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公开(公告)号：JPH05239279A
公开(公告)日：1993-09-17
申请号：JP3944892
申请日：1992-02-26
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To prepare the subject compsn. having permanent antistatic properties and excellent mechanical characteristics by compounding specified amts. of a polyolefin, a polyetheresteramide, a polyamide, and a specific compd. CONSTITUTION:100 pts.wt. polymer component comprising 10-99wt.% polyolefin and 90-1wt.% polyetheresteramide (a polymer obtd. from caprolactam, polyethylene glycol, and terephthalic acid) is compounded with 1-50 pts.wt. polyamide (e.g. nylon 6) and 0.01-50 pts.wt. styrenesulfonic acid compd. contg. at least 50wt.% styrenesulfonic acid structural units of the formula [wherein R is H, alkyl, or aryl; X is H, an alkali or alkaline earth metal, or ammonium; and (n) is 1-20,000].
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公开(公告)号：JPH0559941B2
公开(公告)日：1993-09-01
申请号：JP9063188
申请日：1988-04-13
Applicant: TORAY INDUSTRIES
Inventor： CHIBA KAZUMASA , MURAKI TOSHIO
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公开(公告)号：JPH0515743B2
公开(公告)日：1993-03-02
申请号：JP33141188
申请日：1988-12-27
Applicant: TORAY INDUSTRIES
Inventor： YANO KAZUHISA , IWAMOTO MASAAKI , CHIBA KAZUMASA
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公开(公告)号：JPH0539388A
公开(公告)日：1993-02-19
申请号：JP19441591
申请日：1991-08-02
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain an antistatic composition which is improved in permanent antistatic properties and gives a molding improved in appearance by mixing a polyolefin, a polyether ester amide, and a specified styrenesulfonic acid compound. CONSTITUTION:An amino carboxylic acid, a dicarboxylic acid/diamine salt or a lactam, a dicarboxylic acid, and a poly(alkylene oxide) glycol are melt compounded, and polymerization is effected in a high vacuum to give a polyether ester amide (A). 100 pts.wt. mixture of 90-1wt.% component A and 10-99wt.% polyolefin (B) is mixed with 0.01-50 pts.wt. styrenesulfonic acid compound (C) of the formula [wherein R is H, alkyl or aryl; X is H, an alkali (alkaline earth) metal or ammonium; (n) is 1 to 20,000], thus giving the objective composition.
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公开(公告)号：JPH04345653A
公开(公告)日：1992-12-01
申请号：JP11770291
申请日：1991-05-22
Applicant: TORAY INDUSTRIES
Inventor： NAKAMURA SEIICHI , KUWATA JOSHIN , CHIBA KAZUMASA
Abstract: PURPOSE:To improve mechanical properties, heat resistance, and flex resistance by compounding a thermoplastic polyester, a rubber-reinforced graft polymer, a specific vinyl polymer, and a vinyl polymer having glycidyl ester groups. CONSTITUTION:The title compsn. comprises 96.5-30wt.% thermoplastic polyester with an intrinsic viscosity of 0.36-1.60, 3-60wt.% rubber-reinforced graft polymer obtd. by grafting 100 pts.wt. monomer component consisting of 50-100wt.% arom. vinyl monomer and 50-0wt.% vinyl cyanide monomer onto 12-80 pts.wt. nondiene rubber, 0-40wt.% vinyl polymer obtd. by polymerizing a vinyl monomer of formula I (wherein R1 is H or lower alkyl; and R2 is phenyl, cyano, or a 1-10C alkyl ester group), and 0.1-45wt.% vinyl polymer which has glycidyl ester groups and is obtd. by copolymerizing 99.95-40wt.% the vinyl monomer of formula I with 0.05-60wt.% vinyl monomer of formula II (wherein R3 is R2) having a glycidyl ester group.
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Patent Agency Ranking
公开(公告)号：JPH0465238A
公开(公告)日：1992-03-02
申请号：JP17750590
申请日：1990-07-06
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SEIJI , CHIBA KAZUMASA
IPC: B32B15/08 , B32B15/088
Abstract: PURPOSE:To enhance permanent antistatic properties, extrusion processability, light screening properties and gas barrier properties by laminating an antistatic composition composed of specific amide or specific amide and other thermoplastic resin to a metal foil. CONSTITUTION:A layer of an antistatic resin composition consisting of polyether ester amide and other thermoplastic resin, pref., a polyolefinic resin is laminated to a metal foil. Polyether ester amide is a polymer wherein a polyamide component and a polyether component are bonded through an ester bond. As the metal foil, an aluminum foil is pref. used. As the antistatic resin composition, polyether ester amide can be independently used and can be also used in the form of the blend with other thermoplastic resin. The lamination form of the laminate is set to a two-layer structure wherein the antistatic resin composition layer is an auxiliary layer 2 and the aluminum foil layer is a main layer or a three-layer structure wherein the auxiliary layers 2 are laminated to both surfaces of the main layer 1.
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公开(公告)号：JPH0453863A
公开(公告)日：1992-02-21
申请号：JP16326990
申请日：1990-06-20
Applicant: TORAY INDUSTRIES
Inventor： SAKAI HIDETOSHI , CHIBA KAZUMASA , KUMAKI JIRO
Abstract: PURPOSE:To obtain a thermoplastic resin composition excellent in impact resistance, heat resistance and chemical resistance by mixing an ABS resin with a specified modified polyester resin and a specified vinyl polymer. CONSTITUTION:The title composition is obtained by mixing 10-84 pts.wt. ABS resin with 15-89 pts.wt. polyester resin prepared by modifying 100wt.% thermoplastic polyester prepared from an 8-20C aromatic dicarboxylic acid or its lower alkyl ester and a 2-20C diol with 0.01-20wt.% phenolic hydroxyl-containing organic sulfonic acid salt of formula I (wherein Ar is a 6-30C aromatic ring; M is an alkali metal or an alkaline earth metal; m is 1 or 2; and n is 1-5), 1-70 pts.wt. modified vinyl polymer prepared by copolymerizing a monomer mixture comprising 50-90wt.% aromatic vinyl, 9-50wt.% vinyl cyanide and 0.1-20wt.% alpha,beta-unsaturated carboxylic acid metal salt and an alpha,beta-unsaturated carboxylic acid having the relationship of formula II, wherein x and y are the weight percentages of the alpha,beta-unsaturated carboxylic acid metal and the (alpha,betaunsaturated carboxylic acid in the copolymer, respectively.
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公开(公告)号：JPH0453862A
公开(公告)日：1992-02-21
申请号：JP16326890
申请日：1990-06-20
Applicant: TORAY INDUSTRIES
Inventor： SAKAI HIDETOSHI , CHIBA KAZUMASA , KUMAKI JIRO
Abstract: PURPOSE:To obtain a thermoplastic resin composition excellent in impact resistance, heat resistance and chemical resistance by mixing an ABS resin with a specified modified polyester resin and a specified modified vinyl polymer. CONSTITUTION:10-84 pts.wt. ABS resin is mixed with 15-89 pts.wt. polyester resin prepared by modifying 100wt.% thermoplastic polyester prepared from an 8-20C aromatic dicarboxylic acid or its lower alkyl ester and a 2-20C diol with 0.01-20wt.% phenolic hydroxyl-containing organic sulfonic acid salt of the formula (wherein Ar is a 6-30C aromatic ring; M is an alkali metal or an alkaline earth metal; m is 1 or 2; and n is 1-5) and 1-70 pts.wt. modified vinyl polymer prepared by copolymerizing an aromatic vinyl with vinyl cyanide and an alpha,beta-unsaturated carboxylic acid (the total of components A, B and C is 100 pts.wt.). In this way, a thermoplastic resin composition having both the impact resistance of the ABS resin and the heat resistance and chemical resistance of the polyester resin can be obtained.
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公开(公告)号：JPH0415255A
公开(公告)日：1992-01-20
申请号：JP11950090
申请日：1990-05-08
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SEIJI , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain a resin composition having permanent antistatic properties and excellent impact resistance, rigidity and moldability and not suffering from delamination by mixing a specified polyether ester amide with a specified polyolefin oligomer. CONSTITUTION:A thermoplastic resin composition comprising 1-99wt.% polyether ester amide containing 10-90wt.% polyether ester units prepared by copolymerizing a monomer selected among a C6 or higher aminocarboxylic acid, its lactam, and a salt of a C6 or higher diamine with a dicarboxylic acid with a poly(alkylene oxide) glycol of a number-average mol.wt. of 200-6000 and a C4-20 dicarboxylic acid and 99-1wt.% polyolefin oligomer of a number- average mol.wt. of 1000-20000, prepared by graft-polymerizing an unsaturated carboxylic acid or its anhydride. Example so the monomer which can desirably be used include caprolactam, 12-aminododecanoic acid and hexamethylenediamine/adipic acid salt.
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公开(公告)号：JPH03292349A
公开(公告)日：1991-12-24
申请号：JP9556290
申请日：1990-04-10
Applicant: TORAY INDUSTRIES
Inventor： OGAWA TAKUYA , SAKAI HIDETOSHI , CHIBA KAZUMASA
Abstract: PURPOSE:To improve moldability and resistance to impact, heat, and chemicals by compounding a specific graft copolymer compsn., a polyester, a copolymer, an inorg. filler, and a crystallization accelerator. CONSTITUTION:90-15 pts.wt. monomer mixture comprising 50-90wt.% arom. vinyl monomer, 10-50wt.% vinyl cyanide, and 0-30wt.% vinyl monomer copolymerizable with the above two monomers is graft copolymerized in the presence of 10-85 pts.wt. diene rubber to give a graft copolymer, which is copolymerized with another monomer to give a graft copolymer compsn. 100 pts.wt. compsn. comprising 1-97 pts.wt. said graft copolymer or graft copolymer compsn., 1-97 pts.wt. polyester wherein terephthalic acid accounts for 50mol% or higher of the dicarboxylic acid component and ethylene glycol accounts for 50mol% or higher of the diol component, 1-40 pts.wt. copolymer comprising 50-90wt.% said arom. vinyl monomer, 9-50wt.% vinyl cyanide, 0.01-10wt.% epoxidized vinyl monomer and 0-30wt.% said copolymerizable vinyl monomer, and 1-60 pts.wt. inorg. filler is compounded with 0.01-3 pts.wt. crystallization accelerator (e.g. calcium acetate).
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