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公开(公告)号：KR101308405B1
公开(公告)日：2013-09-16
申请号：KR1020130023862
申请日：2013-03-06
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A synthetic fuel production apparatus using biomethane and a method thereof are provided to be used for vehicles and power generation plants. CONSTITUTION: A biogas reservoir(1) collects biogas from a biogas generation place and stores the biogas. A biogas purifier(2) separates biomethane with high purity from the biogas. A steam methane reforming device(3) is composed of a modular metal structure catalyst which generates synthetic gas by reforming the biomethane and a modular heat exchange reactor with multiple pipes. The Fisher-Tropsch synthesis reactor(5) is composed of a modular metal structure catalyst which liquefies the biogas to generate synthetic fuel and a modular heat exchange reactor with multiple pipes. An electricity generating device for a fuel cell(6) generates electricity using hydrogen with high purity as a raw material. [Reference numerals] (AA) H_2/CO rate 3:1; (BB) H_2/CO rate 2:1
Abstract translation: 目的：提供一种使用生物甲烷的合成燃料生产装置及其方法，用于车辆和发电厂。 构成：沼气池（1）从沼气发电场收集生物气，储存沼气。 沼气净化器（2）将沼气中的高纯度生物甲烷分离出来。 蒸汽甲烷重整装置（3）由通过重整生物甲烷生产合成气体的模块化金属结构催化剂和具有多个管道的模块化热交换反应器组成。 费托合成反应器（5）由将生物气液化以产生合成燃料的模块化金属结构催化剂和具有多个管道的模块式热交换反应器组成。 燃料电池（6）的发电装置以高纯度的氢为原料发电。 （标号）（AA）H_2 / CO率3:1; （BB）H_2 / CO率2：1
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72.发明公开가지형 금속실리케이트를 이용한 금속/실리카 촉매 담지체의 제조방법 및 그 금속/실리카 금속/실리카 촉매 담지체 有权通过分支金属硅酸盐结构和金属/二氧化硅支持的催化剂制备金属/二氧化硅负载催化剂的制备方法
公开(公告)号：KR1020130045024A
公开(公告)日：2013-05-03
申请号：KR1020110109441
申请日：2011-10-25
Applicant: 한국에너지기술연구원
CPC classification number: B01J37/0219 , B01J23/75 , B01J35/023 , B01J37/08 , B01J37/18
Abstract: PURPOSE: A metal and silica doped catalyst and a manufacturing method thereof are provided to uniformly dip metal particles with 20 wt% or higher concentration by developing pores and be thermally stable by not causing sintering between the metal particles at 700°C of high temperature heat treatment. CONSTITUTION: A manufacturing method of a metal and a silica doped catalyst comprises the following steps: manufacturing metal, metal oxide, or an alloy nano particles by decomposing organometallic compounds at high temperature by mixing with organic surfactant and organic solvent; coating the nano-particles with silica using micro emulsion; converting the metal and silica core-shell structure into the branched metal silicate structure using a high temperature hydrothermal reaction; and obtaining metal doped catalyst which is high deposited in silica by reducing and annealing the metal silicate structure under a high temperature hydrogen condition. The metal or metal oxide nano-particle and alloy nano-particle are manufactured in a non-aqueous system. [Reference numerals] (AA) Metal salt + organic surfactant; (BB) Thermal reduction or decomposition; (CC) Metal or metal oxide nanoparticles; (DD) Silica coating using microemulsion; (EE) Metal or metal oxide/silica core-shell nanoparticles; (FF) Hydrothermal reaction; (GG) Branch type metal silicate structure; (HH) High temperature plasticizing or reduction; (II) Metal/silica doped catalyst
Abstract translation: 目的：提供一种金属和二氧化硅掺杂催化剂及其制造方法，通过显影孔均匀浸渍20重量％以上的金属颗粒，并通过在700℃的高温热不引起金属颗粒之间的烧结而热稳定 治疗。 构成：金属和二氧化硅掺杂催化剂的制造方法包括以下步骤：通过与有机表面活性剂和有机溶剂混合在高温下分解有机金属化合物来制造金属，金属氧化物或合金纳米颗粒; 使用微乳液用二氧化硅涂覆纳米颗粒; 使用高温水热反应将金属和二氧化硅核 - 壳结构转化成支链金属硅酸盐结构; 并通过在高温氢气条件下还原和退火金属硅酸盐结构，获得高度沉积在二氧化硅中的金属掺杂催化剂。 金属或金属氧化物纳米颗粒和合金纳米颗粒在非水系统中制造。 （AA）金属盐+有机表面活性剂; （BB）热还原或分解; （CC）金属或金属氧化物纳米粒子; （DD）使用微乳液的二氧化硅涂层; （EE）金属或金属氧化物/二氧化硅核 - 壳纳米粒子; （FF）水热反应; （GG）分支型金属硅酸盐结构; （HH）高温塑化或还原; （II）金属/二氧化硅掺杂催化剂
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公开(公告)号：KR1020120014811A
公开(公告)日：2012-02-20
申请号：KR1020100077009
申请日：2010-08-10
Applicant: 한국에너지기술연구원
CPC classification number: C10G2/344 , B01J8/009 , B01J8/1818 , B01J37/0225 , C10G2/331
Abstract: PURPOSE: A trade bubble column reactor using a redistribution disc is provided to activate the reaction of a catalyst and synthetic gas inside the reactor by uniformly redistributing bubble particles of the synthetic gas. CONSTITUTION: A trade bubble column reactor using a redistribution disc comprises the following: a bubble column reactor body(10) for storing slurry containing a catalyst; a distributing unit(20) converting bubble particles of synthetic gas supplied through an inlet pipe(11) into uniform bubble particles, and supplying into the bubble column reactor body; a re-distributing unit(30) uniformly re-distributing the bubble particles; a filtering unit(40) discharging synthetic fuel after filtering and reacting with the catalyst; and an outlet pipe(12) discharging chemical fume generated from non-reacted synthesis gas.
Abstract translation: 目的：提供使用再分布盘的泡罩塔式反应器，通过均匀重新分配合成气体的气泡颗粒来激活反应器内的催化剂和合成气体的反应。 构成：使用再分配盘的泡罩塔式反应器包括：用于储存含有催化剂的浆料的气泡塔反应器主体（10） 分配单元（20），将通过入口管（11）供应的合成气体的气泡颗粒转化成均匀的气泡颗粒，并供应到气泡塔反应器主体中; 重新分配单元（30）均匀地重新分配气泡颗粒; 过滤单元（40），其在过滤并与所述催化剂反应之后排出合成燃料; 以及排出由未反应的合成气产生的化学烟雾的出口管（12）。
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公开(公告)号：KR1020110045676A
公开(公告)日：2011-05-04
申请号：KR1020090102346
申请日：2009-10-27
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A wet scrubber system using centrifugal force is provided to remove ultra-fine dust through effective wet cleaning through a relatively simple configuration, and to ensure excellent dust collection efficiency compared with existing cyclone dust collectors. CONSTITUTION: A wet scrubber system using centrifugal force comprises: a cyclone chamber(20) in which fine dust(22) within exhaust gas is collected in the lower part thereof: a gas inlet(30) which is installed in order to flow in while exhaust gas is rotated in the cyclone chamber; a control valve(40) which is installed in order to discharge cooling water sprayed from the cyclone chamber and the collected fine dust; a gas outlet(50) which is installed in order to discharge exhaust gas from which the fine dust is removed; screen spray nozzles(60) installed at the wall of the cyclone chamber; and a superfine dust removal unit installed at one end of the gas outlet.
Abstract translation: 目的：使用离心力的湿式洗涤器系统通过相对简单的配置通过有效的湿法清洗来除去超细粉尘，并且与现有的旋风除尘器相比，确保了优异的除尘效率。 构成：使用离心力的湿式洗涤器系统包括：旋风室（20），排气中的细粉尘（22）在其下部收集：气体入口（30），其安装成为流入，同时 排气在旋风室中旋转; 控制阀（40），其安装以排出从旋风室喷射的冷却水和收集的细粉尘; 气体出口（50），其安装以排出除去细粉尘的废气; 安装在旋风室壁上的丝网喷嘴（60）; 以及安装在气体出口一端的超细除尘单元。
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公开(公告)号：KR100986751B1
公开(公告)日：2010-10-08
申请号：KR1020090088000
申请日：2009-09-17
Applicant: 한국에너지기술연구원
CPC classification number: B01J8/22 , B01J8/1836 , B01J2208/00053 , B01J2208/00123 , B01J2208/00132 , C10G2/34 , F28D7/12 , F28D7/16 , F28F9/0273 , C10G2/342
Abstract: PURPOSE: A multistage separation type cooling system for elimination of heat of reaction at a Fischer-Tropsch slurry bubble column reactor is provided to minimize the harmful elements for the bubbling in a reactor and enable the easy installation and maintenance of a cooling pipe. CONSTITUTION: A multistage separation type cooling system for elimination of heat of reaction at an FT(Fischer-Tropsch) slurry bubble column reactor comprises: a first cooling pipe(31) which is horizontally installed in an upper cover of a reactor; a second cooling pipe(32) which protrudes toward the outside and has a discharge hole at an end portion thereof; a third cooling pipe(33) which vertically connects the first and second cooling pipes; and an inner pipe(40) which absorbs the heat around the sprayed cooling water to enable the phase change into stream.
Abstract translation: 目的：提供一种用于消除费 - 托浆鼓泡塔反应器的反应热的多级分离式冷却系统，以最大限度地减少反应器中起泡的有害元素，从而使冷却管易于安装和维护。 构成：用于消除FT（费 - 托）浆液鼓泡塔反应器的反应热的多级分离式冷却系统包括：水平安装在反应器的上盖中的第一冷却管道（31） 第二冷却管（32），其朝向外部突出并在其端部具有排出孔; 第三冷却管（33），其垂直连接第一和第二冷却管; 以及内管（40），其吸收喷射的冷却水周围的热量以使相变成流。
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Patent Agency Ranking
公开(公告)号：KR100901736B1
公开(公告)日：2009-06-09
申请号：KR1020080057939
申请日：2008-06-19
Applicant: 한국에너지기술연구원
IPC: C10B39/04
CPC classification number: B01J8/20 , B01J2208/00132 , C10G2/342 , F28D7/12 , F28F9/026
Abstract: A cooling system for eliminating reaction heat at a fischer-tropsch slurry bubble column reactor is provided to control the heat-generating temperature inside the reactor by jetting the small amount of cooling water on a cooling pipe at cooling pipe through an injection pipe arranged inside the cooling pipe. A cooling system(100) for eliminating reaction heat at a FT(Fischer Tropsch) slurry bubble column reactor comprises: a first cooling pipe(10) which is arranged on the top of the FT slurry bubble column reactor(200) and is connected to the FT slurry bubble column reactor; a plurality of second cooling pipes(11) connected vertically downward to the bottom of the first cooling pipe; and a cooling water spray pipe(20) which has smaller inside diameter than the inside diameter of the second cooling pipe and the first cooling pipe and in which the end part is closed to form inside pressure; The first cooling pipe is arranged as in a concentric circle or a grid structure. The injection pipe is connected to a valve(22) to control the pressure of the cooling water and includes a plurality of nozzles(21) to spray the flowed water.
Abstract translation: 提供了一种用于消除费托淤浆泡罩塔反应器中的反应热的冷却系统，通过在冷却管的冷却管上喷射少量的冷却水，通过布置在内部的喷射管中来控制反应器内的发热温度 冷却管。 用于消除FT（费 - 托）浆液鼓泡塔反应器的反应热的冷却系统（100）包括：第一冷却管（10），其布置在FT浆料鼓泡塔反应器（200）的顶部并连接到 FT浆液鼓泡塔反应器; 多个第二冷却管（11），其垂直向下连接到第一冷却管的底部; 和冷却水喷射管（20），其具有比第二冷却管和第一冷却管的内径小的内径，并且其端部封闭以形成内部压力; 第一冷却管布置成同心圆或网格结构。 喷射管连接到阀（22）以控制冷却水的压力，并且包括多个喷嘴（21）以喷射流动的水。
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公开(公告)号：KR100679341B1
公开(公告)日：2007-02-07
申请号：KR1020040073902
申请日：2004-09-15
Applicant: 한국에너지기술연구원
CPC classification number: B01D71/022 , B01D67/0069 , B01D67/0072 , B01D67/0083 , B01D67/009 , B01D69/10 , B01D69/12 , B01D2323/40 , C01B3/505
Abstract: 본 발명은 수소기체분리용 팔라듐 합금복합막의 제조방법에 관한 것으로, (a) 다공성 지지체의 상부에 전해도금 방법에 의하여 제1금속 코팅층을 형성하는 단계; (b) 제1금속 코팅층의 상부에 건식도금 방법으로 팔라듐 코팅층을 형성하는 단계; 및 (c) 팔라듐 코팅층을 열처리하여 팔라듐과 제1금속의 합금층을 형성하는 단계를 포함하는 수소기체분리용 팔라듐 합금복합막의 제조방법을 제공한다.
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公开(公告)号：KR1020060031935A
公开(公告)日：2006-04-14
申请号：KR1020040080918
申请日：2004-10-11
Applicant: 한국에너지기술연구원
IPC: H01M8/04
CPC classification number: B01J19/0093 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/00873 , B01J2219/00889 , C01B3/384 , C01B2203/0227 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , F28D9/005 , F28D9/0093 , F28F2260/02 , H01M8/0631 , Y02P20/128
Abstract: 본 발명은 미세유로를 갖는 금속박판을 다층으로 적층하고, 가열체와 피가열체가 연소용 박판과 열전달용 박판으로 교차공급되는 시스템에서 가열에 필요한 열량의 생성이 피가열체가 존재하는 반응기 전면에서 고르게 진행될 수 있도록, 연료와 공기의 균일 혼합을 유도하여 반응기내 온도차를 최소화하기 위한 미세유로 가열기에 관한 것으로, 피가열체 유입구와, 연료 유입구와, 산화제 유입구를 포함하는 상부플레이트; 피가열체 배출구와, 배가스 배출구를 포함하는 하부플레이트; 및 상기 상부플레이트와 상기 하부플레이트 사이에 교대로 적층된 다수의 연소용 박판과 열전달용 박판을 포함하고; 상기의 연소용 박판과 열전달용 박판은 피가열체 유입홀과 피가열체 배출홀과 산화제홀과 배가스홀과 연료홀과 미세유로홈이 각각 동일한 위치에 형성되며; 상기 연소용 박판은 배가스홀과 연료홀이 미세유로홈에 의해 연결되고; 상기 열전달용 박판은 상기 피가열체 유입홀과 피가열체 배출홀이 미세유로홈에 의해 연결되고; 상기 연소용 박판에는 연료공급구가 형성되어 상기 열전달용 박판의 연료홀에 연결되어 형성된 연료공급홀과 연접하여 연료를 공급받으며; 상기 상부플레이트의 하부에는 연소용 박판이 피가열체 유입구와 피가열체 유입홀, 연료유입구와 연료홀, 산화제 유입구와 산화제홀이 각각 일치하게 위치하도록 설치되고, 상기 하부플레이트의 하부에는 열전달용 박판이 피가열체 배출홀과 피가열체 배출구, 배가스홀과 배가스 배추구가 각각 일치하게 위치하도록 설치되는 균일가열을 위한 미세유로 가열기이다.
균일가열, 미세유로 가열기, 탄화수소, 연료전지-
公开(公告)号：KR1020060017408A
公开(公告)日：2006-02-23
申请号：KR1020040066073
申请日：2004-08-20
Applicant: 한국에너지기술연구원
IPC: B01D71/02
Abstract: 본 발명은 수소기체분리용 팔라듐 합금복합막의 제조방법에 관한 것으로, (a) 다공성 지지체의 상부를 플라즈마를 이용하여 표면처리하는 단계; (b) 다공성 지지체의 상부에 전해도금 방법에 의하여 1차 금속코팅층을 형성하는 단계; (c) 1차 금속코팅층의 상부에 스퍼터 증착으로 팔라듐 코팅층을 형성하는 단계; 및 (d) 팔라듐 코팅층을 열처리하여 팔라듐과 1차 금속의 합금층을 형성하는 단계를 포함하는 수소기체분리용 팔라듐 합금복합막의 제조방법을 제공한다.
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公开(公告)号：KR1020050030492A
公开(公告)日：2005-03-30
申请号：KR1020030067042
申请日：2003-09-26
Applicant: 한국에너지기술연구원
IPC: C01B3/26
CPC classification number: B01J37/0225 , B01J8/048 , B01J8/0496 , B01J12/007 , B01J19/087 , B01J19/2485 , B01J23/40 , B01J23/58 , B01J23/63 , B01J35/04 , B01J37/0215 , B01J37/0226 , B01J37/0234 , B01J2208/00061 , B01J2208/00495 , B01J2208/0053 , B01J2208/00716 , C01B3/386 , C01B2203/0261 , C01B2203/0833 , C01B2203/085 , C01B2203/0866 , C01B2203/1023 , C01B2203/1064 , Y02P20/52
Abstract: To provide a process for partial-oxidation of a reactant gas into hydrogen and carbon monoxide, which is able to achieve complete conversion of the reactant within a short period of time by pre-heating the reactant through a heat-exchanger and converting the reactant into the hydrogen and carbon monoxide using an electrically-heating type catalyst. In the process, a reactant gas is allowed to pass through a reactor that has a heat-exchanger and is packed with an electrically-heating type catalyst and a noble-metal wash-coated metal-monolith catalyst to be converted into hydrogen and carbon monoxide. The reactant gas is a mixture gas containing methane, natural gas, liquid propane gas, naphtha, gasoline, and a gas containing hydrocarbon and oxygen of diesel oil. The reactant gas is pre-heated by a high-temperature reaction-generation gas in the heat-exchanger and then injected into the reactor.
Abstract translation: 为了提供将反应物气体部分氧化成氢气和一氧化碳的方法，其能够在短时间内通过热交换器预热反应物并将反应物转化成 使用电加热型催化剂的氢和一氧化碳。 在此过程中，使反应气体通过具有热交换器的反应器，并且装有电加热型催化剂和贵金属洗涤涂覆的金属整料催化剂以转化成氢气和一氧化碳 。 反应气体是含有甲烷，天然气，液体丙烷气，石脑油，汽油和含有柴油的烃和氧的气体的混合气体。 反应气体通过热交换器中的高温反应生成气体预热，然后注入反应器。
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