PROCEDE DE PREPARATION D'UN DIESTER PHOSPHORIQUE ET DIESTER AINSI OBTENU

    公开(公告)号:FR2579209B1

    公开(公告)日:1989-04-14

    申请号:FR8604000

    申请日:1986-03-20

    Applicant: KAO CORP KAO CORP

    Abstract: PROCEDE DE PREPARATION D'UN DIESTER PHOSPHORIQUE DE FORMULE (III): (CF DESSIN DANS BOPI) DANS LAQUELLE R SIGNIFIE UN GROUPE ORGANIQUE, R, R, R ET R REPRESENTENT, INDIVIDUELLEMENT, UN ATOME D'HYDROGENE OU UN GROUPE ORGANIQUE, R, R PEUVENT FACULTATIVEMENT ETRE COUPLES L'UN A L'AUTRE POUR FORMER UN NOYAU, ET M REPRESENTE UN ATOME D'HYDROGENE, UN METAL ALCALIN OU ALCALINO-TERREUX, UN GROUPE AMMONIUM OU UN SEL D'ALKYLAMINE OU D'ALCANOLAMINE, QUI CONSISTE DANS LA REACTION D'UN SEL MONOALCALIN D'UN MONOESTER ORGANOPHOSPHORIQUE, DE FORMULE I: (CF DESSIN DANS BOPI) FORMULE DANS LAQUELLE R A LA MEME SIGNIFICATION QUE CI-DESSUS ET M REPRESENTE UN METAL ALCALIN, AVEC UN COMPOSE EPOXY DE FORMULE II: (CF DESSIN DANS BOPI) DANS LAQUELLE R, R, R ET R ONT LES MEMES SIGNIFICATIONS QUE CI-DESSUS, REACTION QUI EST, SI NECESSAIRE, SUIVIE D'UNE ACIDIFICATION PUIS EVENTUELLEMENT D'UNE NEUTRALISATION AVEC DE L'AMMONIAQUE, UNE BASE ALCALINO-TERREUSE, UNE ALKYLAMINE OU UNE ALCANOLAMINE.

    4.
    发明专利
    未知

    公开(公告)号:ES2056861T3

    公开(公告)日:1994-10-16

    申请号:ES88114155

    申请日:1988-08-30

    Applicant: KAO CORP

    Abstract: A process for preparing glucose-1-phosphate from an alpha -glucan and orthophosphate using a phosphorylase immobilized onto an anion-exchange resin is disclosed. The anion-exchange resin used is a synthetic polymer resin into which an anion exchange group; a primary to quarternary ammonium group, a phosphonium group, or a sulfonium group, is introduced. This type of immobilized phosphorylase ensures (i) an effective utilization of phosphorylase, (ii) a higher reactivity of a higher absorbance of the phosphorylase to the resin, (iii) an excellent phosphorylase activity retention performance, and (iv) a higher physical strength of the resin.

    5.
    发明专利
    未知

    公开(公告)号:DE3518636C2

    公开(公告)日:1994-09-15

    申请号:DE3518636

    申请日:1985-05-23

    Applicant: KAO CORP

    Abstract: Metal salts of monoalkyl phosphates of the following formula (I) in which each R represents a saturated or unsaturated, linear or branched hydrocarbon group having from 8 to 32 carbon atoms, and M represents an alkaline earth metal or divalent transition metal. The metal salts are particularly suitable as cosmetic powders, fillers for resins, and lubricants, parting agents and pigment dispersants for polymeric compounds. When used as cosmetic powders, the metal salts improve spreadability, moistness, smoothness, adherence, transparency and covering power of cosmetics. Preparation process of the metal salts is also disclosed.

    6.
    发明专利
    未知

    公开(公告)号:DE3885771D1

    公开(公告)日:1994-01-05

    申请号:DE3885771

    申请日:1988-02-19

    Applicant: KAO CORP

    Abstract: A detergent composition contains as an essential component a compound represented by the following general formula (I): wherein R means R (OR )m- or R (OCH2)n @@-CH2-. R denotes a straight-chain or branched alkyl or alkenyl group or a substituted phenyl group. R is an alkylene group having 2 - 3 carbon atoms, m is 0 - 30, and n stands for 0 or 1. M means a hydrogen atom or denotes an alkali metal, alkaline earth metal, zinc or aluminum atom, an ammonium ion, or an alkylamine or alkanolamine residuum thereby to indicate the formation of a salt of the compound of the general formula (I).

    7.
    发明专利
    未知

    公开(公告)号:DK166679B1

    公开(公告)日:1993-06-28

    申请号:DK84287

    申请日:1987-02-19

    Applicant: KAO CORP

    Abstract: A novel method for purifying a sugar phosphate or its salt, in which a sugar-containing mixture of a sugar phosphate or its salt and phosphoric acid or its salt is subjected to electrodialysis to remove the phosphoric acid or its salt from the mixture.According to this method, the phosphoric acid or its salt can be readily obtained in a reusable form. The method is thus quite advantageous in view of the economy.

    8.
    发明专利
    未知

    公开(公告)号:DE3781816D1

    公开(公告)日:1992-10-29

    申请号:DE3781816

    申请日:1987-02-16

    Applicant: KAO CORP

    Abstract: A novel method for purifying a sugar phosphate or its salt, in which a sugar-containing mixture of a sugar phosphate or its salt and phosphoric acid or its salt is subjected to electrodialysis to remove the phosphoric acid or its salt from the mixture.According to this method, the phosphoric acid or its salt can be readily obtained in a reusable form. The method is thus quite advantageous in view of the economy.

    PHOSPHORIC ESTERS AND PROCESS FOR PREPARING SAME

    公开(公告)号:GB2179660B

    公开(公告)日:1988-12-14

    申请号:GB8618493

    申请日:1986-07-29

    Applicant: KAO CORP

    Abstract: Novel phosphoric esters of the general formula (I) in which X represents a halogen, R1 represents a linear or branched alkyl, fluoroalkyl or alkenyl group having from 1 to 36 carbon atoms, or a phenyl group substituted with a linear or branched alkyl group having from 1 to 15 carbon atoms, R2 represents an alkylene group having 2 or 3 carbon atoms, n is a value of from 0 to 30, and M represents a hydrogen atom, alkali metal, alkaline earth metal, ammonium, or an alkylamine or alkanolamine salt are prepared by reacting a salt of a phosphoric monoester of the general formula (II) (II) in which R1, R2 and n have, respectively, the same meanings as defined above, and M1 represents an alkali metal, with an epihalohydrin of the general formula (III) (III) in which X has the same meaning as defined above, and optionally, converting the resulting product into a free acid or a different salt. The phosphoric esters are reacted with a trialkylamine to readily obtain phospholipid simulants having a quaternary ammonium salt in a molecule thereof. When an alkali is acted on the phosphoric esters, the dehydrohalogenation reaction takes place and the esters are converted into a phosphoric ester having a polymerizable group.

    UN PROCEDIMIENTO PARA LA PRODUCCION DE UNA SAL DE ESTER FOSFORICO DE GRAN PUREZA

    公开(公告)号:ES2001726A6

    公开(公告)日:1988-06-01

    申请号:ES8603311

    申请日:1986-12-05

    Applicant: KAO CORP

    Abstract: SE PRODUCE UNA SAL DE UN ESTER FOSFORICO DE GRAN PUREZA CONVIRTIENDO UN ESTER FOSFORICO, EN UNA MEZCLA QUE CONTIENE EL ESTER FOSFORICO Y UNO O MAS COMPUESTOS ANIONICOS, EN UNA SAL DE ESTER FOSFORICO EMPLEANDO UN COMPUESTO BASICO Y EXTRAYENDO LOS COMPUESTOS NO IONICOS DE LA MEZCLA ANTERIOR EMPLEANDO UNA MEZCLA DISOLVENTE DE HIDROCARBUROS ALIFATICOS O HIDROCARBUROS CICLOALIFATICOS, UN ALCANOL INFERIOR Y AGUA. EL METODO ANTERIOR ES APLICABLE A UN ESTER FOSFORICO NO CRISTALINO DEL QUE NO PUEDEN SEPARARSE POR RECRISTALIZACION COMPUESTOS NO IONICOS. LA SAL DE ESTER FOSFORICO DE GRAN PUREZA ASI OBTENIDA PUEDE SER UTILIZADA TAL COMO ES O DESPUES DE SOMETERLA A CONDENSACION.

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