公开(公告)号：NO20004424D0

公开(公告)日：2000-09-05

申请号：NO20004424

申请日：2000-09-05

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：TR199901895T2

公开(公告)日：2000-04-21

申请号：TR9901895

申请日：1998-01-17

Applicant: BASF AG

Inventor： BASSLER PETER ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  RUST HARALD

IPC: C07C253/34 ,  C07C255/24

Abstract: A process for distillative removal of 6-aminocapronitrile from mixtures (I) comprising 6-aminocapronitrile and an imine (II) comprises conducting the distillation in the presence of carbon dioxide.

公开(公告)号：CZ280299A3

公开(公告)日：2000-04-12

申请号：CZ280299

申请日：1998-01-30

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  LUYKEN HERMANN

IPC: C07C253/34

公开(公告)号：DE19839346A1

公开(公告)日：2000-03-02

申请号：DE19839346

申请日：1998-08-28

Applicant: BASF AG

Inventor： FISCHER ROLF ,  BASLER PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  ANSMANN ANDREAS ,  REHFINGER ALWIN ,  VOIT GUIDO

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent. The method is characterised in that a) adipodinitrile is hydrogenated at temperatures of 70 to 220 DEG C and at pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent to produce a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers, until the sum of the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. % in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6-aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).

公开(公告)号：CZ9901243A3

公开(公告)日：1999-12-15

申请号：CZ124399

申请日：1997-10-17

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  GANN MARTIN ,  MARKL ROBERT ,  SCHMITT RUDIGER

IPC: B01J31/24 ,  C07C27/12 ,  C07C29/32 ,  C07C29/44 ,  C07C29/50 ,  C07C31/135 ,  C07C33/02 ,  C07C33/03 ,  C07C33/035 ,  C07C35/08 ,  C07C45/33 ,  C07C45/51 ,  C07C49/403 ,  C07C49/603

CPC classification number: C07C45/512 ,  C07C29/32 ,  C07C29/50 ,  C07C45/33 ,  C07C2601/14 ,  C07C49/403 ,  C07C35/08

公开(公告)号：TR199901894T2

公开(公告)日：1999-10-21

申请号：TR9901894

申请日：1998-01-30

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  REHFINGER ALWIN

IPC: C07C209/82 ,  C07C209/86 ,  C07C211/09 ,  C07C211/12 ,  C07C249/02 ,  C07C251/08 ,  C07C251/12 ,  C07C253/34 ,  C07C255/04 ,  C07C255/24 ,  C07D223/04

Abstract: A process for distillative separation of part or all of an imine (III) from a mixture (II) comprising an amine (I) and said imine (III) comprises adding to the distillation mixture a compound (IV) which is inert toward said amine (I) under distillation conditions and whose boiling point is above the boiling point of said amine (I) under said distillation conditions to obtain, after the distillation, a mixture (VI) comprising essentially said compound (IV).

公开(公告)号：CZ9902751A3

公开(公告)日：1999-10-13

申请号：CZ275199

申请日：1998-01-30

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  REHFINGER ALWIN

IPC: C07C209/86 ,  C07C211/12 ,  C07C249/02 ,  C07C251/08 ,  C07C251/12 ,  C07C253/34 ,  C07C255/04 ,  C07C255/24 ,  C07D223/04 ,  C07C209/82 ,  C07C211/09

CPC classification number: C07D223/04 ,  C07C209/86 ,  C07C211/12

公开(公告)号：PL332733A1

公开(公告)日：1999-10-11

申请号：PL33273397

申请日：1997-10-17

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  GANN MARTIN ,  MAERKL ROBERT ,  SCHMITT RUEDIGER

IPC: B01J31/24 ,  C07C27/12 ,  C07C29/32 ,  C07C29/44 ,  C07C29/50 ,  C07C31/135 ,  C07C33/02 ,  C07C33/03 ,  C07C33/035 ,  C07C35/08 ,  C07C45/33 ,  C07C45/51 ,  C07C49/403 ,  C07C49/603

Abstract: PCT No. PCT/EP97/05740 Sec. 371 Date Apr. 14, 1999 Sec. 102(e) Date Apr. 14, 1999 PCT Filed Oct. 17, 1997 PCT Pub. No. WO98/17612 PCT Pub. Date Apr. 30, 1998In a process for preparing oxidation products of cyclohexane by catalytic oxidation with oxygen-containing gases in the liquid phase, where the gases are brought into contact essentially uniformly with the liquid cyclohexane in a reaction zone, liquid cyclohexane and the oxygen-containing gases are passed in countercurrent through the reaction zone.

公开(公告)号：CA2322185A1

公开(公告)日：1999-09-10

申请号：CA2322185

申请日：1999-02-23

Applicant: BASF AG

Inventor： FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  MERGER MARTIN ,  LUYKEN HERMANN ,  VOIT GUIDO ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention relates to a substance which is suitable for use as a catalyst, containing a) iron or a compound based on iron or mixtures thereof, b) 0.001 to 0.3 wt. % in relation to a) of a promoter based on 2, 3, 4 or 5 elements from the following group: aluminium, silicon, zirconium, titanium and vanadium, c) 0 to 0.3 wt. % in relation to a) of a compound based on an alkaline and/or alkaline earth metal and d) 0.001 to 1 wt. % in relation to a) of manganese. The inventive substances can be used as catalysts for the hydrogenation of alpha-, omega-dinitriles.

公开(公告)号：DE19809686A1

公开(公告)日：1999-09-09

申请号：DE19809686

申请日：1998-03-06

Applicant: BASF AG

Inventor： VOIT GUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASLER PETER ,  ANSMANN ANDREAS

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention relates to a method for hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a heterogeneous fixed-bed catalyst. The method is characterised in that the reaction mixture contains 2 mu mol to 30 mmol Na, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, in relation to 10 mol of the aliphatic alpha-, omega-dinitrile used.