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公开(公告)号：KR100248945B1
公开(公告)日：2000-04-01
申请号：KR1019970065413
申请日：1997-12-02
Applicant: 한국화학연구원
IPC: A01N43/76
Abstract: 본 발명은 화학식 1로 표시되는 제초성 3-아릴-테트라히드로-1,2-벤즈이속사졸린-4-온 유도체에 관한 것이다.
상기식에서 Xn은 수소, C
1 -C
4 알킬기, C
2 -C
5 알케닐기, C
2 -C
5 알키닐기, C
1 -C
4 알콕시기, C
1 -C
4 할로알킬기, C
1 -C
4 알콕시카보닐기, 아미노카보닐기, 카복시기, 메탄설포닐기, 니트로기, 히드록시기, 니트릴기, 또는 이들의 둘이상의 복합치환기를 나타낸다.-
公开(公告)号：KR1020130092711A
公开(公告)日：2013-08-21
申请号：KR1020120014152
申请日：2012-02-13
Applicant: 동양하이테크산업주식회사 , 한국화학연구원
CPC classification number: Y02P20/52 , B01J29/0325 , B01J21/18 , B01J37/0201 , C01B3/326
Abstract: PURPOSE: A catalyst for aqueous phase reforming reaction with a stable structure compared to that of a conventional catalyst and a manufacturing method thereof are provided to significantly increase a conversion ratio and a production rate of hydrogen and to provide hydrogen economically and environment-friendlily. CONSTITUTION: A catalyst for aqueous phase reforming reaction comprises a metal component carried in a mesoporous carbon carrier. The metal component is one selected from the group consisting of metals of VIIB group and VIII group. The mesoporous carbon carrier is manufactured by using a 3-dimensional mesoporous silica molecular sieve of one selected from the group consisting of SBA-1, SBA-6, SBA-16, FDU-5, KIT-6, and MCM-48.
Abstract translation: 目的：提供一种与常规催化剂相比具有稳定结构的水相重整反应催化剂及其制备方法，以显着提高氢气的转化率和生产率，从而在经济和环保方面提供氢气。 构成：用于水相重整反应的催化剂包括载于介孔碳载体中的金属组分。 金属成分选自VIIB族和VIII族金属。 通过使用选自SBA-1，SBA-6，SBA-16，FDU-5，KIT-6和MCM-48的一种3维介孔二氧化硅分子筛制造介孔碳载体。
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Patent Agency Ranking3.发明公开
公开(公告)号：KR1020120133751A
公开(公告)日：2012-12-11
申请号：KR1020110052570
申请日：2011-06-01
Applicant: 동양하이테크산업주식회사 , 한국화학연구원
CPC classification number: Y02P20/52 , C01B32/05 , B01J23/42 , B01J23/8986 , C01B3/40
Abstract: PURPOSE: A carbon supported metal catalyst with a three dimensional bimodal mesoporous structure and an aqueous phase reforming method of oxygenated compounds using the same are provided to directly form carbon with a bimodal porous structure without a separate template material. CONSTITUTION: An aqueous phase reforming method of oxygenated compounds using a carbon supported metal catalyst with a three dimensional bimodal mesoporous structure includes the following steps: a carbon precursor is impregnated into silica; the impregnated product is dried and carbonated to prepare a silica/carbon complex; and the silica is removed from the silica/carbon complex. The silica is one or more selected from silica gel with mesopores, silica nanoparticles, silica beads, aluminum anodic oxide, and alumino silicagel. [Reference numerals] (AA) Adsorption; (BB) Desorption; (CC) Adsorption amount; (DD) Relative pressure
Abstract translation: 目的：提供具有三维双峰介孔结构的碳负载金属催化剂和使用其的含氧化合物的水相重整方法，以直接形成具有双峰多孔结构的碳，而没有单独的模板材料。 构成：使用具有三维双峰介孔结构的碳负载金属催化剂的含氧化合物的水相重整方法包括以下步骤：将碳前体浸渍到二氧化硅中; 将浸渍的产物干燥并碳酸化以制备二氧化硅/碳络合物; 并且二氧化硅从二氧化硅/碳络合物中除去。 二氧化硅是选自具有介孔的硅胶，二氧化硅纳米颗粒，二氧化硅珠，铝阳极氧化物和铝硅胶中的一种或多种。 （附图标记）（AA）吸附; （BB）解吸; （CC）吸附量; （DD）相对压力
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公开(公告)号：KR1020000013379A
公开(公告)日：2000-03-06
申请号：KR1019980032207
申请日：1998-08-07
Applicant: 한국화학연구원
IPC: C07D261/20
Abstract: PURPOSE: A hexahydro-1,2-benzisoxazol derivative is excellent in weeding activity and innoxious to paddy rice. CONSTITUTION: A hexahydro-1,2-benzisoxazol derivative represented by the following formula, wherein Xn is a hydrogen, a C1-C3 alkyl group, a C2-C4 alkenyl group, a C2-C4 alkynyl group, a C1-C3 alkoxyl group, a C1-C3 haloalkyl group, a C1-C3 thioalkyl group, a C1-C3 alkylsulfenyl group, a C1-C3 alkylsulfonyl group, a halogen group, a nitro group, a nitrile group, or a composite substituent thereof; Yn is a hydrogen, a C1-C6 alkyl group, a halogen group, a nitro group, a nitrile group, or a composite substituent thereof; Yn is a hydrogen, a C1-C3 alkyl group, a halogen group, a nitro group, a nitrile group, or a composite substituent thereof; and R is a hydrogen or a methyl group.
Abstract translation: 目的：六氢-1,2-苯并异恶唑衍生物具有优良的除草活性和无害水稻。 构成：由下式表示的六氢-1,2-苯并异恶唑衍生物，其中Xn为氢，C1-C3烷基，C2-C4烯基，C2-C4炔基，C1-C3烷氧基 C1-C3卤代烷基，C1-C3硫代烷基，C1-C3烷基亚磺酰基，C1-C3烷基磺酰基，卤素基，硝基，腈基或其复合取代基; Yn为氢，C1-C6烷基，卤素基，硝基，腈基或其复合取代基; Yn为氢，C1-C3烷基，卤素基，硝基，腈基或其复合取代基; R为氢或甲基。
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5.发明授权
公开(公告)号：KR101843974B1
公开(公告)日：2018-04-02
申请号：KR1020110052570
申请日：2011-06-01
Applicant: 동양하이테크산업주식회사 , 한국화학연구원
CPC classification number: Y02P20/52
Abstract: 본발명은주형으로서의상용실리카에탄소전구체를함침시킨다음건조및 탄화시켜실리카/탄소복합물을얻고실리카/탄소복합물로부터실리카를제거하는단계를포함하는 3차원이원메조기공을갖는탄소의제조방법및 이로부터제조된 3차원이원메조기공을갖는탄소, 이에담지된금속촉매, 및메조기공탄소담지금속촉매를이용한함산소화합물의수상개질반응을통하여수소를효율적으로제조하는방법을제공한다. 본발명에따른탄소담지체는 3차원적으로이원화된메조기공을갖는구조적특성으로인하여, 함산소화합물의수상개질반응에서기상으로의전환율및 수소의수율을증가시킬수 있다.
Abstract translation: 本发明涉及一种制造具有碳浸渍的前体，然后干燥并通过硅胶碳化碳的方法/获得碳复合第三维是赢了中孔，包括在模具中的商业二氧化硅作为从二氧化硅/碳复合材料中去除二氧化硅的步骤和 仅使用碳的三维由其制备的具有圆孔，负载型金属催化剂在其上的负载型金属催化剂，和中孔碳提供通过奖含氧化合物的重整更有效地生产氢的方法。 根据本发明的碳载体可以提高由含水重整反应至气相的含氧化合物的转化率和由于三维中间化中孔的结构特征而产生的氢的产率。
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公开(公告)号：KR100303264B1
公开(公告)日：2001-11-22
申请号：KR1019980032207
申请日：1998-08-07
Applicant: 한국화학연구원
IPC: C07D261/20
Abstract: 본 발명은 하기 화학식 1로 표시되는 헥사히드로-1,2-벤즈이속사졸 유도체 및 그의 제조방법에 관한 것으로, 본 발명의 화합물은 피 (ECHOR), 올챙이고랑이 (SCPJU), 물달개비 (MOOVA), 너도방동산이 (CYPSE), 올미 (SAGPY) 등의 논 잡초에 대해 고루 우수한 제초활성을 보이므로 이양벼 및 직파벼 조건에서 논 잡초용 제초제로 유용하게 사용될 수 있다.
상기식에서 Xn, Yn 및 R 은 명세서에 기재된 바와 같다.-
公开(公告)号：KR1019990047157A
公开(公告)日：1999-07-05
申请号：KR1019970065413
申请日：1997-12-02
Applicant: 한국화학연구원
IPC: A01N43/76
Abstract: 본 발명은 화학식 1로 표시되는 제초성 3-아릴-테트라히드로-1,2-벤즈이속사졸린-4-온 유도체에 관한 것이다.
상기식에서 Xn은 수소, C
1 -C
4 알킬기, C
2 -C
5 알케닐기, C
2 -C
5 알키닐기, C
1 -C
4 알콕시기, C
1 -C
4 할로알킬기, C
1 -C
4 알콕시카보닐기, 아미노카보닐기, 카복시기, 메탄설포닐기, 니트로기, 히드록시기, 니트릴기, 또는 이들의 둘이상의 복합치환기를 나타낸다.
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