Abstract:
Methods of bonding a pressure-sensitive adhesive to a substrate are provided. The methods include heating a styrenic block copolymer composition to provide an adhesive melt composition, wherein the styrenic block copolymer composition contains a hard segment block with a glass transition temperature of from 90°C to 220°C; masticating the adhesive melt composition; delivering the adhesive melt composition onto the substrate at a temperature that exceeds the glass transition temperature of the hard segment block by from 20°C to 150°C; and cooling the adhesive melt composition to obtain a bonded pressure-sensitive adhesive. Optionally, the substrate can be a non-film substrate, or the styrenic block copolymer composition can be provided in a core-sheath filament that includes a styrenic block copolymer core and a sheath that is non-tacky at ambient temperature.
Abstract:
A multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer. The polymeric foam comprises a multi-arm block copolymer having the formula Q n -Y, with Q representing an arm of the multi-arm block copolymer, n being at least 3, and Y being the residue of a multifunctional coupling agent; a polymeric plasticizer having a weight average molecular weight Mw of at least 10.000 g/mol; and at least one hydrocarbon tackifier having a VOC value of less than 1000 ppm. The first pressure sensitive adhesive comprises a linear block copolymer having the formula M - (G) p , with M being a rubbery block and p being 1 or 2; at least one second hydrocarbon tackifier; and a (meth)acrylate copolymer having a Tg higher than 25 °C and a weight average molecular weight (Mw) between 1000 and 100,000 Daltons.
Abstract:
Described herein is a foam adhesive article comprising: a closed cell foam layer comprising an extruded thermoplastic polymer foam and particles distributed therein, wherein the particles comprise a plurality of hollow particles, wherein the hollow particles comprise at least one of thermoplastic expanded polymeric particles, glass particles, and mixtures thereof; and a plurality of sorbent particles. Also disclosed herein are precursor compositions and methods of making such constructions.
Abstract:
A core-sheath filament including a crosslinkable adhesive core that can be cured using ultraviolet or visible light radiation. These crosslinkable adhesive core compositions can provide very high bond strength and are capable of replacing traditional mechanical fasteners in many industrial applications. Core-sheath filaments including such crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions contain pendant aromatic ketone groups or pendant (meth)acryloyl groups that, upon exposure to ultraviolet radiation, result in the formation of crosslinks within the polymeric material. The crosslinked compositions can function as pressure-sensitive adhesives.
Abstract:
Described are adhesive compositions containing a block copolymer component that includes a midblock segment and a plurality of end block segments, each end block segment comprising polystyrene, a (meth)acrylic functional additive having a glass transition temperature of from 50°C to 160°C, a first tackifier compatible with the midblock segment and containing a hydrocarbon, and a second tackifier compatible with the end block segments and containing a polyphenylene ether. These compositions are useful in providing pressure-sensitive adhesives that are melt processible, display a high temperature resistance, and effectively bond to low surface energy substrates.
Abstract:
The present disclosure relates to a method of adhering a first part to a second part, wherein the first part and the second part are used for outdoor applications and comprise a thermoplastic or a thermosetting organic polymer. The present disclosure is also directed to a composite assembly comprising: a) a first part and a second part used for outdoor applications and comprising a thermoplastic or a thermosetting organic polymer; and b) a multilayer pressure sensitive adhesive foam tape as described in the present disclosure, wherein the first pressure sensitive adhesive layer is adhered to the first part, and the second pressure sensitive adhesive layer is adhered to the second part.
Abstract:
A pressure-sensitive adhesive is provided that is a dried product of a latex composition, which is formed from an emulsion composition. The latex composition and the emulsion composition are also provided. The emulsion composition has droplets that contain various monomers plus a (meth)acrylate polymer and a hydrogenated hydrocarbon tackifier dissolved in the monomers. Additionally, an article containing a layer of the pressure-sensitive adhesive and a method of forming the pressure-sensitive adhesive are provided. The pressure-sensitive adhesives often have both high peel adhesion and high shear strength (i.e., high cohesive strength or high shear holding power).
Abstract:
Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 10 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.
Abstract:
An adhesive article including: a coextruded polymeric backing that includes: a first layer including an amorphous polyamide, the first layer having first and second opposing major surfaces; and a second layer including a polar-modified polyolefin, the second layer having first and second opposing major surfaces; wherein the first major surface of the second layer is in contact with the second major surface of the first layer; and an acrylic pressure sensitive adhesive layer in contact with the first major surface of the first layer of the backing.
Abstract:
Pressure-sensitive adhesive compositions and articles that include a layer of the pressure-sensitive adhesive compositions are provided. The pressure-sensitive adhesive compositions are particularly well suited for use with substrates that have been considered to have difficult to bond to surfaces such as those routinely encountered in the automotive industry. For example, the pressure-sensitive adhesive can be adhered to clear coat compositions, painted surfaces, and various polymeric materials having low energy surfaces (e.g., surfaces having a surface energy no greater than 35 dynes per centimeter).