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公开(公告)号:FI910252A0
公开(公告)日:1991-01-17
申请号:FI910252
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , DE CLERCQ ARNOLD , RIEBELING ULRICH
IPC: B01J13/00 , C09K23/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , C07C
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:AU603258B2
公开(公告)日:1990-11-08
申请号:AU2220188
申请日:1988-09-14
Applicant: BASF AG
Inventor: AUHORN WERNER , DEGEN HANS-JUERGEN , HOEHR LOTHAR , RIEBELING ULRICH
Abstract: Process for improving the printability of paper by a single- or two-sided application of aqueous coating materials consisting of a) 100 parts by weight of a finely dispersed pigment b) 5 to 70 parts by weight (based on solids) of a cationic aqueous polymer dispersion of a paper size and c) 0.01 to 10 parts by weight of a surfactant which interferes with the formation of the surface sizing and/or of a polymeric dispersant to the surface of the paper in a quantity of 0.5 to 4 g/m and drying the coated paper.
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公开(公告)号:AU594492B2
公开(公告)日:1990-03-08
申请号:AU7685587
申请日:1987-08-13
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F220/12 , C08F2/22 , C08F2/24 , C08F220/10 , C08F220/18 , C08F220/42 , C08F251/00 , C08F290/00 , D21H17/28 , D21H17/37 , D21H17/55 , D21H21/16 , D21H3/46 , C08F2/44 , C08F220/56
Abstract: Sizes for paper are based on finely divided aqueous dispersions of copolymers which are obtainable by copolymerization of from 10 to 56 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric, saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers by an emulsion polymerization method in 100 parts by weight of an aqueous solution of from 1.7 to 25% by weight of a degraded starch having a viscosity eta i of from 0.12 to 0.50 dl/g, at from 40 DEG to 100 DEG C. in the presence of a peroxide-containing initiator.
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公开(公告)号:DE3730887A1
公开(公告)日:1989-03-23
申请号:DE3730887
申请日:1987-09-15
Applicant: BASF AG
Inventor: AUHORN WERNER , DEGEN HANS-JUERGEN DR , HOEHR LOTHAR DR , RIEBELING ULRICH
Abstract: Process for improving the printability of paper by a single- or two-sided application of aqueous coating materials consisting of a) 100 parts by weight of a finely dispersed pigment b) 5 to 70 parts by weight (based on solids) of a cationic aqueous polymer dispersion of a paper size and c) 0.01 to 10 parts by weight of a surfactant which interferes with the formation of the surface sizing and/or of a polymeric dispersant to the surface of the paper in a quantity of 0.5 to 4 g/m and drying the coated paper.
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公开(公告)号:DE3702712A1
公开(公告)日:1988-08-11
申请号:DE3702712
申请日:1987-01-30
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN DR , REICHEL FRITZ DR , RIEBELING ULRICH , HOEHR LOTHAR DR
IPC: C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H19/24 , D21H21/16 , D21H3/46 , C08L33/06
Abstract: Sizing agents for paper are based on finely divided aqueous dispersions of copolymers obtainable by copolymerizing from 40 to 140 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, the weight percentages (a), (b) and (c) always adding up to 100, in the manner of an emulsion polymerization in 100 parts by weight of an aqueous solution containing in solution from 2.7 to 15% by weight of a degraded starch having a viscosity ni from 0.04 to less than 0.12 dl/g at from 40 DEG to 100 DEG C. in the presence of a peroxide initiator.
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公开(公告)号:FI880037A
公开(公告)日:1988-07-31
申请号:FI880037
申请日:1988-01-06
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H19/24 , D21H21/16 , C08F
Abstract: Sizing agents for paper are based on finely divided aqueous dispersions of copolymers obtainable by copolymerizing from 40 to 140 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, the weight percentages (a), (b) and (c) always adding up to 100, in the manner of an emulsion polymerization in 100 parts by weight of an aqueous solution containing in solution from 2.7 to 15% by weight of a degraded starch having a viscosity ni from 0.04 to less than 0.12 dl/g at from 40 DEG to 100 DEG C. in the presence of a peroxide initiator.
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公开(公告)号:AU7685587A
公开(公告)日:1988-02-18
申请号:AU7685587
申请日:1987-08-13
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F220/12 , C08F2/22 , C08F2/24 , C08F220/10 , C08F220/18 , C08F220/42 , C08F251/00 , C08F290/00 , D21H17/28 , D21H17/37 , D21H17/55 , D21H21/16 , D21H3/46 , C08F2/44 , C08F220/56
Abstract: Sizes for paper are based on finely divided aqueous dispersions of copolymers which are obtainable by copolymerization of from 10 to 56 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric, saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers by an emulsion polymerization method in 100 parts by weight of an aqueous solution of from 1.7 to 25% by weight of a degraded starch having a viscosity eta i of from 0.12 to 0.50 dl/g, at from 40 DEG to 100 DEG C. in the presence of a peroxide-containing initiator.
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公开(公告)号:FI873236A
公开(公告)日:1988-02-15
申请号:FI873236
申请日:1987-07-23
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F220/12 , C08F2/22 , C08F2/24 , C08F220/10 , C08F220/18 , C08F220/42 , C08F251/00 , C08F290/00 , D21H17/28 , D21H17/37 , D21H17/55 , D21H21/16 , C08F
Abstract: Sizes for paper are based on finely divided aqueous dispersions of copolymers which are obtainable by copolymerization of from 10 to 56 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric, saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers by an emulsion polymerization method in 100 parts by weight of an aqueous solution of from 1.7 to 25% by weight of a degraded starch having a viscosity eta i of from 0.12 to 0.50 dl/g, at from 40 DEG to 100 DEG C. in the presence of a peroxide-containing initiator.
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公开(公告)号:FI873312A
公开(公告)日:1988-02-02
申请号:FI873312
申请日:1987-07-29
Applicant: BASF AG
Inventor: WEBERNDOERFER VOLKMAR , FREUDENBERG ENRIQUE , DEGEN HANS-JUERGEN , RIEBELING ULRICH
Abstract: Engine sizes for paper are based on aqueous emulsions of C14-C20-alkyl diketenes and cationic copolymers of (a) from 40 to 99% by weight of acrylamide and/or methacrylamide, (b) from 1 to 40% by weight of an unsubstituted or substituted N-vinylimidazoline and (c) from 0 to 30% by weight of an unsubstituted or substituted N-vinylimidazole.
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公开(公告)号:NO880391D0
公开(公告)日:1988-01-29
申请号:NO880391
申请日:1988-01-29
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H19/24 , D21H21/16 , D21H
Abstract: Sizing agents for paper are based on finely divided aqueous dispersions of copolymers obtainable by copolymerizing from 40 to 140 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, the weight percentages (a), (b) and (c) always adding up to 100, in the manner of an emulsion polymerization in 100 parts by weight of an aqueous solution containing in solution from 2.7 to 15% by weight of a degraded starch having a viscosity ni from 0.04 to less than 0.12 dl/g at from 40 DEG to 100 DEG C. in the presence of a peroxide initiator.
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