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公开(公告)号：KR100319489B1
公开(公告)日：2002-01-05
申请号：KR1019990052792
申请日：1999-11-25
Applicant: 한국화학연구원
IPC: C08G77/04
Abstract: 본발명은과불소알킬-실록산그룹함유고분자및 이를이용한고분자분리막에관한것으로서, 더욱상세하게는과불소알킬함유다이아민및 실록산다이아민의두 종류의다이아민화합물을다이카르복시산유도체와축중합시켜얻은신규과불소알킬-실록산그룹함유고분자와, 이를직접이용하여제조된것으로기체분리, 투과증발등의일반적인막분리공정에적용되어우수한분리능을나타내는고분자분리막에관한것이다.
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公开(公告)号：KR100270408B1
公开(公告)日：2001-01-15
申请号：KR1019980030863
申请日：1998-07-30
Applicant: 한국화학연구원
IPC: C09K3/18
Abstract: 본 발명은 불소-실리콘계 올리고머형 방무제에 관한 것으로서, 더욱 상세하게는 다음 화학식 1로 표시되는 과불소화알킬기 함유 화합물과 다음 화학식 2로 표시되는 실리콘기 함유 화합물 및 다음 화학식 3으로 표시되는 하이드록시기가 치환되거나 치환되지 않은 알킬기 함유 가교성 단량체 각각을 공중합 단량체로하여 랜덤 공중합체 형태로 중합됨으로써 농업용으로 사용되고 있는 염화비닐계 수지필름, 폴리에틸렌 필름, 에틸렌-비닐아세테이트 필름, 폴리에스테르 필름 등에 첨가되어 하우스 내부에서 발생되는 수적방지와 토양분진에 의한 내오염성을 부여하고, 광투과성을 높여 농작물의 성장을 촉진하고 대기와의 온도차로 인하여 생성되는 구름성을 제거할 수 있으며, 표면개질특성이 매우 우수한 불소-실리콘계 올리고머형 방무제에 관한 것� ��다.
상기 화학식 1, 2 및 3에서;
R
f 는 C
k F
2k+1 이고, 이때 k는 1 ∼ 10의 정수이고,
R은 H 또는 CH
3 이고,
R
1 , R
2 , R
3 는 서로 같거나 다른 것으로서 실릴옥시기, C
1 ∼ C
3 의 알콕시기 또는 C
1 ∼ C
3 의 알킬기이고,
A는 -CO
2 -(CH
2 )
m -이고, 이때 m은 1 ∼ 4의 정수이고,
R
4 는 하이드록시기가 치환되거나 치환되지 않은 C
1 ∼ C
4 의 알킬기이다.-
公开(公告)号：KR1020000067454A
公开(公告)日：2000-11-15
申请号：KR1019990015268
申请日：1999-04-28
Applicant: 한국화학연구원
IPC: B01D71/70
CPC classification number: B01D71/70 , B01D63/02 , B01D63/08 , B01D63/10 , B01D67/0006 , B01D67/0079 , B01D69/06 , B01D69/08 , B01D71/022 , B01D71/025 , B01D71/027
Abstract: PURPOSE: A polymer membrane prepared with a polymer material introduced a crosslinked structure in an inside polymer and a siloxane group in main chains is provided which has excellent processability, mechanical strength and separation performance. CONSTITUTION: Siloxane diamine of formula 1 and one or two or more dicarboxylic acid derivatives selected from diacylchloride, disulfonylchloride, diacid, dianhydride and monoacid-monoanhydride are polycondensated and crosslinked to produce a polymer separation membrane containing crosslinked organopolysiloxane. The polymer separation membrane exhibits excellent separation performance by applying to general membrane separation process such as gas separation and permeation evaporation.
Abstract translation: 目的：提供用聚合物材料制备的聚合物膜，其在主链内部聚合物和硅氧烷基团中引入交联结构，其具有优异的加工性能，机械强度和分离性能。 构成：式1的硅氧烷二胺和选自二酰氯，二磺酰氯，二酸，二酐和单酸酐的一种或两种以上二羧酸衍生物进行缩聚交联以制备含有交联的有机聚硅氧烷的聚合物分离膜。 聚合物分离膜通过应用于气体分离和渗透蒸发等一般膜分离方法而表现出优异的分离性能。
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公开(公告)号：KR1019970003956B1
公开(公告)日：1997-03-24
申请号：KR1019930010165
申请日：1993-06-05
Applicant: 한국화학연구원
IPC: C09K5/00
Abstract: The refrigerant oil for household refrigerator is prepared using R-134a as a coolant. R-134a is prepared through additive reaction of pentaerysritol, 2-ethylhexylacid, 2-methylhexylacid or etc. using the solvent prereacted with pentaerysritol, 2-ethylhexylacid, 2-methylhexylacid or etc. The prepared refrigerant oil reduces the reaction time so that heat loss is minimized and the change of color is prevented.
Abstract translation: 用于家用冰箱的制冷剂油是使用R-134a作为冷却剂制备的。 R-134a通过使用预先与五甲硅烷醇，2-乙基己基酸，2-甲基己酸等进行反应的溶剂，通过季戊四醇，2-乙基己基酸，2-甲基己酸等的添加反应来制备。制备的制冷剂油减少反应时间，使得热损失 被最小化并且防止了颜色的变化。
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Patent Agency Ranking
公开(公告)号：KR100361584B1
公开(公告)日：2002-11-22
申请号：KR1020000061353
申请日：2000-10-18
IPC: C08J11/12
Abstract: 본 발명은 높은 장치 투자비 및 운전비가 필요한 일반적인 TFE 제조방법과 대비되는 PTFE를 열분해하여 TFE를 연속적으로 대량 생산하는 이송장치에 관한 것으로서, PTFE의 열분해에 의해서 TFE의 상업적 생산이 가능한 공정을 개발하기 위한 PTFE의 연속 이송장치를 제공하고 있다.
본 발명에서 제공하고 있는 이송장치는 분말 혹은 입자형 PTFE를 고진공하에서 PTFE 이송의 중단없이 고온 열분해 반응기에 연속적으로 주입하여 TFE를 연속 대량 생산할 수 있는 것을 특징으로 하고 있으며, 본 발명의 이송장치에 따르면 종전 PTFE 열분해에 의해 TFE를 생산하는 방법의 단점인 회분식 반응 및 PTFE의 이송불량(용착, 고착 등)에 의해 열분해 반응의 중단 및 잦은 장치의 해체 및 보수에 따른 생산성 저하를 극복하여 편리하고 경제적인 TFE의 상업적 대량 생산을 가능하게 하는 효과를 기대할 수 있다.-
公开(公告)号：KR1020020030944A
公开(公告)日：2002-04-26
申请号：KR1020000061353
申请日：2000-10-18
IPC: C08J11/12
CPC classification number: Y02W30/703
Abstract: PURPOSE: Provided is a device for continuously transferring polytetrafluoroethylene, for developing a process capable of industrially producing a TFE by pyrolysis of PTFE. CONSTITUTION: The device comprises at least two major reservoir(10) for PTFE capable of storing particles or powders of PTFE and operating alternately; a minor reservoir(11) for PTFE which temporarily stores PTFE supplied from the major reservoir(10); a vertical screw feeder(13) which quantitatively introduces PTFE supplied from the minor reservoir(11) into process by duct(14); and a heat exchanger(15) which blocks and cools a heat transmitted from a vertical pyrolysis reactor(16). The device can conveniently and economically mass-produce a TFE.
Abstract translation: 目的：提供一种用于连续转移聚四氟乙烯的装置，用于开发通过PTFE热解工业生产TFE的方法。 构成：该装置包括用于PTFE的至少两个主要储存器（10），其能够存储PTFE的颗粒或粉末并交替操作; 用于PTFE的小储存器（11），其临时存储从主储存器（10）供应的PTFE; 一个垂直螺旋进料器（13），定量地将从小容器（11）供应的PTFE引入通过管道（14）的过程; 以及热交换器（15），其阻断并冷却从垂直热解反应器（16）传递的热量。 该设备可以方便和经济地批量生产TFE。
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公开(公告)号：KR1020010048205A
公开(公告)日：2001-06-15
申请号：KR1019990052792
申请日：1999-11-25
Applicant: 한국화학연구원
IPC: C08G77/04
Abstract: PURPOSE: A polymer containing perfluoride alkyl-siloxane group and a separation membrane using the polymer are provided, to improve the separation efficiency of the separation membrane. CONSTITUTION: The polymer containing perfluoride alkyl-siloxane group is obtained by condensation polymerizing perfluoride alkyl-containing diamine represented by the formula 1; siloxane diamine represented by the formula 5; and one or more dicarboxylic acid derivatives selected from diacyl chloride, dianhydride, disulfonyl chloride, diacid and monoacid-monoanhydride. The equivalence of the dicarboxylic acid derivatives is equal to that of the two kinds of diamines. In the formula 1, Rf is represented by C(W1W2W3)(CF3)n(X)m(Y)-; W1, W2 and W3 represent H, F, Cl or CF3; X represents CONR or SO2NR (wherein R is H or an alkyl group of C1-C5); Y represents an alkylene group of C1-C10 substituted with OH or OCOCH3 or unsubstituted; n is an integer of 2-20; and m is 0 or 1, and in the formula 5, m is an integer of 2-95. The separation membrane is asymetric and is prepared by using one or two kinds of the polymer with the number mean molecular weight of 5,000-100,000.
Abstract translation: 目的：提供含有全氟化物烷基硅氧烷基团的聚合物和使用该聚合物的分离膜，以提高分离膜的分离效率。 构成：含有全氟化物烷基 - 硅氧烷基团的聚合物是通过使由式1表示的全氟化烷基的二胺缩合而获得的; 由式5表示的硅氧烷二胺; 和一种或多种选自二酰氯，二酐，二磺酰氯，二酸和单酸一酐的二羧酸衍生物。 二羧酸衍生物的等价性与两种二胺的相等。 在式1中，Rf由C（W1W2W3）（CF3）n（X）m（Y） - 表示。 W1，W2和W3表示H，F，Cl或CF3; X表示CONR或SO2NR（其中R是H或C1-C5的烷基）; Y表示被OH或OCOCH 3取代的C1-C10的亚烷基或未取代的; n为2-20的整数; m为0或1，在式5中，m为2-95的整数。 分离膜是不对称的，并且通过使用数均分子量为5,000-100,000的一种或两种聚合物来制备。
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公开(公告)号：KR1019930006910B1
公开(公告)日：1993-07-24
申请号：KR1019900004185
申请日：1990-03-28
Applicant: 한국화학연구원
IPC: C08F10/08
Abstract: This relates to manufacturing polybutene using C4-raffinates and LPG. The manufacturing method comprises: (A) mixing raffinate and LPG in the ratio of 1:0.25-4; (B) polymerizing continuously in the presence of Friedel-Craft catalyst; and (C) removing the activity of catalyst residue by caustic soda. Pref. C4 raffinate is composed of 10-20 wt.% butane, 20-30 wt.% 1-butene, 40-50 wt.% isobutene, 0.5-3 wt.% 1,3-butadiene, and 10-20 wt.% trans- and cis-2-butene. Also the claimed manufacturing system comprises: impeller propelled multitubular reactor (1); in-line type and stirring type mixer (2,2'); the first and second tank (3,3'); filtering tank (4) and film evaporator (5).
Abstract translation: 这涉及使用C4萃余液和LPG制造聚丁烯。 制造方法包括：（A）以1:0.25-4的比例混合萃余液和LPG; （B）在Friedel-Craft催化剂存在下连续聚合; 和（C）通过苛性钠除去催化剂残留物的活性。 县。 C4萃余液由10-20重量％丁烷，20-30重量％1-丁烯，40-50重量％异丁烯，0.5-3重量％1,3-丁二烯和10-20重量％ 反式和顺-2-丁烯。 所要求的制造系统还包括：叶轮推进多管反应器（1）; 直列式搅拌式搅拌机（2,2'）; 第一和第二罐（3,3'）; 过滤罐（4）和薄膜蒸发器（5）。
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公开(公告)号：KR100376273B1
公开(公告)日：2003-03-15
申请号：KR1020000039958
申请日：2000-07-12
IPC: C08J11/12
CPC classification number: Y02W30/703
Abstract: PURPOSE: A continuous polytetrafluoroethylene(PTFE) pyrolysis apparatus and a method for preparing PTFE using the apparatus are provided, to obtain tetrafluoroethylene of high purity massively with low cost. CONSTITUTION: The apparatus comprises at least two PTFE main tanks(10) which stores PTFE powder or particle and can be operated alternatively; a PTFE auxiliary tank(11) which is connected with the main PTFE main tanks(10) through a ball valve(24) and a transparent hose(12) for vacuum and stores PTFE supplied from the main tanks(10) temporarily before PTFE is applied to the process; a vertical-type screw feeder(13) which is operated by a motor and a magnetic driver, whose rotation number can be controlled, and which injects the PTFE supplied from the auxiliary tank(11) into a pyrolysis reactor through a cooler(15); and a vertical-type pyrolysis reactor(14) which pyrolyzes the PTFE supplied from the screw feeder(13) to generate tetrafluoroethylene gas and delivers the generated tetrafluoroethylene gas to a tetrafluoroethylene condensation tank.
Abstract translation: 目的：提供一种连续的聚四氟乙烯（PTFE）热解设备和使用该设备制备PTFE的方法，以低成本大量获得高纯度的四氟乙烯。 构成：该设备包括至少两个PTFE主容器（10），其存储PTFE粉末或颗粒并且可以交替地操作; 通过球阀（24）和真空透明软管（12）与主PTFE主容器（10）连接的PTFE辅助容器（11），用于真空并在PTFE之前临时储存从主容器（10）供应的PTFE 适用于该过程; 由能够控制转数的电动机和磁驱动器操作并且将从辅助罐（11）供应的PTFE通过冷却器（15）注入热解反应器的立式螺旋送料器（13） ; 以及将从螺旋送料器（13）供给的PTFE热分解而生成四氟乙烯气体并将生成的四氟乙烯气体送入四氟乙烯冷凝罐的立式热解反应器（14）。
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