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公开(公告)号:ES2057347T3
公开(公告)日:1994-10-16
申请号:ES90124486
申请日:1990-12-18
Applicant: BASF AG
Inventor: KSOLL PETER DR , HAHN ERWIN DR , WITTMER PETER , HOHMANN ANDREAS DR , DE CLERQ ARNOLD DR , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C09K23/00 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:DE3874622D1
公开(公告)日:1992-10-22
申请号:DE3874622
申请日:1988-06-08
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE DR , WITTMER PETER , HOHMANN ANDREAS DR , BECHTOLSHEIMER HANS-HEINRICH D
Abstract: Prodn. of carboxylic acid halides of formula RCOX (I), where R= an organic gp. contg. more than 7 C atoms and X=Cl or Br, is effected by (a) reacting RCOOH with a P halide, (b) treating the reaction mixt. with a carboxamide hydrochloride or hydrobromide (II)which is immiscible with (I), and (c) sepg. the (I)-contg. phase. Pref. step (a) is effected by reacting a 9-29C fatty acid with PCl3. Step (b) is effected by adding an amide (esp. DMF) to the reaction mixt. and then introducing HCl.
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公开(公告)号:NO910199A
公开(公告)日:1991-07-19
申请号:NO910199
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH
IPC: B01F17/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , C09K15/06 , C09K15/22 , D21H21/16
CPC classification number: C07D315/00 , C07C45/90 , D21H17/06 , D21H17/07 , D21H17/17
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公开(公告)号:DE3719640A1
公开(公告)日:1988-12-29
申请号:DE3719640
申请日:1987-06-12
Applicant: BASF AG
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公开(公告)号:DE10349727A1
公开(公告)日:2005-05-25
申请号:DE10349727
申请日:2003-10-23
Applicant: BASF AG
Inventor: DYLLICK-BRENZINGER RAINER , KESLER THOMAS , GUENTHERBERG NORBERT , WITTMER PETER , ETTL ROLAND
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公开(公告)号:NO173863C
公开(公告)日:1994-02-16
申请号:NO910199
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ DE ARNOLD , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C09K23/00 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , D21H21/16
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:FI90527B
公开(公告)日:1993-11-15
申请号:FI882785
申请日:1988-06-10
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE , WITTMER PETER , HOHMANN ANDREAS , BECHTOLSHEIMER HANS-HEINRICH
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公开(公告)号:AT80606T
公开(公告)日:1992-10-15
申请号:AT88109086
申请日:1988-06-08
Applicant: BASF AG
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公开(公告)号:DE4001237A1
公开(公告)日:1991-07-25
申请号:DE4001237
申请日:1990-01-18
Applicant: BASF AG
Inventor: KSOLL PETER DR , HAHN ERWIN DR , WITTMER PETER , HOHMANN ANDREAS DR , DE CLERCQ ARNOLD DR , RIEBELING ULRICH
IPC: C09K23/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:DE2927118A1
公开(公告)日:1981-01-08
申请号:DE2927118
申请日:1979-07-05
Applicant: BASF AG
Inventor: FREY GUENTER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , WITTMER PETER , POSCHMANN FRANZ DIPL CHEM DR , WULZ KLAUS DIPL CHEM DR , MUELLER RICHARD DIPL CHEM DR
Abstract: Mixt. of 0.5-10 pts. wt. trimethylamine per 100 pts. wt. of another tert. amine is used as the tert. amine in fatty alkyl diketene, (I), prepn. by (a) reacting fatty acid halides with tert. amines in inert, organic solvents at up to 90 deg.C; (b) washing out the reaction mixt. with water; (c) separating the organic phase; and (d) recovering (I) by organic solvent evaporation. Aq. emulsions of (I), or mixts. of (I), are used as bulk sizing agents for paper, e.g. in 0.05-0.15% concn., calculated as solids, w.r.t. pulp. Trimethylamine addn. suppresses viscosity increase during amine addn. and increases purity of (I).
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