公开(公告)号：DE3606706A1

公开(公告)日：1986-09-04

申请号：DE3606706

申请日：1986-03-01

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA KICHINARI ,  KONO YASUO ,  MIYAMOTO TSUTOMU ,  KOTOKU YASUHIKO ,  TAKAYA HARUO

IPC: B01J20/10 ,  B01J20/30 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/87 ,  C01B39/38 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C09K3/00 ,  C01B33/20 ,  B01J29/04 ,  C07C1/24

Abstract: Methanol and/or dimethyl ether is converted into lower olefins by bringing a gas stream containing methanol and/or dimethyl ether into contact with a catalyst which contains an aluminosilicate or gallosilicate containing a divalent metal and which has been obtained by hydrothermal treatment of a solution containing a source of metal oxides using a monohydric alcohol having from 1 to 8 carbon atoms as crystallisation aid.

公开(公告)号：JPS61200928A

公开(公告)日：1986-09-05

申请号：JP4249285

申请日：1985-03-04

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA YOSHINARI ,  KONO YASUO ,  KAMITOKU YASUHIKO ,  MIYAMOTO TSUTOMU ,  TAKATANI HARUO

IPC: B01J20/10 ,  B01J20/30 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/87 ,  C01B39/38 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C09K3/00

Abstract: PURPOSE:To produce a lower olefin from methanol or dimethyl ether, in high efficiency, by preparing a crystalline alumino (or gallo)-silicate containing a specific bivalent metal using a 1-8C monohydric alcohol as the crystallizing agent, and using the obtained silicate as a catalyst. CONSTITUTION:A lower olefin such as ethylene propylene, etc., can be produced from methanol and/or dimethyl ether, stably, in high yield and selectivity, by using a catalyst consisting of a bivalent metal-containing crystalline aluminosilicate or gallosilicate of formula (M is alkali metal or H; M is one or more bivalent metal selected from Ca, Mg, Sr, Mn, Cu, Ni and Co; M is Al or Ga; 0.1 0; 20

公开(公告)号：JPS62207231A

公开(公告)日：1987-09-11

申请号：JP4936786

申请日：1986-03-06

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA YOSHINARI ,  KONO YASUO ,  OKADO HIDEO ,  HAGIWARA HIROYUKI ,  TAKATANI HARUO

IPC: B01J29/00 ,  B01J29/04 ,  B01J29/86 ,  C01B39/04 ,  C01B39/12 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00

Abstract: PURPOSE:To stably obtain the titled compound from methanol and/or dimethyl ether in high selectivity for a long period, by using a specific catalyst prepared by modifying an alkaline earth metal-containing aluminoborosilicate with an alkaline earth metal-containing compound. CONSTITUTION:Methanol or ethanol or both in the vapor phase are brought into contact with a catalyst to produce the titled compound. In the process, a modified catalyst prepared by hydrothermal treatment of a raw material satisfying the respective molar ratios as follows; 12-3,000 SiO2/Al2O3, 1-1,000 SiO2/B2O3, 0.02-10 OH /SiO2, 1-2,000 H2O/SiO2 and 0.01-3 tetra propylammonium compound/SiO2 and atomic ratio as follows; 0.03-300 alkaline earth metal/Al at 80-250 deg.C temperature and blending or supporting >=0.25wt% alkaline earth metal expressed in terms of the metal on the resultant fired zeolite having the composition expressed by the formula (M is alkali metal or H; M is alkaline earth metal; a is 0-2; b is 0.1-100; c is 12-3,000; n is 0-30) is used to improve the catalyst life.

公开(公告)号：JPS6251630A

公开(公告)日：1987-03-06

申请号：JP19039485

申请日：1985-08-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA YOSHINARI ,  OKADO HIDEO ,  SHOJI HIROSHI ,  KONO YASUO ,  TAKATANI HARUO

IPC: C07C1/20 ,  B01J29/00 ,  C07B61/00 ,  C07C1/00 ,  C07C11/02 ,  C07C67/00

Abstract: PURPOSE:In producing the titled compound in a gaseous phase from methanol and/or dimethyl ether, to obtain the aimed compound stably in high selectively for a long period, by using a alkaline earth metal modified zeolite catalyst containing an alkaline earth metal. CONSTITUTION:The titled compound is advantageously obtained by bringing methanol and/or dimethyl ether into contact in a gaseous phase with a catalyst modified by treating hydrothermally a raw material having a composition satisfying molar ratios of SiO2/Al2O3=10-3,000, OH /SiO2=0.02-10, H2O /SrO2=1-2,000 and tetrabutyl compound/SiO4=0.01-4 and an atomic ratio of alkaline earth metal/Al=0.03-300 at 80-200 deg.C to give a calcined material having a composition shown by the fomrula (M is alkali metal; M is alkaline earth metal; a is 0-2.0; b is 0.1-100; c is 10-3,000; n is 0-30), treating the calcined material with an alkaline earth metan containing compound in a solid state or in solution so that >=0.25wt% calculated as metal of the alkaline earth metal is blended with or supported on zeolite.

公开(公告)号：JPS62105917A

公开(公告)日：1987-05-16

申请号：JP24543585

申请日：1985-11-01

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA YOSHINARI ,  KONO YASUO ,  OKADO HIDEO ,  SHIN SHIGEMITSU ,  TAKATANI HARUO

IPC: C07C1/20 ,  B01J29/00 ,  B01J29/04 ,  C01B39/04 ,  C01B39/12 ,  C01B39/20 ,  C01B39/30 ,  C07B61/00 ,  C07C1/00 ,  C07C11/02 ,  C07C67/00

Abstract: PURPOSE:To produce the titled novel catalyst, capable of efficiently producing a lower olefin and having a specific X-ray diffraction pattern, by adding a boron source and alkaline earth metal source to a silica source, alumina source and alkali metal source to give a specific composition, and subjecting the mixture to hydrothermal reaction. CONSTITUTION:Raw materials are mixed so as to satisfy composition of 12-3,000 molar ratio (SiO2/Al2O3), 1-1,000 molar ratio (SiO2/B2O3), 0.02-10 molar ratio (OH /SiO2), 1-2,000 molar ratio (H2O/SiO2), 0.01-3 molar ratio (terapropylammonium/SiO2) and 0.03-300 atomic ratio (alkaline earth metal/Al). The resultant mixture is then stirred while heating at about 80-300 deg.C for about 1-200hr and subjected to hydrothermal reaction to produce the aimed alkaline earth metal-containing aluminoborosilicate, having the composition expressed by the formula (M is alkali metal and/or hydrogen atom; M is alkaline earth metal; a is 0-2; b is 0.1-100; c is 12-3,000; n is 0-30) and having an X-ray diffraction pattern shown in the table.