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公开(公告)号:DE4120362A1
公开(公告)日:1992-12-24
申请号:DE4120362
申请日:1991-06-20
Applicant: BASF AG
Inventor: HAHN ERWIN DR , WIESENFELDT MATTHIAS DR , REICHELT HELMUT DR , GRUETTNER SABINE DR
IPC: C09B29/042 , C09B29/00 , C09B29/08 , C09B29/09
Abstract: Thiazole azo dyestuffs of the formula … … in which …… R denotes hydrogen, optionally substituted C1-C6-alkyl, halogen, optionally substituted C1-C6-alkoxy, optionally substituted C1-C6-alkylthio, optionally substituted phenylthio, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or C1-C4-alkoxycarbonyl, … R denotes cyano, C1-C4-alkanoyl, benzoyl, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or a radical of the formula -CH = T, in which T represents the radical of a CH-acidic compound, … R denotes hydrogen, optionally substituted C1-C6-alkoxy, C1-C4-alkoxycarbonyl, carbamoyl or C1-C4-mono- or dialkyl carbamoyl, … R denotes C1-C6-alkyl, optionally substituted C1-C6-alkoxy, optionally substituted C1-C4-alkoxycarbonyloxy, optionally substituted phenoxycarbonyloxy, substituted aminocarbonyloxy, optionally substituted C1-C4-alkanoyloxy, optionally substituted C1-C4-alkanoylamino, or optionally substituted phenyl, … R denotes hydrogen, optionally substituted C1-C10-alkyl or optionally substituted C3-C5-alkenyl and … R and R denote hydrogen, halogen, cyano, optionally substituted C1-C10-alkyl, optionally substituted C1-C4-alkoxy, amino or C1-C4-mono- or dialkylamino, … and their use for the dyeing or printing of textile fibres.
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公开(公告)号:DE4119341A1
公开(公告)日:1992-12-17
申请号:DE4119341
申请日:1991-06-12
Applicant: BASF AG
Inventor: HAHN ERWIN DR , DUNG BERNHARD DR , BURKHART BERND DR , TSCHANG CHUNG-JI DR
Abstract: The invention relates to the production of bright zinc-plated or zinc-alloy-plated shaped parts by the electrolytic desposition or zinc or a zinc alloy from an acidic aqueous galvanic bath containing as its essential components one or more zinc salts and optionally salts of other alloy metals, one or more conducting salts, one or more surface-active agents and one or more brighteners. Used as brighteners are compounds of the formula (I), in which R is a C1-C8 alkoxy, phenoxy, benzyloxy, amino, C1-C6 alkylamino or di(C1-C6) alkylamino group; R is a C1-C4 alkyl, phenyl or benzyl group or one of the groups given for R ; Ar is a phenyl or naphthyl group which may be substituted by one to three C1-C4 alkyl or C1-C4 alkoxy groups.
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公开(公告)号:DE3686230D1
公开(公告)日:1992-09-03
申请号:DE3686230
申请日:1986-09-30
Applicant: BASF AG
Inventor: HAHN ERWIN DR , KOWARSCH HEINRICH DR
IPC: C07D209/50
Abstract: Tetrachloro-3-imino- isoindolin-1-one (I) or its alkali metal salts (Ia) is prepd. by reacting tetrachloro-orthophthalodinitrile (II) with LiOH, NaOH and/or KOH in substantially anhydrous tert. butanol as solvent, and opt. liberating the (I) from the (Ia) formed by treatment with a dil. acid: M = Li, Na, K. Pref. the finely divided alkali metal hydroxide is used in an amt. of 1.0-5.0 mol. per mol. (III), and the tert. butanol has a water content of less than 5 wt. % and is used in an amt. of 5-15 times the wt. of (II). The reaction is carried out at 26-80 deg. C.
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公开(公告)号:DE4101380A1
公开(公告)日:1992-07-23
申请号:DE4101380
申请日:1991-01-18
Applicant: BASF AG
Inventor: HAHN ERWIN DR , GLAS GUENTHER DR , GUENTHERT PAUL DR
IPC: C07D265/22
Abstract: Production of 4H-3,1-benzoxazine-4-ones of formula (I) in which: R is hydrogen, C1-C4-alkyl, C1-C4-alkoxy, carboxyl, sulpho, nitro or halogen; R is C1-C20-alkyl, phenyl or phenylalkyl with 1 to 4 C atoms in the alkyl group, whereby a phenyl nucleus may be substituted by one or two C1-C4-alkyl groups, C1-C3-halogen alkyl groups, C1-C4-alkoxy groups, C1-C3-halogen alkoxy groups, C1-C4-alkyl mercapto groups, C1-C3-halogen alkyl mercapto groups, carboxyl groups, sulpho groups, C1-C4-alkyl sulphonyl groups, C1-C3-halogen alkyl sulphonyl groups, nitro groups or halogen atoms; and n is 1 or 2; by the reaction of isato acid anhydrides of formula (II) with acyl halides of formula (III) in which X is chlorine or bromine, by conducting the reaction at an outside temperature of 215 to 280 DEG C and causing the reaction components (II and III) to react together for at least 4 hours at this temperature.
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公开(公告)号:DE3941295A1
公开(公告)日:1991-06-20
申请号:DE3941295
申请日:1989-12-14
Applicant: BASF AG
Inventor: HAHN ERWIN DR , AUMUELLER ALEXANDER DR , REUTHER WOLFGANG DR , KRALLMANN REINHOLD , WEGERLE DIETER DR
Abstract: Process for dyeing polyamide substrates from aqueous baths with suitable dyes and also with copper complexes as light stabilisers for the dyed polyamide by using as copper complexes those of organic N-nitrosohydroxylamines.
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公开(公告)号:DE3933903A1
公开(公告)日:1991-04-18
申请号:DE3933903
申请日:1989-10-11
Applicant: BASF AG
Inventor: HAHN ERWIN DR , OSTERTAG WERNER DR , SEYBOLD GUENTHER DR
Abstract: Fluorescent pigments whose average particle size is 8 to 16 mu m and which possess apolar polymer matrices based on polymethyl methacrylate, polystyrene, polybutadiene-modified polystyrene, polycarbonate, polyvinyl chloride or polyamide and contain one or more apolar fluorescent dyes of the coumarin or perylene series.
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公开(公告)号:DE3574265D1
公开(公告)日:1989-12-21
申请号:DE3574265
申请日:1985-07-16
Applicant: BASF AG
Inventor: BERGMANN UDO DR , HAHN ERWIN DR , HANSEN GUENTER DR
IPC: C09B29/00 , C09B29/033 , C09B29/36 , D06P1/18
Abstract: Novel compounds of the general formula I I where X is hydrogen, nitro or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or hetaryl, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, R is unsubstituted or substituted alkyl or aryl, R1 is hydrogen or R2, and R2 is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl, are useful for dyeing textile fibers, in particular polyesters.
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公开(公告)号:DE3814781A1
公开(公告)日:1989-11-09
申请号:DE3814781
申请日:1988-04-30
Applicant: BASF AG
Inventor: HAHN ERWIN DR , NEUMANN PETER DR
Abstract: A process for the preparation of 2-hydroxy-4-(2'-hydroxyethoxy)benzophenones, by reacting 2,4-dihydroxybenzophenones with ethylene carbonate in the presence of a quaternary ammonium salt catalyst at elevated temperatures, and isolating the finished product from the crude reaction mixture.
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公开(公告)号:DE3660332D1
公开(公告)日:1988-07-28
申请号:DE3660332
申请日:1986-01-22
Applicant: BASF AG
Inventor: COLBERG HORST DR , HAHN ERWIN DR
Abstract: The compounds of the formula where Y is hydrogen, chlorine, bromine or nitro, Z is hydrogen, chlorine, bromine, a sulfonic ester group or unsubstituted or substituted sulfamyl, X is -O- or R is alkylene which may or may not be interrupted by oxygen or m is 0 or 1, p is 1 or 2, R1 and R2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, or aryl, or R1 and R2 together with the nitrogen form a heterocyclic structure, R3 is hydrogen or unsubstituted or substituted alkyl, R6 and R7 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkoxy or acylamino, K is a radical of a coupling component, A(-) is an anion, R4 is unsubtituted or substituted alkyl and R5 is hydrogen or C1-C4-alkyl, and the radical may furthermore be an unsubstituted or substituted piperazine radical, are useful for dyeing acid-modified fibers, leather and in particular paper.
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公开(公告)号:DE3631678A1
公开(公告)日:1988-03-24
申请号:DE3631678
申请日:1986-09-18
Applicant: BASF AG
Inventor: HENNING GEORG DR , HAHN ERWIN DR , HAUSER PETER DR , PATSCH MANFRED DR
IPC: C08K5/34 , C08K5/3412 , C08K5/3437 , C09B5/62 , C09B67/48 , C09D7/00 , C09D7/12 , C09D11/02 , C09B67/20 , C09D17/00
Abstract: A tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide pigment which contains not less than 85% by weight of the tetrachloro compound of the formula which is present to the extent of not less than 95% by weight in the beta -modification and which, in an X-ray spectrum, exhibits 2(-) CuK alpha main lines at 9.0 DEG , 13.3 DEG , 15.0 DEG , 16.8 DEG , 19.1 DEG , 21.5 DEG , 24.2 DEG , 25.4 DEG , 26.5 DEG , 27.0 DEG and 27.5 DEG . In finishes, the pigment gives very brilliant colorations which are very highly lightfast and fast to weathering and which, upon weathering, neither bleach nor darken up.
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