公开(公告)号：JP2002356598A

公开(公告)日：2002-12-13

申请号：JP2002095242

申请日：2002-03-29

Applicant: TORAY INDUSTRIES

Inventor： MATSUMOTO HIDEKI ,  KOYAMA MASAFUMI ,  YAMANAKA TORU ,  TANAKA AKIKO

IPC: C08J5/00 ,  C08F8/48 ,  C08L33/02 ,  C08L33/04 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition having excellent mechanical performances, small anisotropy of the molding, and among others, excellent thermal resistance and retention stability. SOLUTION: This thermoplastic resin composition comprises (A) 1 to 99 pts.wt. of a crystalline thermoplastic resin, and (B) 99 to 1 pts.wt. of a copolymer comprising (i) an unsaturated carboxylic acid alkyl ester unit, (ii) a glutaric acid anhydride unit expressed by formula (1) (where R and R are the same or different and each represents hydrogen atom or a 1-5C alkyl group), or a copolymer having (iii) an unsaturated carboxylic acid unit in addition to the above units, or a copolymer having (iv) another vinylic monomer unit in addition to the above (i) (ii) or (i) (ii) (iii) units.

公开(公告)号：JP2002105330A

公开(公告)日：2002-04-10

申请号：JP2000301524

申请日：2000-09-29

Applicant: TORAY INDUSTRIES

Inventor： HIDAKA SHINSUKE ,  KATO KIMIYA ,  YAMANAKA TORU

IPC: C08J5/18 ,  C08K3/08 ,  C08L67/02 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To obtain a semi-crystalline thermoplastic resin-metal cluster composite composition film which has improved elastic modulus and excellent toughness. SOLUTION: This semi-crystalline thermoplastic resin-metal cluster composite composition film comprising (A) a semi-crystalline thermoplastic resin and (B) a metal cluster, characterized in that (B) the metal cluster is heterogeneously finely dispersed in the semi-crystalline thermoplastic resin-metal cluster composite composition film.

公开(公告)号：JP2001329166A

公开(公告)日：2001-11-27

申请号：JP2000153880

申请日：2000-05-24

Applicant: TORAY INDUSTRIES

Inventor： NISHIMURA TORU ,  SAITO MAKIKO ,  YAMANAKA TORU

IPC: C08J5/00 ,  C08K3/34 ,  C08K5/00 ,  C08K7/02 ,  C08K9/04 ,  C08L77/00

Abstract: PROBLEM TO BE SOLVED: To provide a molded article of a polyamide resin reinforced with a fiber filler, having excellent specific rigidity and exhibiting higher rigidity by the addition of a small amount of the reinforcing material. SOLUTION: This molded article is produced by the melt-molding of a resin composition composed of (A) 100 pts.wt. of a polycapramide or a copolymerized polyamide containing a capramide component as a main component, (B) 0.1-15 pts.wt. of a swelling lamellar silicate and (C) 10-150 pts.wt. of a fibrous reinforcing material. The ratio of α-crystal in the crystal of the polyamide component in the molded article is >=50%.

公开(公告)号：JP2001261947A

公开(公告)日：2001-09-26

申请号：JP2000071329

申请日：2000-03-14

Applicant: TORAY INDUSTRIES

Inventor： HIDAKA SHINSUKE ,  KATO KIMIYA ,  YAMANAKA TORU

IPC: C08J3/20 ,  C08K3/34 ,  C08K7/00 ,  C08K9/04 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To obtain a polyester resin composition excellent in durability and dimensional stability at high temperatures and in high humidity by melting and kneading a polyester resin with a layered silicate. SOLUTION: This polyester resin composition is obtained by melting and kneading (A) the polyester resin and (B) the layered silicate regulated so that the layered silicate (B) may homogeneously dispersed in the polyester resin composition so as to form the level of 5-20 layers.

公开(公告)号：JP2000212420A

公开(公告)日：2000-08-02

申请号：JP32753699

申请日：1999-11-17

Applicant: TORAY INDUSTRIES

Inventor： OOME HIROKAZU ,  NISHIMURA TORU ,  YAMANAKA TORU

IPC: C08L67/02 ,  C08K3/24 ,  C08K9/04

Abstract: PROBLEM TO BE SOLVED: To obtain a composition good in mechanical characteristics and electrical characteristics and excellent in flame retardancy by incorporating a phyllosilicate salt having exchangeable cations existing between layers replaced by organic onium ions and an organic brominated oligomer or polymer each in a specific amount into a thermoplastic polyester resin. SOLUTION: Into 100 pts.wt. of a thermoplastic polyester resin (A) are incorporated 0.1-40 pts.wt. of a phyllosilicate salt (B) having exchangeable cations existing between layers replaced by organic onium ions and 2-60 pts.wt. of an organic brominated oligomer or polymer (C). Preferably, at least 70% of the component B is uniformly dispersed in the phase A and the component B is previously dispersed in the component A before the component C is added. Further are added 0.2-30 pts.wt. of an auxiliary flame retardant, 2-100 pts.wt. of a fibrous inorganic filler, 0.1-10 pts.wt. of a fluorine-containing resin, 3-80 pts.wt. of an impact modifier and 0.05-10 pts.wt. of an organic compound having a functional group reactive with the thermoplastic polyester.

公开(公告)号：JP2000160011A

公开(公告)日：2000-06-13

申请号：JP34077298

申请日：1998-11-30

Applicant: TORAY INDUSTRIES

Inventor： NISHIMURA TORU ,  KOBAYASHI SADAYUKI ,  YAMANAKA TORU

IPC: C08K3/34 ,  C08L81/02

Abstract: PROBLEM TO BE SOLVED: To obtain a polyphenylene sulfide(PPS) resin composition which inhibits generation of burrs and is especially useful for small precision components, or the like. SOLUTION: This resin composition is prepared by mixing (A) a polyphenylene sulfide resin and (B) from 0.1 to 50 wt.% swellable lamellar silicate, calculated as an inorganic ash content in the composition. Here, the extractability of the polyphenylene sulfide resin into chloroform in Soxhlet extraction is 3 wt.% or less of the polyphenylene sulfide resin.

公开(公告)号：JP2000053871A

公开(公告)日：2000-02-22

申请号：JP22504198

申请日：1998-08-07

Applicant: TORAY INDUSTRIES

Inventor： YAMANAKA TORU ,  NISHIMURA TORU

IPC: C08J3/20 ,  C08K3/00 ,  C08K3/34 ,  C08L55/02 ,  C08L67/00 ,  C08L77/00 ,  C08L81/02 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To obtain a resin compsn. which contains a filler or layered silicate having a small particle size and homogeneously dispersed therein by mixing a thermoplastic resin with an inorg. filler under contact with a supercritical fluid. SOLUTION: This resin compsn. is prepd. by mixing 100 pts.wt. thermoplastic resin with an inorg. filler in an amt. of 80-0.01 wt.% of the compsn. and 0.05-10 pts.wt. olefin compd. having a carboxylic anhydride group under contact with carbon dioxide or the like which becomes a supercritical fluid at a temp. in the range from the m.p. of the resin to its decomposition temp. in an amt. of the fluid of 0.01-30 wt.% of the compsn. Examples of the thermoplastic resin are a polyamide resin, a polyester resin, and a polyarylene sulfide resin. The inorg. filler is a fibrous one (e.g. glass fibrs or steel fibres), a powdery or platy one (e.g. tale or mica), or a layered silcate (e.g. montmorillonite), and 0.01-20 wt.% coupling agent (e.g. a silane compd.) is added to the filler.

公开(公告)号：JPH09216951A

公开(公告)日：1997-08-19

申请号：JP2571096

申请日：1996-02-13

Applicant: TORAY INDUSTRIES

Inventor： TOGAWA MITSUNARI ,  YAMANAKA TORU ,  KUMAKI JIRO

IPC: C08J5/00 ,  B29C45/00 ,  B29K67/00 ,  B29K77/00 ,  B29K81/00 ,  B29K105/16 ,  B29K105/18 ,  B29L22/00 ,  B29L31/34 ,  C08K3/00 ,  C08K9/04 ,  C08L23/16 ,  C08L67/00 ,  C08L77/00 ,  C08L81/02 ,  C08L81/04 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide a housing having an excellent balance among heat resistance, rigidity and impact resistance. SOLUTION: This housing is made by molding a resin composition comprising at least three components of a thermoplastic resin (A), an inorganic filler (B) and an elastic polymer (C) having a glass transition temperature of -20 deg.C or below and being a resin composition which contains a thermoplastic resin (A) as the matrix resin, and in which at least 30% of the dispersed particles of the elastic polymer (C) in the composition are present in a state in which they and inorganic filler (B) have common interfaces.

公开(公告)号：JPH05156136A

公开(公告)日：1993-06-22

申请号：JP33943691

申请日：1991-11-29

Applicant: TORAY INDUSTRIES

Inventor： KUREMATSU TOSHIO ,  YAMANAKA TORU ,  INOUE SHUNEI

IPC: C08K7/00 ,  C08K3/00 ,  C08L67/00

Abstract: PURPOSE:To prepare the subject compsn. excellent in flame retardancy, esp. resistance to falling of granules during burning as well as in mechanical proper ties, heat resistance, and molding appearance. CONSTITUTION:100 pts.wt. melt-anisotropic polyester, 0.5-30 pts.wt. organobromine polymer of which the wt. loss on heating under nitrogen blow at a heating rate of 10 deg.C/min reaches 1wt.% at 315 deg.C or higher, and 0-200 pts.wt. filler are compounded to give the objective compsn.

公开(公告)号：JPH04283230A

公开(公告)日：1992-10-08

申请号：JP4468991

申请日：1991-03-11

Applicant: TORAY INDUSTRIES

Inventor： YAMANAKA TORU ,  KIMURA TAKESHI ,  INOUE SHUNEI

IPC: C08G63/60 ,  C08K3/00 ,  C08K7/04 ,  C08L67/00

Abstract: PURPOSE:To obtain a copolyester which is excellent in flow and moldability, gives a molding excellent in heat resistance, rigidity, impact resistance, etc., and is desirable for the production of electrical or electronic components, etc., by combining four specified kinds of structural units. CONSTITUTION:A copolyester which comprises structural units of formulas I, II, III and IV, wherein the amount of structural units of formulas I and II is 80-90mol% based on structural units of formulas I, II and III, the amount of structural units of formula III is 20-1mol% based on structural units of formulas I, II and III, the molar ratio of units of formula I to units of formula II is 75/25-95/5, the molar ratio of units of formula II to units of formula III is 90/10-40/60, the melting temperature (Tm deg.C) satisfies formula V (wherein x is a molar ratio of units of formula III to units of formulas I, II and III), and the logarithmic viscosity is 3-10dl/g, and which has melt anisotropy. An example of the production process comprises reacting p-hydroxybenzoic acid with 4,4'- dihydroxybiphenyl and acetic anhydride, 2,6-diacetoxy-naphthalene and terephthalic acid and polymerizing them through the elimination of acetic acid in a molten state.