METAL CARBOXYLATES OF ALKYLENE BIS-PHENOL ALKONIC ACIDS USEFUL AS ADDITIVES FOR FUELS AND LUBRICANTS
    71.
    发明申请
    METAL CARBOXYLATES OF ALKYLENE BIS-PHENOL ALKONIC ACIDS USEFUL AS ADDITIVES FOR FUELS AND LUBRICANTS 审中-公开
    作为燃料和润滑剂的添加剂使用的亚苄基双酚A碱金属的金属羧酸

    公开(公告)号:WO1993021143A1

    公开(公告)日:1993-10-28

    申请号:PCT/US1993003210

    申请日:1993-04-05

    Abstract: This invention relates to metal salts of the general formula (I) A M , wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of formula (II), wherein T is selected from the group consisting of (V) or (VI) wherein each R is independently selected from O and OR wherein R is H or alkyl and each t is independently 0 or 1, wherein each Ar is independently an aromatic group of from 4 to about 30 carbon atoms having from 0 to 3 optional substituents selected from the group consisting of polyalkoxyalkyl, lower alkoxy, nitro, halo or combinations of two or more of said optional substituents, or an analog of such an aromatic group, wherein T is as hereinbefore defined, each R is independently alkyl, alkenyl or aryl having at least 8 carbon atoms, R is H or a hydrocarbyl group, R and R are each independently H or a hydrocarbyl group, each m is independently an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, (OR )bOH or O wherein each R is independently a divalent hydrocarbyl group and b is a number ranging from 1 to about 30 and c ranges from 0 to about 3 with the proviso that when t in Formula (II) = 0, or when T is Formula (V), then c is not O provided that the sum of m, c and t does not exceed the unsatisfied valences of the corresponding Ar. Additive concentrates for preparing lubricants and fuels other than two-cycle engine lubricants and fuel compositions as well as lubricating compositions and fuel compositions other than those for two-cycle engines are also disclosed.

    Abstract translation: 本发明涉及通式(I)的化合物,其中M表示一个或多个金属离子,y是全部M的总价,A表示一个或多个含阴离子的基团, 总共约有y个单独的阴离子部分和每个含阴离子的基团是式(II)的基团,其中T选自(V)或(VI),其中每个R 5独立地选自O - 和OR 6,其中R 6是H或烷基,并且各t独立地为0或1,其中每个Ar独立地为具有0至3个选自以下的任选取代基的4至约30个碳原子的芳族基团: 由多烷氧基烷基,低级烷氧基,硝基,卤素或两个或更多个所述任选取代基的组合组成的组,或这种芳基的类似物,其中T如上文所定义,每个R独立地为烷基,烯基或芳基, 至少8个碳原子,R 1是H或烃基,R 2和R 3各自独立地 每个m独立地为1至约10的整数,x为0至约8,Z各自独立地为OH,(OR 4)bOH或O - ,其中每个R 4为独立的二价烃基,b为1〜30的数,c为0〜约3,条件是当式(II)中的t = 0时,或当T为式(Ⅴ)时, ,则c不为O,条件是m,c和t之和不超过相应Ar的不饱和化合价。 还公开了用于制备除二循环发动机润滑剂和燃料组合物以外的润滑剂和燃料的添加剂浓缩物以及除二循环发动机以外的润滑组合物和燃料组合物。

    OVERBASED MAGNESIUM DEPOSIT CONTROL ADDITIVE FOR RESIDUAL FUEL OILS
    73.
    发明申请
    OVERBASED MAGNESIUM DEPOSIT CONTROL ADDITIVE FOR RESIDUAL FUEL OILS 审中-公开
    用于残留燃料油的超级磁体沉积控制添加剂

    公开(公告)号:WO99051707A1

    公开(公告)日:1999-10-14

    申请号:PCT/US1999/004245

    申请日:1999-02-25

    Abstract: An overbased magnesium composition deposit control additive for residual fuel oils and turbine fuels is an overbased magnesium sulfonate, carboxylate or phanate or mixtures thereof containing at least 14 % and upwards to about 18 % by weight of magnesium and containing a succinic anhydride and lower carboxylic acid co-promoter reaction product. The additive when added to fuel oils, such as residual fuel oils containing high asphaltenes, reduces, if not eliminates, magnesium/asphaltene deposits or sediment and the consequential plugging of filters. The additive also reduces, if not eliminates, vanadium caused corrosion in the turbine. The invention is also the process for preparing the overbased composition or deposit control additive, wherein the overbasing reaction incorporates the combination of a lower carboxylic acid, preferably acetic acid and a succinic anhydride, preferably dodecenyl succinic anhydride (DDSA), as the co-promoter.

    Abstract translation: 用于残余燃料油和涡轮机燃料的高碱性镁组合物沉积物控制添加剂是含有至少14重量%至约18重量%的镁并含有琥珀酸酐和低级羧酸的高碱性磺酸镁,羧酸盐或其盐或其混合物 共促进剂反应产物。 当添加到燃料油中的添加剂,例如含有高沥青质的残余燃料油,减少(如果不消除)镁/沥青质沉积物或沉淀物以及由此导致的过滤器堵塞。 该添加剂还减少了如果不消除,钒在涡轮机中引起腐蚀。 本发明也是制备高碱性组合物或沉积物控制添加剂的方法,其中高碱性反应包括低级羧酸,优选乙酸和琥珀酸酐,优选十二碳烯基琥珀酸酐(DDSA)的组合,作为助促进剂 。

    Colorless petroleum marker dyes
    78.
    发明申请
    Colorless petroleum marker dyes 审中-公开
    无色石油标记染料

    公开(公告)号:US20020038064A1

    公开(公告)日:2002-03-28

    申请号:US09954373

    申请日:2001-09-17

    CPC classification number: C10L1/003 C10L1/1855 C10L1/191 C10L1/202 C10L1/205

    Abstract: A composition comprising a liquid petroleum product and a colorless marker compound in an amount that is not detectable visually, and a method for marking a liquid petroleum product with a colorless marker compound.

    Abstract translation: 一种包含液体石油产品和无色标记化合物的组合物,其量不可视觉地检测,以及用无色标记化合物标记液体石油产品的方法。

    Overbased magnesium deposit control additive for residual fuel oils
    79.
    发明授权
    Overbased magnesium deposit control additive for residual fuel oils 失效
    用于残余燃料油的高碱性镁沉积物控制添加剂

    公开(公告)号:US06197075B1

    公开(公告)日:2001-03-06

    申请号:US09054005

    申请日:1998-04-02

    Abstract: An overbased magnesium composition deposit control additive for residual fuel oils and turbine fuels is an overbased magnesium sulfonate, carboxylate or phenate or mixtures thereof containing at least 14% and upwards to about 18% by weight of magnesium and containing a succinic anhydride and lower carboxylic acid co-promoter reaction product. The additive when added to fuel oils, such as residual fuel oils containing high asphaltenes, reduces, if not eliminates, magnesium/asphaltene deposits or sediment and the consequential plugging of filters. The additive also reduces, if not eliminates, vanadium caused corrosion in the turbine. The invention is also the process for preparing the overbased composition or deposit control additive, wherein the overbasing reaction incorporates the combination of a lower carboxylic acid, preferably acetic acid and a succinic anhydride, preferably dodecenyl succinic anhydride (DDSA), as the co-promoter.

    Abstract translation: 用于残余燃料油和涡轮机燃料的高碱性镁组合物沉积物控制添加剂是高碱性磺酸镁,羧酸盐或酚盐或其混合物,其含有至少14重量%至约18重量%的镁并含有琥珀酸酐和低级羧酸 共促进剂反应产物。 当添加到燃料油中的添加剂,例如含有高沥青质的残余燃料油,减少(如果不消除)镁/沥青质沉积物或沉淀物以及由此导致的过滤器堵塞。 该添加剂还减少了如果不消除,钒在涡轮机中引起腐蚀。 本发明也是制备高碱性组合物或沉积物控制添加剂的方法,其中高碱性反应包含低级羧酸,优选乙酸和琥珀酸酐,优选十二碳烯基琥珀酸酐(DDSA)的组合,作为助催化剂 。

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