公开(公告)号：WO2015067657A1

公开(公告)日：2015-05-14

申请号：PCT/EP2014/073812

申请日：2014-11-05

Applicant: BASF SE

Inventor： VAUTRAVERS, Nicolas ,  TELES, Joaquim Henrique ,  PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich

IPC: C07D313/04

CPC classification number: C07D313/04 ,  B01J27/1806 ,  B01J29/7088 ,  B01J31/0209 ,  C07B41/12

Abstract: A process for the oxidation of an organic carbonyl compound comprising reacting the compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material and at least one potassium salt.

Abstract translation: 一种用于氧化有机羰基化合物的方法，包括任选地在溶剂存在下使化合物与过氧化氢在含有含锡沸石材料和至少一种钾盐的催化剂存在下反应。

公开(公告)号：WO2015059171A1

公开(公告)日：2015-04-30

申请号：PCT/EP2014/072609

申请日：2014-10-22

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  LÜTZEL, Hans-Jürgen ,  TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  SEELIG, Bianca ,  URBANCZYK, Daniel ,  WEGERLE, Ulrike ,  HESSE, Michael ,  WALCH, Andreas ,  BENDIG, Volker ,  STEGMANN, Veit ,  ALTHÖFER, Henning ,  GASPAR, Boris ,  STALLMACH, Frank ,  PUSCH, Anne Kristin

IPC: B01J29/89 ,  B01J29/035 ,  B01J35/10 ,  B01J37/00 ,  C01B39/08 ,  B01J37/10 ,  B01J39/14 ,  B01J20/10 ,  B01J35/02

CPC classification number: B01J29/89 ,  B01J20/183 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3085 ,  B01J29/035 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0018 ,  B01J37/10 ,  B01J39/14 ,  B01J2229/183 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/085 ,  C01B39/40

Abstract: The present invention relates to A process for the production of a molding, comprising (I) providing a zeolitic material; (II) mixing the zeolitic material provided in step (I) with one or more binders; (III) kneading of the mixture obtained in step (II); (IV) molding of the kneaded mixture obtained in step (III) to obtain one or more moldings; (V) drying of the one or more moldings obtained in step (IV); and (VI) calcining of the dried molding obtained in step (V); wherein the zeolitic material provided in step (I) displays a water adsorption ranging from 1 to 15 wt.-% when exposed to a relative humidity of 85%, as well as to a molding obtainable or obtained according to the inventive process in addition to a molding per se and to their respective use.

Abstract translation: 本发明涉及一种用于生产模制品的方法，包括（I）提供沸石材料; （II）将步骤（I）中提供的沸石材料与一种或多种粘合剂混合; （III）捏合步骤（II）中获得的混合物; （IV）成型步骤（III）中获得的捏合混合物以获得一种或多种模制品; （V）干燥步骤（IV）中获得的一种或多种模制品; 和（VI）煅烧步骤（V）中获得的干燥模塑物; 其中步骤（I）中提供的沸石材料当暴露于85％的相对湿度时显示出1至15重量％的水吸附，以及根据本发明方法获得或获得的模制物，除了 成型本身及其各自的用途。

公开(公告)号：WO2015040593A1

公开(公告)日：2015-03-26

申请号：PCT/IB2014/064724

申请日：2014-09-22

Applicant: BASF SE ,  BASF CHINA COMPANY LIMITED

Inventor： MAURER, Stefan ,  MATTENHEIMER, Hendrik ,  MÜLLER, Ulrich

IPC: B01J20/34 ,  B01D11/02 ,  B01J20/22 ,  B01J20/282

CPC classification number: C07C51/487 ,  B01D11/02 ,  B01J20/226 ,  B01J20/3085 ,  C07C51/47 ,  C07C63/331 ,  C07C63/307 ,  C07C63/26 ,  C07C57/15

Abstract: The present invention relates to a process for the recovery of an at least bidentate organic compound comprised in a porous metal-organic framework material, the material comprising the at least bidentate organic compound coordinated to at least one metal ion, the process comprising the steps of (a) treating the metal-organic framework material with an acidic or alkaline liquid; (b) optionally separating off solid residue; and (c) isolating the at least bidentate organic compound.

Abstract translation: 本发明涉及回收包含在多孔金属 - 有机骨架材料中的至少二齿有机化合物的方法，所述材料包含与至少一种金属离子配位的至少二齿有机化合物，该方法包括以下步骤： （a）用酸性或碱性液体处理金属 - 有机骨架材料; （b）任选分离固体残余物; 和（c）分离出至少二齿有机化合物。

公开(公告)号：WO2015032851A2

公开(公告)日：2015-03-12

申请号：PCT/EP2014/068822

申请日：2014-09-04

Applicant: BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： FEYEN, Mathias ,  RUETZ, Roger ,  MÜLLER, Ulrich ,  GAAB, Manuela ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  WEISS, Ralf ,  GIES, Hermann ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  YILMAZ, Bilge ,  DE BAERDEMAECKER, Trees

IPC: C01B37/02

CPC classification number: B01J29/035 ,  B01J29/049 ,  B01J29/06 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B33/38 ,  C04B35/16 ,  C04B2235/5409 ,  C07C1/20 ,  C07C2521/08 ,  C07C2529/00 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a pillared silicate compound comprising a layered silicate structure and bridging silicon atoms located between adjacent silicate layers of the silicate structure, wherein said bridging silicon atoms form at least one covalent bond to each of the adjacent silicate layers, said process comprising (1) providing one or more layered silicates; (2) adding said one or more layered silicates to a solvent system, wherein the resulting mixture has a pH of 5 or less; and (3) subjecting the mixture obtained in step (2) to solvothermal conditions; wherein no silicon-containing compound according to formula (I) R4-mSi[-(SiR2)n-R]m (I) is used at any point of the process up to and including step (3), wherein m is 1, 2, 3, or 4, and n is an integer greater than or equal to 0, wherein when n is equal to 0, one or more residues R are leaving groups, and wherein none of the residues R contains Si, as well as to a pillared silicate compound per se, preferably as obtained and/or obtainable according to the inventive process as well as to the use of the inventive compounds.

Abstract translation: 本发明涉及一种制备柱状硅酸盐化合物的方法，其包括层状硅酸盐结构和位于硅酸盐结构的相邻硅酸盐层之间的桥接硅原子，其中所述桥连硅原子与相邻的每个相邻的硅酸盐层形成至少一个共价键 硅酸盐层，所述方法包括（1）提供一层或多层分层硅酸盐; （2）将一种或多种层状硅酸盐加入到溶剂体系中，其中所得混合物的pH为5或更小; 和（3）使步骤（2）中获得的混合物经历溶剂热条件; 其中在直到并包括步骤（3）的任何处理方法中，不使用根据式（I）的含硅化合物R 4-m Si [ - （SiR 2）n R] m（I），其中m为1,2， 3或4，并且n是大于或等于0的整数，其中当n等于0时，一个或多个残基R是离去基团，并且其中残基R中没有一个包含Si，以及被支化的 硅酸盐化合物本身，优选根据本发明方法获得和/或可获得，以及本发明化合物的用途。

公开(公告)号：WO2015025268A1

公开(公告)日：2015-02-26

申请号：PCT/IB2014/063967

申请日：2014-08-19

Applicant: BASF SE ,  BASF CHINA COMPANY LIMITED

Inventor： MAURER, Stefan ,  KIMURA, Riichiro ,  PARVULESCU, Andrei-Nicolae ,  SA GOMES, Pedro ,  MARX, Stefan ,  SIGGEL, Lorenz ,  MÜLLER, Ulrich

IPC: C02F1/28 ,  B01J20/26 ,  B01D15/00

CPC classification number: B01D15/00 ,  B01J20/226 ,  B01J20/28066 ,  C02F1/281 ,  C02F1/285 ,  C02F1/288 ,  C02F2101/32 ,  C02F2101/322 ,  C07C7/12 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08

Abstract: The invention relates to a method for purifying a mixture comprising at least one liquid hydro- carbon and water by at least partly separating off the at least one liquid hydrocarbon from the mixture, the method comprising the step of passing the mixture through a sorption agent comprising at least one porous metal-organic framework material, wherein the at least one metal- organic framework material comprises at least one organic compound coordinated to at least one metal ion, wherein the at least one organic compound is based on imidazole, which is unsubstituted or substituted with one or more substituents independently selected from the group consisting of C 1-6 alkyl, phenyl and benzyl. The invention further relates to the use of such metal-organic framework material for purifying the mixture.

Abstract translation: 本发明涉及通过至少部分地从混合物中分离至少一种液态烃来纯化包含至少一种液体碳氢化合物和水的混合物的方法，所述方法包括使混合物通过吸附剂的步骤，所述吸附剂包含 至少一种多孔金属 - 有机骨架材料，其中所述至少一种金属 - 有机骨架材料包含与至少一种金属离子配位的至少一种有机化合物，其中所述至少一种有机化合物是基于咪唑，其为未取代的或未取代的 被一个或多个独立地选自C 1-6烷基，苯基和苄基的取代基取代。 本发明还涉及这种金属 - 有机骨架材料用于纯化混合物的用途。

公开(公告)号：WO2015022633A1

公开(公告)日：2015-02-19

申请号：PCT/IB2014/063870

申请日：2014-08-12

Applicant: BASF SE ,  BASF CHINA COMPANY LIMITED

Inventor： WEICKERT, Mathias ,  MARX, Stefan ,  MÜLLER, Ulrich ,  ARNOLD, Lena

IPC: F17C5/00 ,  C10L3/06 ,  B01J20/20 ,  B60K15/06

CPC classification number: B01J20/20 ,  B01J20/08 ,  B01J20/103 ,  B01J20/18 ,  B01J20/226 ,  B01J20/26 ,  B01J20/28052 ,  B60K15/03006 ,  B60K15/07 ,  B60K2015/0638 ,  C10L3/06 ,  C10L2290/567 ,  F17C11/005 ,  F17C11/007 ,  Y02E60/321

Abstract: Sorption store (1) for the storage of a gas (16) comprising at least two gas adsorbent media disposed within an at least one vessel, said at least two gas adsorbent media distinguishable from each other by different adsorption capacities (30), said adsorption capacities (30) defined by the ratio of the mass of the adsorbed gas (16) to the mass of the adsorbent medium, for the stored gas (16) at equal adsorption conditions, said adsorption conditions defined by temperature (20), pressure (32) and gas phase composition.

Abstract translation: 用于存储气体（16）的吸附储存器（1），包括至少两个气体吸附剂介质，所述至少两个气体吸附介质设置在至少一个容器内，所述至少两个气体吸附介质通过不同的吸附容量彼此区分开，所述吸附 由吸附气体（16）的质量与吸附剂介质质量之比（在相等的吸附条件下）为储存气体（16）所定义的容量（30），所述吸附条件由温度（20），压力 32）和气相组成。

公开(公告)号：WO2015010994A1

公开(公告)日：2015-01-29

申请号：PCT/EP2014/065256

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim Henrique ,  SEELIG, Bianca ,  KAMPE, Philip ,  WEBER, Markus ,  RESCH, Peter ,  BARTOSCH, Christian ,  RIEDEL, Dominic ,  URBANCZYK, Daniel ,  SCHRÖDER, Alexander ,  WEGERLE, Ulrike

IPC: B01J29/90 ,  B01J29/89 ,  B01J37/06 ,  C07D301/12 ,  C07D303/04 ,  B01J38/48 ,  B01J37/10 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J29/90 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  B01J38/02 ,  B01J38/06 ,  B01J38/48 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/584

Abstract: The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300 °C; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300 °C.

Abstract translation: 本发明涉及一种用于再生包含含钛沸石的催化剂的方法，所述催化剂已用于制备烯烃氧化物并沉积有磷酸盐的方法中，所述再生方法包括以下步骤： （a）将反应混合物与催化剂分离，（b）用液体水系洗涤由（a）获得的催化剂; （c）任选地在低于300℃的温度下将包含惰性气体的气流中的（b）得到的催化剂干燥; （d）在至少300℃的温度下，将由（c）得到的催化剂在包含氧的气​​流中煅烧。

公开(公告)号：WO2015010992A1

公开(公告)日：2015-01-29

申请号：PCT/EP2014/065249

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： TELES, Joaquim Henrique ,  SEELIG, Bianca ,  RIEDEL, Dominic ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  SCHRÖDER, Alexander ,  WEIDENBACH, Meinolf ,  WITZL, Werner

IPC: B01J29/89 ,  B01J29/70 ,  B01J37/02 ,  C07D301/12 ,  C07D301/36 ,  C07D303/04 ,  B01J35/00 ,  B01J37/10

CPC classification number: C07D301/36 ,  B01J23/06 ,  B01J27/18 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/10 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/52

Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, dissolved potassium dihydrogen phosphate, and optionally propane; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions; (iii) removing an effluent stream from the epoxidation reactor; wherein the concentration of the dissolved potassium dihydrogen phosphate in the liquid feed stream is at least 10 % of the solubility limit of the potassium dihydrogen phosphate in the liquid feed stream.

Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，溶解的磷酸二氢钾和任选的丙烷的液体进料流; （ii）将（i）中提供的液体进料流送入包含包含结构类型MWW的钛沸石的催化剂的环氧化反应器中，并使液体进料流进行环氧化反应条件; （iii）从环氧化反应器中除去流出物流; 其中所述液体进料流中溶解的磷酸二氢钾的浓度为所述液体进料流中磷酸二氢钾的溶解度极限的至少10％。

公开(公告)号：WO2014199348A2

公开(公告)日：2014-12-18

申请号：PCT/IB2014/062202

申请日：2014-06-13

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： FEYEN, Mathias ,  SPANNHOFF, Kirsten ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  BILGE, Yilmaz

CPC classification number: C07C1/20 ,  B01J29/049 ,  B01J29/061 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/78 ,  B01J29/7815 ,  B01J29/89 ,  B01J29/90 ,  B01J37/0201 ,  B01J38/12 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/08 ,  C01B39/085 ,  C07C2529/70 ,  C07C2529/89 ,  Y02P20/584 ,  C07C11/167

Abstract: The present invention relates to a process for the preparation of butadiene comprising (i) providing a gas stream G- comprising ethanol; (ii) contacting the gas stream G- provided in (i) with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene; wherein the catalyst comprises a crystalline material supporting one or more catalytically active metals M, as well as to the use of the crystalline material supporting one or more catalytically active metals M.

Abstract translation: 本发明涉及一种制备丁二烯的方法，包括（i）提供包含乙醇的气流G-; （ii）使（i）中提供的气流G-与催化剂接触，从而获得包含丁二烯的气流G-2; 其中所述催化剂包含支撑一种或多种催化活性金属M的结晶物质，以及支持一种或多种催化活性金属M的结晶物质的用途。

公开(公告)号：WO2014122150A1

公开(公告)日：2014-08-14

申请号：PCT/EP2014/052203

申请日：2014-02-05

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  LÜTZEL, Hans-Jürgen ,  UHL, Georg ,  BAYER, Robert ,  VOGELSANG, Regina ,  SCHLOSSER, Robert ,  RUSLIM, Franky ,  CZAJKA, Pawel

IPC: C01B39/12 ,  C01B37/00

CPC classification number: C01B39/12 ,  B01J29/86 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  C01B37/007 ,  C01B39/46 ,  C01B39/48 ,  C01P2002/70 ,  C01P2006/12 ,  C01P2006/90

Abstract: A process for preparing an aluminum-free boron containing zeolitic material comprising the framework structure MWW (BMWW), comprising (a) hydrothermally synthesizing the BMWW from a synthesis mixture containing water, a silicon source, a boron source, and an MWW template compound obtaining the BMWW in its mother liquor, the mother liquor having a pH above 9; (b) adjusting the pH of the mother liquor, obtained in (a) and containing the BMWW, to a value in the range of from 6 to 9; (c) separating the BMWW from the pH- adjusted mother liquor obtained in (b) by filtration in a filtration device.

Abstract translation: 一种制备包含框架结构MWW（BMWW）的无铝含硼沸石材料的方法，包括（a）从含水的合成混合物，硅源，硼源和MWW模板化合物水热合成BMWW，获得 宝马在母液中，母液pH值高于9; （b）将（a）中获得并含有BMWW的母液的pH调节至6至9的值; （c）通过在过滤装置中过滤将BMWW与（b）中得到的经pH调节的母液分离。