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    새로운방향족폴리술폰에테르케톤중합체
    1.
    发明授权
    새로운방향족폴리술폰에테르케톤중합체 失效
    新型芳香族聚砜醚酮聚合物

    公开(公告)号：KR1019930006259B1

    公开(公告)日：1993-07-09

    申请号：KR1019900001238

    申请日：1990-02-02

    Applicant: 한국과학기술연구원

    Inventor： 김영하 ,  한양규 ,  김대식 ,  지성대 ,  박종원

    IPC: C08G75/20

    CPC classification number: C08G75/23 ,  C08G65/4012 ,  C08L2205/05

    Abstract: The polymer having a repeating unit of formula (I) is prepared by condensation reacting aromatic dihalogen compound (A) of formula (II) and aromatic diol (B) of formula (III) in the presence of alkali metal salt at 140-250 deg.C for 1-12 hr. In formulae, Ar is phenylene, biphenylene, etc., X is chlorine and M is alkali metal, compound (A) is 4-fluoro-4'-(4-fluorobenzoyl phenyloxy)diphenylsulfone and compound (B) is selected from 2,2-bis- (4-hydroxyphenyl)propane, hydroquinone or 4,4'-biphenol. The alkali metal salt is potassium carbonate and its addition amount is 1.0-20 wt.% w.r.t. aromatic diol.

    Abstract translation: 具有式（I）的重复单元的聚合物通过在140-250度的碱金属盐存在下使式（II）的芳族二卤化合物（A）和式（III）的芳族二醇（B） C 1〜12小时。 式中，Ar为亚苯基，亚联苯等，X为氯，M为碱金属，化合物（A）为4-氟-4' - （4-氟苯甲酰苯氧基）二苯砜，化合物（B） 丙二醇，对苯二酚或4,4'-联苯酚。 碱金属盐是碳酸钾，其添加量为1.0-20重量％w.r.t. 芳族二醇。

    물성이 개량된 아크릴산 알칼리 금속염 흡수성 수지의 제조방법
    2.
    发明授权
    물성이 개량된 아크릴산 알칼리 금속염 흡수성 수지의 제조방법 失效
    一种制备丙烯酸金属树脂吸收树脂的方法

    公开(公告)号：KR1019920000785B1

    公开(公告)日：1992-01-23

    申请号：KR1019870014654

    申请日：1987-12-21

    Applicant: 한국과학기술연구원

    Inventor： 김영하 ,  한양규 ,  김수현 ,  지성대

    IPC: C08F20/06

    Abstract: The acrylic acid alkali metal salt resin is prepd. by steps: (A) polymerising acrylic acid and acrylic acid alkali metal salt in presence of crosslinking agent and radical polymerising initiator in alicyclic hydrocarbon org. solvent; (B) after-polymerising the carboxyl gp. of the obtd. polymer with water soluble diglycidyl ether; (C) adding low molecular water soluble polymer selected from polyehylene glycol or hydroxyethyl cellulose. The sametimely crosslinking agent is selected from diacrylate, triacrylate, polyethyleneglycol di(meth)acrylate or alkylenebisacryl amide of polyol having more two polymerisable functional gp.. The solvent contains 3-6 HLB surfactant and 8-15 HLB surfactant.

    Abstract translation: 制备丙烯酸碱金属盐树脂。 步骤：（A）丙烯酸和丙烯酸碱金属盐在交联剂和自由基聚合引发剂存在下在脂环族烃组分中聚合。 溶剂; （B）羧基gp的后聚合。 的obtd。 聚合物与水溶性二缩水甘油醚; （C）加入选自聚乙二醇或羟乙基纤维素的低分子水溶性聚合物。 同时交联剂选自二丙烯酸酯，三丙烯酸酯，聚乙二醇二（甲基）丙烯酸酯或具有更多两个可聚合官能团的多元醇的亚烷基双丙烯酰胺。该溶剂含有3-6个HLB表面活性剂和8-15个HLB表面活性剂。

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