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公开(公告)号:KR1020100137853A
公开(公告)日:2010-12-31
申请号:KR1020090056089
申请日:2009-06-23
Applicant: 한국화학연구원 , 에스케이이노베이션 주식회사
CPC classification number: B01J29/70 , B01J23/10 , B01J2523/15 , C07C15/14
Abstract: PURPOSE: A catalyst for removing sulfur dioxide of dibenzothiophene sulfone and a method for manufacturing biphenyl using the same are provided to efficiently remove a sulfur compound from the dibenzothiophene sulfone by a complex oxide catalyst. CONSTITUTION: Nitric acid cesium is manufactured. Cesium is impregnated in MCM-41 during incipient wetness. MCM-41 catalyst is obtained. A fixed layer continuous-type reactor is filled with the MCM-41 catalyst. Toluene including dibenzothiophene sulfone 500 ppm is put into in the reactor. A dibenzothiophene sulfone decomposition reaction is enforced. The dibenzothiophene sulfone is converted into biphenyl.
Abstract translation: 目的:提供用于除去二苯并噻吩砜的二氧化硫的催化剂和使用其的联苯的制造方法,以通过复合氧化物催化剂有效地从二苯并噻吩砜中除去硫化合物。 构成:制造硝酸铯。 在初潮期间,铯被浸渍在MCM-41中。 获得MCM-41催化剂。 用MCM-41催化剂填充固定层连续型反应器。 包括二苯并噻吩砜500ppm的甲苯放入反应器中。 二苯并噻吩砜分解反应得到实施。 二苯并噻吩砜转化为联苯。
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公开(公告)号:KR101525943B1
公开(公告)日:2015-06-09
申请号:KR1020140032363
申请日:2014-03-19
Applicant: 한국화학연구원
Abstract: 본발명은메탄올의일산화탄소에의한탈수반응및 카보닐화반응에의하여디메틸에테르와아세트산을동시에제조하는반응에사용되는불균일계구리촉매에관한것이다.
Abstract translation: 本发明涉及通过脱甲基反应和甲醇一氧化碳引起的羰基化反应同时制备二甲醚和乙酸的异相铜催化剂。 为了实现这一点,本发明提供了由化学式1表示的异相铜催化剂,并用于同时制备二甲醚和乙酸。
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公开(公告)号:KR100351630B1
公开(公告)日:2002-09-11
申请号:KR1019990014329
申请日:1999-04-22
Applicant: 한국화학연구원
IPC: C07C69/675 , C07C69/34
Abstract: 본발명은표면장력저하능이우수하며중금속및 유해유기물질에대한세척능우수하여수용성혹은유용성의계면활성제로또는토양세척제로유용한다음화학식 1로표시하는스피큘리스포릭산에스테르유도체에관한것이다. 상기화학식 1에서 : R, R및 R은각각알콕시기, 폴리옥시에틸렌기또는폴리옥시프로필렌기를나타낸다.
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公开(公告)号:KR100451670B1
公开(公告)日:2004-10-08
申请号:KR1020010056740
申请日:2001-09-14
Applicant: 한국화학연구원
IPC: C07D477/14
CPC classification number: Y02P20/55
Abstract: PURPOSE: Provided are carbapenem derivatives represented by formula(1) and a preparation method thereof. The carbapenem derivatives have antibacterial activity against the resistant strains such as methicillin resistant Staphylococcus aureus(MRSA) and resistant strain against Ofloxacin. CONSTITUTION: The method of preparation comprises: reacting a compound of formula(2) with a compound of formula(3) to make an ester derivatives of carbapenem represented by formula(4); and de-protecting carboxy group and hydroxy group. In formula(1), X is S or O atom; Y is hydrogen or halogen atom on a certain location in phenyl group, or C1-2 alkoxy group; M is hydrogen atom or a pair ion forming a pharmaceutically allowable salt. In formula(2,3 and 4), R1 is hydrogen atom or hydroxy protecting group; R2 is carboxy protecting group; X is S or O atom; Y is hydrogen or halogen atom on a certain location in phenyl group.
Abstract translation: 用途:提供了由式(1)表示的碳代青霉烯衍生物及其制备方法。 碳青霉烯衍生物对耐药菌株如耐甲氧西林金黄色葡萄球菌(MRSA)和抗氧氟沙星耐药菌株具有抗菌活性。 构成:制备方法包括:使式(2)化合物与式(3)化合物反应,制得式(4)代表的碳青霉烯酯衍生物; 和去保护羧基和羟基。 在式(1)中,X是S或O原子; Y是在苯基中的某个位置上的氢或卤素原子,或C1-2烷氧基; M是氢原子或形成药学上允许的盐的一对离子。 在式(2,3和4)中,R 1是氢原子或羟基保护基; R2是羧基保护基; X是S或O原子; Y在苯基的某个位置上是氢或卤素原子。
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公开(公告)号:KR1020000066919A
公开(公告)日:2000-11-15
申请号:KR1019990014329
申请日:1999-04-22
Applicant: 한국화학연구원
IPC: C07C69/675 , C07C69/34
Abstract: PURPOSE: Spiculisporic acid ester derivatives excellent in lowering performance of surface tension, detergency for heavy metal and harmful organic materials obtained by acylating spiculisporic acid and esterify is provided which is useful as a water soluble or oily surfactant or a soil cleaning agent. CONSTITUTION: Spiculisporic acid ester derivatives of formula 1 are obtained by acylating spiculisporic acid in a benzene solvent and esterifying with nonionic alcohol or alkyl alcohol in pyridine and dimethylformamide. In formula, R1, R2 and R3 are the same or different hydroxyl, alkoxy, benzoyl, polyoxyethylene or polyoxypropylene.
Abstract translation: 目的:提供优异的降低表面张力性能,通过酰化spiculisporic酸和酯化获得的重金属和有害有机物质的去污力的Spiculisporic酸酯衍生物,其可用作水溶性或油性表面活性剂或土壤清洁剂。 构成:式1的间歇酸酯衍生物通过在苯溶剂中酰化spiculisporic酸并在吡啶和二甲基甲酰胺中用非离子醇或烷基醇酯化获得。 在式中,R 1,R 2和R 3是相同或不同的羟基,烷氧基,苯甲酰基,聚氧乙烯或聚氧丙烯。
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公开(公告)号:KR101068994B1
公开(公告)日:2011-09-30
申请号:KR1020090056089
申请日:2009-06-23
Applicant: 한국화학연구원 , 에스케이이노베이션 주식회사
Abstract: 본 발명은 디벤조티오펜설폰의 이산화황 제거용 촉매 및 이를 이용한 비페닐의 제조방법에 관한 것으로서, 더욱 상세하게 설명하면, 특정 금속이 담지된 메조포어 분자체를 포함하는 촉매 및 상기 촉매 하에서, 비페닐을 제조하는 방법에 관한 것이다. 본 발명의 상기 촉매를 이용하여 디벤조티오펜설폰이 이산화황 등의 황 화합물을 제거 시, 매우 효과적으로 황 화합물을 제거할 수 있으며, 이를 통하여 비페닐을 높은 수율로 얻을 수 있다.
디벤조티오펜설폰, 비페닐, 메조포어 분자체-
公开(公告)号:KR1020030023968A
公开(公告)日:2003-03-26
申请号:KR1020010056740
申请日:2001-09-14
Applicant: 한국화학연구원
IPC: C07D477/14
CPC classification number: Y02P20/55
Abstract: PURPOSE: Provided are carbapenem derivatives represented by formula(1) and a preparation method thereof. The carbapenem derivatives have antibacterial activity against the resistant strains such as methicillin resistant Staphylococcus aureus(MRSA) and resistant strain against Ofloxacin. CONSTITUTION: The method of preparation comprises: reacting a compound of formula(2) with a compound of formula(3) to make an ester derivatives of carbapenem represented by formula(4); and de-protecting carboxy group and hydroxy group. In formula(1), X is S or O atom; Y is hydrogen or halogen atom on a certain location in phenyl group, or C1-2 alkoxy group; M is hydrogen atom or a pair ion forming a pharmaceutically allowable salt. In formula(2,3 and 4), R1 is hydrogen atom or hydroxy protecting group; R2 is carboxy protecting group; X is S or O atom; Y is hydrogen or halogen atom on a certain location in phenyl group.
Abstract translation: 目的:提供式(1)表示的碳青霉烯衍生物及其制备方法。 碳青霉烯衍生物对抗性菌株如耐甲氧西林金黄色葡萄球菌(MRSA)和耐氧沙星的抗性菌株具有抗菌活性。 构成:制备方法包括:使式(2)化合物与式(3)化合物反应,制得由式(4)表示的碳青霉烯的酯衍生物; 并脱保护羧基和羟基。 在式(1)中,X是S或O原子; Y是苯基或C1-2烷氧基中某一位置上的氢或卤素原子; M是氢原子或形成药学上允许的盐的成对离子。 在式(2,3和4)中,R 1是氢原子或羟基保护基; R2是羧基保护基; X是S或O原子; Y是苯基中某一位置的氢或卤素原子。
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