07F17/00 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F10/00 ,  C08F110/06 ,  C08F297/08 ,  C08F4/646 ,  C08F4/645 ,  C08F10/10

Abstract: A compound of formula (1) in either pure meso form or as a 1:99 meso:racemic mixture is claimed. In (1), M = a Group IVb, Vb or VIIb metal; R , R = H, 1-10C alkyl, 1-10C alkoxy, 5-10C aryl, 6-10C aryloxy, 2-10C alkenyl, 7-40C arylalkyl or alkylaryl, 8-40C aralkenyl or halogen; R , R = H, halogen, 1-10C alkyl, optionally halogenated , 6-10C aryl, optionally halogenated, -NR 2, -SR , -OSR 3, -SiR 3 or -PR 2; R , R = halogen, 1-10C alkyl, optionally halogenated , 6-10C aryl, optionally halogenated, -NR 02, -SR , -OSR 3, -SiR 3 or -PR 2 where two or more of R -R may form a ring system; R = halogen, 1-10C alkyl or 6-10C aryl; R = -M )(R )-, -M )(R )-M )(R )-, , -M 2)-, -O-M )(R )-O-, -C(R )(R )-, -O-M )(R )-, =BR , =AlR , -Ge-, Sn, O, S, =SO, =SO2, =NR , =CO, =PR or P(OR) ; R , R , R = H, halogen, 1-10C alkyl, 1-10C fluoroalkyl, 6-10C aryl, 6-10C fluoroaryl, 1-10C alkoxy, 2-10C alkenyl, 7-40C arylalkyl, 8-40C arylalkenyl, 7-40C alkylaryl where R and R or R and R together form a ring system. M = silicon, germanium or tin; m, n = 0, 1 or 2 m+n = 0, 1 or 2; and where meso-Dimethylsilylbil (1-(2-methyl-4-ethylindenyl)) zirconiumdichloride, meso-Dimethylsilylbil (1-(2-methyl-4-isopropylindenyl)) zirconium dichloride, meso-Dimethylsilylbil (1-(2-methyl-4-tert-butylindenyl)) zirconium dichloride, meso/meso/rac(1:1:2)-methylphenylsilylbis(1 -(2-methyl-4-isopropylindenyl)) zirconium dichloride, meso/rac(5:1)-dimethylsilylbis(1 -(2-ethyl-4-methylindenyl)) zirconium dichloride, meso/rac(1:1)-dimethylsilylbis(1 -(2,4-dimethylindenyl)) zirconium dichloride, meso/rac(1:3)-dimethylsilylbis(1 -(2-methyl-4,6-disopropylindenyl)) zirconium dichloride, meso/rac(1:2)-methylphenylsilylbis(1-(2-methyl-4,6-diisopropylindenyl)) zirconium dichloride, meso/rac-1,2-butandiylbis(1-(2-methy-4,6-diisopropylindenyl)) zirconium dichloride, meso/rac(1:2)-dimethylsilylbis(1 -(2-,4,6-trimethylindenyl)) zirconium dichloride, meso/rac(1:2)-1,2-ethandiylbis(1 -(2-methyl-4,6-diisopropylindenyl)) zirconium dichloride, meso/rac(1:1)-dimethylsilylbis(2 -methyl- alpha -acenaphthindenyl) zirconium dichloride, meso/rac-methylphenylsilylbis(1 -(2-methyl-4,5-benzoindenyl)) zirconium dichloride, meso/rac-methylphenylsilylbis(2 -methyl- alpha -acenaphthindenyl)) zirconium dichloride, rac-1,2-butandiylbis(1- (2-methyl-4,5-benzoindenyl)) zirconium dichloride, meso/rac (1:3)-dimethylsilylbis(1- (2-methyl-4,5-benzoindenyl)) zirconium dichloride, meso/rac (1:1)-dimethylsilylbis(1 -(2-methyl-4-phenylindenyl)) zirconium dichloride meso/rac (1:1)-dimethylsilylbis(1- (2-ethyl-4-phenylindenyl)) zirconium dichloride, meso/rac (1:1)-dimethylsilylbis(1- (2-methyl-4-(1-naphthyl)indenyl)) zirconium dichloride, meso/rac (1:1)-dimethylsilylbis(1- (2-methyl-4-(2-naphthyl)indenyl)) zirconium dichloride, and meso/rac(1:1)-ethandiylbis(1- (2-methyl-4-phenylindenyl)) zirconium dichloride are excluded.

公开(公告)号：AU647432B2

公开(公告)日：1994-03-24

申请号：AU6829890

申请日：1990-12-20

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  DOLLE VOLKER ,  ROHRMANN JURGEN ,  SPALECK WALTER ,  ANTBERG MARTIN

IPC: C08F4/42 ,  C08F4/60 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F8/00 ,  C08F210/06 ,  C08J5/00 ,  C08J5/18 ,  C08F210/02

公开(公告)号：AU641291B2

公开(公告)日：1993-09-16

申请号：AU8777791

申请日：1991-11-13

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  OSAN FRANK ,  ROHRMANN JURGEN ,  ANTBERG MARTIN

IPC: C08F4/642 ,  C08F4/60 ,  C08F4/6592 ,  C08F6/26 ,  C08F10/14 ,  C08F32/00 ,  C08F32/08 ,  C08F210/00 ,  C08F232/08 ,  C08F4/622

Abstract: Polymers of polycyclic olefins such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins are obtained without ring opening, in high space-time yield, with high cycloolefin incorporation rate and at industrially favourable polymerisation temperatures by a bulk polymerisation in which the catalyst used consists of an aluminoxane and of a stereorigid, chiral metallocene compound of an element of groups IVb to VIb, where the hydrocarbon radicals forming the sandwich structure are different.

公开(公告)号：ZA9207905B

公开(公告)日：1993-04-21

申请号：ZA9207905

申请日：1992-10-14

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  DOLLE VOLKER ,  SPALECK WALTER ,  ANTBERG MARTIN ,  ROHRMANN JUERGEN

IPC: C08F4/622 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

公开(公告)号：CA1315468C

公开(公告)日：1993-03-30

申请号：CA586514

申请日：1988-12-20

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  ANTBERG MARTIN ,  ROHRMANN JUERGEN

IPC: C08F4/622 ,  C08F2/38 ,  C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/04 ,  C08F10/14 ,  C08F110/06

Abstract: of the disclosure: 1-Olefin polymer wax, and a process for the preparation thereof 1-Olefin polymer waxes having a very narrow molecular weight distribution, high isotacticity, a narrow grain size distribution and a high bulk density are obtained by means of a catalyst comprising a chiral, stereorigid metallocene compound and an aluminoxane, in the presence of small amounts of hydrogen during the polymerization.

公开(公告)号：CA2076775A1

公开(公告)日：1993-02-27

申请号：CA2076775

申请日：1992-08-25

Applicant: HOECHST AG

Inventor： SPALECK WALTER ,  ROHRMANN JUERGEN ,  ANTBERG MARTIN

IPC: C07C13/465 ,  C07C1/24 ,  C07C13/28 ,  C07C45/28 ,  C07C45/46 ,  C07C49/67 ,  C07F7/00 ,  C07F17/00 ,  C08F2/06 ,  C08F4/60 ,  C08F4/602 ,  C08F4/625 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/76 ,  C08F4/82 ,  C08F10/00 ,  C08F110/06 ,  C08F2/00

Abstract: HOE 91/F 267 Process for the preparation of an olefin polymer A very effective catalyst system for olefin polymerization consists of a cocatalyst, preferably an aluminoxane, and a metallocene of the formula (I) (13 (I) in which, preferably, M1 is Zr, R1 and R2 are alkyl or halogen, R3 to R6 are alkyl, -(CR8R9)m-R7- -CR8R9)n- is a chain having one or more members, in which R7 can also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system leads to polymers of variable molecular weight and stereotacticity, depending on the substituents R3 to R6 chosen, at polymerization temperatures which are relevant in industry.

公开(公告)号：ZA921686B

公开(公告)日：1992-10-28

申请号：ZA921686

申请日：1992-03-06

Applicant: HOECHST AG

Inventor： MICHAEL-JOACHIM BREKNER ,  BREKNER MICHAEL-JOACHIM ,  ROHRMANN JUERGEN ,  JUERGEN ROHRMANN ,  OSAN FRANK ,  FRANK OSAN ,  ANTBERG MARTIN ,  MARTIN ANTBERG

IPC: C07F17/00 ,  C08F32/08 ,  C08F4/62 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/659 ,  C08F10/00 ,  C08F32/00 ,  C08F210/02 ,  C08F232/08 ,  C08F

Abstract: Metallocenes of formula (XI) are new, wherein M = Ti, Zr, Hf, V, Nb or Ta; R , R = H, halogen, 1-10 C alkyl, 1-10 C alkoxy, 6-10 C aryl, 6-10 C aryloxy, 2-10 C alkenyl, 7-40 C arylalkyl, 7-40 C alkylaryl or 8-40 C arylalkenyl; R , R = 9-fluorenyl and 1-(3-isopropyl)cyclopentadienyl, or 9-fluorenyl and 1-(3-t-butyl)cyclopentadienyl, forming a sandwich structure with M ; R = a one or more membered bridge, which connects R and R , pref. -(R )M )-, -(R )M )-(R )M )-, -(R )M )-CR2 -, -(R )C(R )-, -O-(R )M )-, -(R )C(R )-(R )C(R )-, =BR , =AlR , -Ge-, -Sn-, -O-, -S-, =SO, =SO2, =NR , =CO, =pr or =P(O)R ; R , R , R = independently H, halogen, 1-10 C alkyl, 1-10 C fluoroalkyl, 6-10 C aryl, 1-10 C alkoxy, 2-10 C alkenyl, 7-40 C arylalkyl, 8-40 C arylalkenyl or 7-40 C alkylaryl, or R and R or R and R form together a ring with bonded atoms; and isopropylene or diphenylmethylene; and M = Si, Ge or Sn. Catalysts comprising a linear type aluminoxane of formula (IX) and/or a cyclic type aluminoxane of formula (X), in addn. to (XI) are also claimed; R = 1-5 C alkyl, phenyl or benzyl; and n = 0-50.

公开(公告)号：ZA9200182B

公开(公告)日：1992-09-30

申请号：ZA9200182

申请日：1992-01-10

Applicant: HOECHST AG

Inventor： ANTBERG MARTIN ,  MARTIN ANTBERG ,  HERRMANN HANS-FRIEDRICH ,  HANS-FRIEDRICH HERRMANN ,  ROHRMANN JUERGEN ,  JUERGEN ROHRMANN

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F30/04 ,  C08F

CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/6092