公开(公告)号：DE3518094A1

公开(公告)日：1985-11-28

申请号：DE3518094

申请日：1985-05-21

Applicant: AGENCY IND SCIENCE TECHN

Inventor： OKADO HIDEO ,  SHOJI HIROSHI ,  TAKAYA HARUO ,  KAWAMURA KICHINARI ,  YAMAZAKI YASUYOSHI

IPC: B01J29/00 ,  B01J29/40 ,  C01B39/00 ,  C01B39/04 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C01B33/26 ,  B01J29/28 ,  C07C1/24

Abstract: A zeolite material obtained by modifying a crystalline aluminosilicate having the following empirical formula: xM2O.yM'O.Al2O3.zSiO2.nH2O wherein M is an exchangeable cation selected from the group consisting of alkali metals, hydrogen and mixtures thereof, M' is an alkaline earth metal, x is between 0 and 1.5, y is between 0.2 and 40, z is between 50 and 3000 and n is between 0 and 40 and wherein x+y is at least 1.2, with an alkaline earth metal compound. The modifying may be by impregnation or by mere mixing. The zeolite material is useful as catalyst for converting methanol and/or dimethyl ether into lower olefins.

公开(公告)号：DE3606706A1

公开(公告)日：1986-09-04

申请号：DE3606706

申请日：1986-03-01

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWAMURA KICHINARI ,  KONO YASUO ,  MIYAMOTO TSUTOMU ,  KOTOKU YASUHIKO ,  TAKAYA HARUO

IPC: B01J20/10 ,  B01J20/30 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/87 ,  C01B39/38 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C09K3/00 ,  C01B33/20 ,  B01J29/04 ,  C07C1/24

Abstract: Methanol and/or dimethyl ether is converted into lower olefins by bringing a gas stream containing methanol and/or dimethyl ether into contact with a catalyst which contains an aluminosilicate or gallosilicate containing a divalent metal and which has been obtained by hydrothermal treatment of a solution containing a source of metal oxides using a monohydric alcohol having from 1 to 8 carbon atoms as crystallisation aid.

公开(公告)号：DE3341902A1

公开(公告)日：1984-06-14

申请号：DE3341902

申请日：1983-11-19

Applicant: AGENCY IND SCIENCE TECHN

Inventor： OKADO HIDEO ,  HASHIMOTO KAZUO ,  KAWAMURA KICHINARI ,  YAMAZAKI YASUYOSHI ,  TAKAYA HARUO

IPC: B01J29/00 ,  B01J29/70 ,  B01J29/74 ,  C01B39/04 ,  C01B39/38 ,  C01B39/40 ,  C01B39/48 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C10G3/00 ,  C01B33/28 ,  B01J29/06 ,  C07C1/24

Abstract: A crystalline aluminosilicate having the following empirical formula: xM2O.yM'O.Al2O3.zSiO2.nH2O wherein M is an exchangeable cation selected from the group consisting of alkali metals, hydrogen and mixtures thereof, M' is an alkaline earth metal, x is between 0 and 1.5, y is between 0.2 and 40, z is between 12 and 3000 and n is between 0 and 40 and wherein x+y is 1.2 or more, said aluminosilicate having the X-ray diffraction lines of Table 1 of the specification. The crystalline aluminosilicate material is obtained by providing a reaction mixture containing water, a tetrapropylammonium compound and a source of an alkali metal oxide, an oxide of silicon, an oxide of aluminum and an oxide of an alkaline earth metal and having a composition falling within the following ranges: SiO2/Al2O3 molar ratio: 12-3000 OH-/SiO2 molar ratio: 0.02-10 H2O/SiO2 molar ratio: 1-1000 tetrapropylammonium ion/SiO2 molar ratio: 0.02-2 alkaline earth metal/Al atomic ratio: 0.03-300, and maintaining the mixture at a temperature and for a period of time sufficient to form crystals of the aluminosilicate. The aluminosilicate is useful as catalyst for converting methanol and/or dimethyl ether into lower olefins.

公开(公告)号：DE3237389A1

公开(公告)日：1983-04-28

申请号：DE3237389

申请日：1982-10-08

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KOTOKU YASUHIKO ,  WATANABE HIDEO ,  KAWAMURA KICHINARI ,  SHIMAZAKI YUZI ,  SHIN SHIGEMITSU ,  TAKAYA HARUO

IPC: B01J29/70 ,  B01J29/87 ,  C01B33/20 ,  C01B39/08 ,  C01B39/36 ,  C07C1/20 ,  B01J29/04 ,  B01J29/28 ,  C01B33/26 ,  C07C1/24 ,  C07C11/02

Abstract: The invention proposes a new class of crystalline aluminium silicates and gallium silicates having a crystal structure differing markedly from the conventional silicates with respect to the X-ray diffraction diagrams. The novel crystalline metal silicates are prepared hydrothermically by heating an aqueous mixture, which contains the starting materials for silicon dioxide, aluminium oxide or gallium oxide and alkali metal ions in defined proportions and additionally an aliphatic alcohol, for example n-propyl and n-butyl alcohols, in a defined amount. The crystalline metal silicates prepared in this manner are, in particular after conversion into the proton form by ion exchange techniques, usable as catalysts for the catalytic conversion of methyl alcohol or dimethyl ether in the gaseous form into lower olefins, such as for example ethylene and propylene with high yield and high selectivity.