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公开(公告)号：JPH05124928A
公开(公告)日：1993-05-21
申请号：JP29306791
申请日：1991-11-08
Applicant: KAO CORP
Inventor： IMAI KAZUYASU , KAJIWARA YASUSHI , KITA KATSUMI
IPC: A61K8/55 , A61K8/00 , A61K8/02 , A61K8/58 , A61K8/60 , A61K8/73 , A61Q5/00 , A61Q5/12 , A61Q19/10
Abstract: PURPOSE:To obtain a cosmetic having moisture-retention effect resistant to sweat, water washing, etc., free from stickiness to the skin and hair and giving moist feeling by compounding a specific phosphobetaine. CONSTITUTION:The objective cosmetic contains a phosphobetaine of formula I (Z is residue obtained by removing (m+n) x OH groups from monosaccharide, oligosaccharide, sugar alcohol or glycerol; R to R are alkyl, alkenyl or hydroxyalkyl; M and M are H or cation; (m) is >=0; (n) is >=1) [e.g. alpha-D- glucopyranose-1-[Z-hydroxy-3-(N,N-dimethyl-N-octadecylammonio) propyl]phosphate]. The phosphobetaine of formula I is preferably compounded in an amount of 0.5-10wt.% based on the cosmetic. The compound can be produced e.g. by reacting a phosphoric acid ester of formula 2 with an epoxy compound of formula 3. The cosmetic is especially suitable as a wash-off type rinse and body rinse.
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公开(公告)号：JPH0570358A
公开(公告)日：1993-03-23
申请号：JP23059891
申请日：1991-09-10
Applicant: KAO CORP
Inventor： KAYANE SHIGETO , KITA KATSUMI , NAKAI RYOZO , EGUCHI YASUTERU , FUJIKURA YOSHIAKI
Abstract: PURPOSE:To obtain a clinically extremely useful therapeutic agent for hyperesthesia of dentin, composed of a zinc-containing colloid and/or zinc salt of a polyol phosphate stable within a wide pH range and capable of exhibiting high safety. CONSTITUTION:A therapeutic agent for hyperesthesia of dentin containing (A) a colloid of zinc hydroxide and/or zinc oxide obtained by mixing a water-soluble zinc salt (zinc chloride, zinc sulfate and zinc nitrate are especially preferred) with a polyol phosphate (glucose-1-phosphate, glucose-6-phosphate, mannose-6-phosphate, galactose-6-phosphate, etc., are especially preferred) and/or its salt in an aqueous medium (pH 4-10 is especially preferred) and (B) zinc salt of the polyol phosphate [the polyol phosphate is the same as those exemplified in the ingredient (A)]. Only the ingredient (A) or (B) or both may be used in the therapeutic agent. Since the therapeutic agent is low irritant and excellent in safety, the agent can be used within a wide range of products or medicines for the oral cavity. The manifestation of hyperesthetic symptoms is effectively prevented by always using the therapeutic agent.
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公开(公告)号：JPH04103595A
公开(公告)日：1992-04-06
申请号：JP21904690
申请日：1990-08-22
Applicant: KAO CORP
Inventor： KAMIYA HIROSHI , KITA KATSUMI , FUJIKURA YOSHIAKI
Abstract: NEW MATERIAL:Compound of formula G-(A)n [G is (substituted) 5-6C reducing sugar, condensate thereof or residue obtained when n X hydroxyl groups are removed from saccharide selected from (substituted) oligosaccharide constituting 5-6C reducing sugar; A is group to be bonded to C atom to which n X eliminated hydroxyl groups were bonded in G and represented by formulae I-IV (R is 5-23C branched chain alkyl or branched chain alkenyl); n is from/to the number of hydroxyl groups in saccharide.]. EXAMPLE:3-0-(2-Heptylundecanoyl)-1-0-glucosylglycerol. USE:A base material for hair care or skin care cosmetics, a humectant, a detergent, an emulsifier, etc. PREPARATION:A compound of formula G-(B)n [B is group to be bonded to C atom to which n X eliminated hydroxyl groups were bonded in G and represented by formulae VI-VIII (X is halogen), etc.] is allowed to react with a compound of formula RCOOM (M is H or cation).
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公开(公告)号：JPH0477493A
公开(公告)日：1992-03-11
申请号：JP19134090
申请日：1990-07-19
Applicant: KAO CORP
Inventor： UENO ASAKO , KITA KATSUMI , FUJIKURA YOSHIAKI
IPC: C07H15/04
Abstract: NEW MATERIAL:A compound expressed by the formula [Z is residue obtained by excluding n x OH from monosaccharide, oligo sugar and sugar alcohol which may have a substituent group; formula II is a group capable of binding to carbon to which OH excluded in Z is bound; A is formula III to V (R is 1-4C hydroxyalkyl or hydroxyalkenyl; R and R are 1-4C alkyl, alkenyl, hydroxyalkyl or hydroxyalkenyl; X is halogen); (n) is 1-5]. EXAMPLE:3-[N-(2-Hydroxyethyl)-N,N-dimethylammonium chloride]-2- hydroxypropyl-D-glucopyranoside. USE:A base and humectant for hair cosmetic, skin cosmetic, etc. PREPARATION:A compound expressed by the formula Z(OCH2L)n [L is formula VI (X is halogen), etc.] is allowed to react with an amine compound expressed by the formula R NH2, formula R (R )NH or formula VI.
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公开(公告)号：JPH0454192A
公开(公告)日：1992-02-21
申请号：JP16324190
申请日：1990-06-21
Applicant: KAO CORP
Inventor： KAMIYA HIROSHI , KITA KATSUMI , FUJIKURA YOSHIAKI
Abstract: NEW MATERIAL:The sugar derivative of formula I [Y is residue produced by removing n hydroxyl groups from fructofuranose, fructopyranose or glucopyranose (excluding the hydroxyl bonded to alpha-carbon atom of ether bond); K is group of formula II (R is alkyl or alkenyl), formula III, formula IV or formula V bonding to Y through a carbon atom to which the hydroxyl group removed from the fructofuranose, fructopyranose or glucopyranose is bonded; n is 1-4]. EXAMPLE:Mono-(decylglyceryl-etherified)sugar. USE:Surfactant, detergent, emulsifier, dispersing agent, humidifier, solubilizing agent, etc. PREPARATION:The compound of formula I can be produced by hydrolyzing a compound of formula VI (Z is residue produced by removing m hydroxyl groups from sucrose; m is 1-8) in the presence of an acid catalyst.
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Patent Agency Ranking
公开(公告)号：JPH02306988A
公开(公告)日：1990-12-20
申请号：JP12617189
申请日：1989-05-19
Applicant: KAO CORP
Inventor： KAMIYA HIROSHI , KITA KATSUMI , HORINISHI NOBUTAKA , KUROSAKI TOMIHIRO
Abstract: NEW MATERIAL:A compound shown by the formula (R is 8-24C alkyl, alkenyl, hydroxyalkyl or hydroxyalkenyl). EXAMPLE:Octylfructoside. USE:Washing agent, emulsifying agent, dispersant, wetting agent and solubilizing agent for toiletry and cosmetic. PREPARATION:Sucrose is reacted with 8-24C alcohol or diol.
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公开(公告)号：JPH02242692A
公开(公告)日：1990-09-27
申请号：JP6449789
申请日：1989-03-16
Applicant: KAO CORP
Inventor： KITA KATSUMI , KAYANE SHIGETO , UENO ASAKO , KUROSAKI TOMIHIRO
Abstract: PURPOSE:To facilitate enzymatic reaction between a liposoluble alcohol and a saccharide and to efficiently produce a glycoside by subjecting the liposoluble alcohol and the saccharide to enzymatic reaction using an amphipathic compound to both the substances. CONSTITUTION:A solvent which is an amphipathic solvent to bath a liposoluble alcohol and a saccharide is blended with 0.01-20wt.%, preferably 0.5-5wt.% (based on the solvent) of the liposoluble alcohol and the saccharide, which are subjected to enzymatic reaction to give a glycoside. Monoethylene glycol, diethylene glycol or polyethylene glycol may be cited as the concrete example of the solvent. Methanol, ethanol, propanol, butanol, pentanol, etc., may be cited as the concrete example of the alcohol. A preferable example of the enzyme used in the enzymatic reaction is alpha-amylase, beta-amylase or glucoamylase.
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公开(公告)号：JPH02231092A
公开(公告)日：1990-09-13
申请号：JP4963889
申请日：1989-03-01
Applicant: KAO CORP
Inventor： KITA KATSUMI , FURUGAKI HISAKAZU , KAYANE SHIGETO , KUROSAKI TOMIHIRO
Abstract: PURPOSE:To obtain the subject compound useful as a cosmetic base, etc., on an industrial scale at a low cost by reacting a glucose-1-phosphate with maltodextrin in the presence of phosphorylase immobilized to a synthetic polymer anion-exchange resin. CONSTITUTION:The objective compound (e.g. alpha-1,4-glucan) is produced by dissolving (A) glucose-1-phosphate or its salt (e.g. dipotassium glucose-1-phosphate) and (B) a maltodextrin (e.g. maltopentaose) in ion-exchanged water, adjusting the pH of the solution to 6.5 with dilute hydrochloric acid, adding a synthetic polymer anion-exchange resin (e.g. strongly basic anion exchange resin composed of polystyrene containing trimethylammonium group) and reacting the components under shaking at 40 deg.C for 3hr.
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公开(公告)号：JPH02207053A
公开(公告)日：1990-08-16
申请号：JP2608589
申请日：1989-02-03
Applicant: KAO CORP
Inventor： UNO TETSUO , KITA KATSUMI
Abstract: PURPOSE:To purify a trimethylol compound difficult to purify by distillation because of its high boiling point or by crystallization, by adding boric acid to a crude trimethylol compound, dissolving the reaction product in an organic solvent then isolating and hydrolyzing the salt with a base. CONSTITUTION:Boric acid is added to a trimethylol compound which is represented by the formula (R is 5-28C alkyl or alkenyl) and contains impurity to effect the reaction at room temperature to 100 deg.C. Then, the reaction product is dissolved in an organic solvent such as ethanol and an alkali metal or alkaline earth metal hydroxide such as sodium hydroxide to isolate the insoluble salt. The salt is hydrolyzed with an aqueous mineral acid or hot water to give purified trimethylol compound. The trimethylol compounds are useful as a starting substance for cosmetics, surfactants, alkyd resins, polyurethanes or polyester as well as a starting substance for a variety of esters.
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公开(公告)号：JPH01283235A
公开(公告)日：1989-11-14
申请号：JP11331288
申请日：1988-05-10
Applicant: KAO CORP
Inventor： KITA KATSUMI , UNO TETSUO , MASUDA SHINICHI , YAHAGI KAZUYUKI
Abstract: NEW MATERIAL:A trimethylolmethyl branched alkane expressed by formula I (m and n are integers of 0-19 and m + n is 7-19). EXAMPLE:Trimethylolisoheptadecane. USE:A base for hair and skin cosmetics, emulsifying agent and lubricant. PREPARATION:For example, an aldehyde expressed by formula II (R is formula III) is reacted with formaldehyde in the presence of a base in a suitable solvent to afford the aimed compound expressed by formula I.
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