公开(公告)号：JPH0959125A

公开(公告)日：1997-03-04

申请号：JP21598595

申请日：1995-08-24

Applicant: KAO CORP

Inventor： IHARA TAKESHI ,  YANO SHINJI ,  KITA KATSUMI

IPC: A61K8/72 ,  A61K8/18 ,  A61K8/25 ,  A61K8/29 ,  A61K8/89 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q1/12 ,  C08L83/12 ,  C09C3/12 ,  A61K7/00 ,  A61K7/02

Abstract: PROBLEM TO BE SOLVED: To obtain a powder for water-repellent cosmetics low in treating temperatures and excellent in cosmetic performances by using a specific carboxyl group-modified organo(poly)siloxane as a surface-treating agent for the powder. SOLUTION: This powder is treated with a carboxyl group-modified organo(poly)siloxane whose at least one silicon atom is modified with a group of formula I (R is a 1-20C alkylene; R is a 1-4C alkylene; M is H, a monovalent cation; (a) is 0, 1). As the carboxyl group-modified organo(poly)siloxane, a compound of formula II (R -R are each an alkyl, an alkoxy, phenyl; at least one of X, b number of Y and Z is the group of formula I and the rests are each an alkyl, alkoxy, phenyl; (b) is 0-1,000) is preferred. The powder is, for example, talc, kaolin, sericite, mica, zinc white, titania, barium sulfate or iron oxide. The prepared cosmetic is excellent in application feeling such as spreadability on, adhesion to and smoothness of shin.

公开(公告)号：JPH093018A

公开(公告)日：1997-01-07

申请号：JP15419395

申请日：1995-06-21

Applicant: KAO CORP

Inventor： KITA KATSUMI ,  KAMIYA HIROSHI

IPC: A61K8/00 ,  A61K8/42 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q19/10 ,  B01F17/22 ,  B01F17/38 ,  C07C231/02 ,  C07C233/18 ,  C10M105/68 ,  A61K7/075 ,  A61K7/50

Abstract: PURPOSE: To obtain a new unsaturated fatty acid amide becoming a lyotropic liquid crystal in the presence of water at room temperature, excellent in lubrici ty, compatibility with solvents and homogeneous dispersibility in water, etc., thus useful as a base for hair or skin cosmetics, emulsifier or lubricant. CONSTITUTION: This new compound is expressed by formula I (R is a 5-24C alkenyl such as oleoyl or elaidoyl), e.g. N-tris(hydroxymethyl)methyl oleamide. The compound of formula I is obtained by reaction of a compound of the formula RCOOH with tris(hydroxymethyl)aminomethane in an inert solvent or in the absence of any solvent at 100-250 deg.C (esp. 130-220 deg.C) to form a compound of formula II, which is then hydrolyzed in a mixed solvent of a l-6C lower alcohol, and water at 50-150 deg.C (esp. 70-120 deg.C).

公开(公告)号：JPH08104663A

公开(公告)日：1996-04-23

申请号：JP24104794

申请日：1994-10-05

Applicant: KAO CORP

Inventor： FUJII YASUYUKI ,  FURUGAKI HISAKAZU ,  KITA KATSUMI

IPC: A61K8/30 ,  A61K8/37 ,  C07C67/03 ,  C07C67/08 ,  C07C67/14 ,  C07C69/025 ,  C07C69/30 ,  A61K7/00

Abstract: PURPOSE: To easily produce a glycerol derivative useful as a cosmetic oil having low stickiness at a low cost by reacting a monohydric alcohol with an epihalohydrin in the presence of a base and reacting the resultant glycerol diether compound with a fatty acid (or its derivative). CONSTITUTION: The objective compound of formula III is produced by reacting (A) a compound of formula, R1 -OH [R1 is a 1-24C (branched)alkyl, an alkenyl or a cycloalkyl] with (B) a compound of formula I (X is a halogen) in the presence of (C) a base such as alkali metal hydroxide, carbonate, hydride or alkylate and reacting the resultant compound of formula II with (D) a compound of formula, R2 -COOR3 [R2 is a 1-23C (branched)alkyl or an alkenyl; R3 is H, CH3 or C2 H5 ] or a compound of formula, R2 -COCI. The amounts of the components C and A are preferably 0.5-10 times equivalent and 1-1,000 times equivalent based on the component B, respectively.

公开(公告)号：JPH0859532A

公开(公告)日：1996-03-05

申请号：JP14725595

申请日：1995-06-14

Applicant: KAO CORP

Inventor： HASHIZUME NAOMICHI ,  KAMIYA HIROSHI ,  KITA KATSUMI

IPC: C07C41/03 ,  C07C43/13

Abstract: PURPOSE: To efficiently produce the subject compound useful as a base, an emulsifying agent, etc., for fragrant cosmetics or cosmetics by reacting a polyhydric alcohol ester of a fatty acid as a raw material with an epoxy compound and further carrying out the hydrolysis. CONSTITUTION: This method for producing an etherified polyhydric alcohol of formula 4 G is a residue after removing H atoms of all OH groups in a polyhydric alcohol having >=3 OH groups; A is formula 5 or 6 [R is R' or CH2 OR' (R' is a 1-36C alkyl or alkenyl)]; x and y are each >=1 so as to provide z of the sum total thereof; z is the number of hydroxyl groups in the polyhydric alcohol in G} comprises reacting a polyhydric alcohol ester of formula 1 [B is H or a 1-11C acyl; at least one H and at least one acyl group are contained in (z) × B] with an epoxy compound of formula 2, providing an etherified polyhydric alcohol ester of a fatty acid of formula 3 [at least one of (y) ×B is an acyl] and then hydrolyzing the resultant ester. The content of one mol adduct of the epoxy compound can be raised even when, e.g. the excessive ratio of the polyhydric alcohol based on the epoxy compound is reduced.

公开(公告)号：JPH06228079A

公开(公告)日：1994-08-16

申请号：JP1534093

申请日：1993-02-02

Applicant: KAO CORP

Inventor： UNO MITSURU ,  KITSUKI TOMOHITO ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI ,  IMAI KAZUYASU

IPC: A61K8/00 ,  A61K8/40 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  C07C303/22 ,  C07C309/14 ,  C08L71/02 ,  C11D1/92 ,  A61K7/075 ,  A61K7/08 ,  A61K7/48 ,  A61K7/50

Abstract: PURPOSE:To obtain a new compound excellent in humectancy and moist feeling and useful for cosmetics and cleansing agents. CONSTITUTION:A compound of formula I [A is (OH-substituted) 2-12C alkylene; R and R are (OH-substituted) 1-12C alkyl or 2-12C alkenyl], e.g. 1-hydroxy-2- sulfoethyl-N,N-dimethyl-N-hydroxyethyl-N-methanealminium hydroxide inner salt. Furthermore, the compound of formula I is obtained by reacting a compound of formula II with a compound of formula III (X is halogen; M is H or cation).

公开(公告)号：JPH06228070A

公开(公告)日：1994-08-16

申请号：JP1533993

申请日：1993-02-02

Applicant: KAO CORP

Inventor： KITSUKI TOMOHITO ,  UNO MITSURU ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI

IPC: C07C231/02 ,  A61K8/00 ,  A61K8/30 ,  A61K8/40 ,  A61K8/49 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q7/00 ,  A61Q17/00 ,  A61Q19/10 ,  C07C231/12 ,  C07C235/10 ,  C07C275/14 ,  C07D207/28 ,  C11D1/90

Abstract: PURPOSE:To obtain a new compound, excellent in humectant properties and useful as a detergent for kitchens, a hair cosmetic, a skin cosmetic, etc. CONSTITUTION:This compound of formula I [R is (hydroxyl group-substituted) 1-6C alkyl, formula II, etc.; R is H or (hydroxyl group-substituted) 1-6C alkyl], e.g. N,N-dimethyl-N-ethylureidoglycine. Furthermore, the compound of formula I is prepared by reacting an amine compound of formula III with a haloacetic acid (salt) of formula IV (X is halogen; Y is H or cation).

公开(公告)号：JPH06157388A

公开(公告)日：1994-06-03

申请号：JP32034792

申请日：1992-11-30

Applicant: KAO CORP

Inventor： HASHIZUME NAOMICHI ,  KAMIYA HIROSHI ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI

IPC: A61K8/30 ,  A61K8/00 ,  A61K8/02 ,  A61Q5/00 ,  A61Q5/12 ,  C07C41/24 ,  C07C43/13 ,  A61K7/00 ,  A61K7/06 ,  A61K7/08

Abstract: PURPOSE:To obtain a new compound capable of forming a thermotropic liquid crystal in water disperse system, soluble in almost all solvents, having good dispersibility to water, exhibiting very excellent lubricating properties and useful as a emulsifier, a lubricating agent, a liquid forming agent, etc. CONSTITUTION:A compound of formula I (R is 16-36C branched alkyl; R to R are H or 16-36C branched alkyl), e.g. 1mol isostearyl ether adduct of pentaerythritol of formula II. This compound is obtained by reacting pentaerythritol or its branched alkyl ether with a branched alkyl halide of the formula R X (X is halogen) (preferably branched alkyl bromide such as isostearyl bromide or heptyldecyl bromide) in the presence of a basic substance (preferably NaOH, etc.), preferably at 80-150 deg.C. Furthermore, this reaction is preferably carried out by dissolving or dispersing the compound of formula II in an organic solvent such as methanol and then adding a branched alkyl halide thereto while removing water content.

公开(公告)号：JPH06145358A

公开(公告)日：1994-05-24

申请号：JP30259192

申请日：1992-11-12

Applicant: KAO CORP

Inventor： IHARA TAKESHI ,  YANO SHINJI ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI

IPC: A61K8/18 ,  A61K8/00 ,  A61Q13/00 ,  C08G77/38 ,  C08G77/395 ,  C08L83/08 ,  A61K7/46

Abstract: PURPOSE:To obtain the title salt which has excellent smoothness, stickiness, etc., in addition to the excellent characteristics, e.g. water repellency, inherent in the conventional silicone and which is useful as the material of cosmetics. CONSTITUTION:The title salt is represented by the general formula: (Q)2B wherein Q is a group linked to B through a silicon atom provided at least one of z Q' s is -R -(OR )p-PO4M2/m and the rest are each or is -R -(OR )p-OH wherein R is a 2-4C linear or branched alkylene group; R is an optionally hydroxylated 1-50C linear or branched alkylene group; p is 0-200; M is an alkaline earth metal or a divalent or higher transition metal; and m is the valency of M; B is an organo(poly)siloxane residue having an alkyl-Si bond; and z is 1 or higher.

公开(公告)号：JPH06128202A

公开(公告)日：1994-05-10

申请号：JP27597692

申请日：1992-10-14

Applicant: KAO CORP

Inventor： UNO MITSURU ,  KITSUKI TOMOHITO ,  KITA KATSUMI ,  IMAI KAZUYASU ,  FUJIKURA YOSHIAKI

IPC: A61K8/30 ,  A61K8/00 ,  A61K8/40 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q19/00 ,  A61Q19/10 ,  C07C227/26 ,  C07C229/16 ,  C07C229/24 ,  C11D1/90 ,  A61K7/00 ,  A61K7/06 ,  A61K7/50

Abstract: PURPOSE:To obtain a new carboxybetaine excellent in humectant properties, useful as various kinds of bases for cosmetics and capable of simply and inexpensively producing. CONSTITUTION:A carboxybetaine expressed by formula I [either one or both of R and R are 1-5C alkyl having OH and the remainder is 1-5C alkyl; X is H or cation), e.g. N-methyl-N-(1-hydroxyethyl)-N-carboxymethylglycine sodium salt. This carboxybetaine of formula (1) is obtained by reacting, e.g. an amine compound of formula (2) with a carboxylic acid salt of formula (3) (Y is halogen) in the presence of an inert solvent, etc., and as necessary, subjecting the reactional product to salt exchange.

公开(公告)号：JPH05132410A

公开(公告)日：1993-05-28

申请号：JP29453191

申请日：1991-11-11

Applicant: KAO CORP

Inventor： IMAI KAZUYASU ,  KAJIWARA YASUSHI ,  KITA KATSUMI

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/02 ,  A61K8/73 ,  A61Q5/00 ,  A61Q5/12 ,  A61Q19/10

Abstract: PURPOSE:To obtain a cosmetic having excellent insulation effectiveness not damaged by washing with water, sweat, etc., providing softness and an excellent feeling of use, comprising a phosphobetaine compound. CONSTITUTION:A cosmetic containing 0.1-20wt.% compound of the formula (Z is group derived from a polysaccharide which may be replaced and has >=10 condensation degree of constituent monosaccharide or its partial hydrolyzate; R , to R are H, 1-24C alkyl, alkenyl, etc.; M and M are H or cationic group; (m) is >=0; (n) is >=1). The cosmetic can be made into a dosage form such as creamy, solid or powdery dosage form. The cosmetic has softness to skin and hair and no greasiness, provides moist and good touch and is suitable especially for rinse and body rise used by washing and flowing.