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1.发明授权
公开(公告)号：EP0706998B1
公开(公告)日：1998-10-14
申请号：EP95110418.1
申请日：1995-07-04
Applicant: ELF ATOCHEM NORTH AMERICA, INC.
Inventor： Gernon, Michael David , Sandler, Stanley Robert
IPC: C07C319/06 , C07C321/04
CPC classification number: C07C319/06 , C07C321/04
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公开(公告)号：EP0333980B1
公开(公告)日：1993-07-28
申请号：EP89100500.1
申请日：1989-01-12
Inventor： Sandler, Stanley Robert
CPC classification number: C07C69/54
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3.发明公开Process for the transfer of alkyl groups in dialkyl trisulfides and mercaptans 失效一种用于传送二烷基硫醚和硫醇的烷基方法。
公开(公告)号：EP0614885A1
公开(公告)日：1994-09-14
申请号：EP93117418.9
申请日：1993-10-27
Applicant: ELF ATOCHEM NORTH AMERICA, INC.
Inventor： Sandler, Stanley Robert
IPC: C07C319/24 , C07C321/14
CPC classification number: C07C319/24 , C07C319/22 , C07C321/14
Abstract: The alkyl groups of dialkyl trisulfides are exchanged with the alkyl groups of mercaptans by reacting a tertiary dialkyl trisulfide with an alkyl mercaptan having a greater number of carbon atoms in its alkyl group than said trisulfide in the presence of an acidic or basic type catalyst for a time and a temperature sufficient to produce a dialkyl trisulfide having at least one transferred alkyl group from said mercaptan.
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4.发明公开Process for the preparation of alkane- and arenesulfonamides 失效Verfahren zur Herstellung von Alkan- und Arensulfonamiden。
公开(公告)号：EP0439687A1
公开(公告)日：1991-08-07
申请号：EP90120562.5
申请日：1990-10-26
Applicant: ATOCHEM NORTH AMERICA, INC.
IPC: C07C303/38 , C07C311/03
CPC classification number: C07C303/38 , C07C311/03
Abstract: A process for the preparation of alkane- and arenesulfonamides in high purity and yield is provided. Ammonia or alkylamine is reacted under boiling conditions with an alkane- or arenesulfonyl halide in the absence of an added solvent. The heat of reaction is dissipated by the heat of vaporization of the ammonia or alkylamine.
Abstract translation: 提供了一种以高纯度和高产量制备烷烃和芳烃磺酰胺的方法。 在不存在加入的溶剂的情况下，氨或烷基胺在沸腾条件下与烷烃或芳烃磺酰卤反应。 反应的热量由氨或烷基胺的蒸发热消散。
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5.发明公开Photochemical preparation of 3-(organothio) aldehydes 失效Photochemisches Verfahren zur Herstellung von 3-（有机硫）醛。
公开(公告)号：EP0417386A1
公开(公告)日：1991-03-20
申请号：EP90107565.5
申请日：1990-04-20
Applicant: ATOCHEM NORTH AMERICA, INC.
Inventor： Sandler, Stanley Robert
IPC: C07C323/22 , C07C319/18
CPC classification number: C07C319/18 , C07C323/22
Abstract: A process is disclosed for the preparation of 3-(organothio)aldehydes by reacting a mercaptan with an α, β-unsaturated aliphatic aldehyde under actinic radiation in the absence of an oxygen-containing gas wherein the mercaptan and aldehyde are mixed in substantially equimolar amount and the reaction temperature ranges from about 2° to less than 60°C.
Abstract translation: 公开了一种制备3-（有机硫）醛的方法，该方法是在不存在含氧气体的情况下，通过在光化辐射下使硫醇与α，β-不饱和脂族醛反应，其中硫醇和醛以基本上等摩尔量混合 反应温度为约2℃至小于60℃。
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Patent Agency Ranking6.发明公开Propanone 1,3-disulfonic acid as an esterification catalyst 失效Propanon-1,3-disulfonsäureals Veresterungskatalysator。
公开(公告)号：EP0333980A1
公开(公告)日：1989-09-27
申请号：EP89100500.1
申请日：1989-01-12
Inventor： Sandler, Stanley Robert
CPC classification number: C07C69/54
Abstract: The present invention discloses the use of propanone 1,3-disulfonic acid as an esterification catalyst. This catalyst has a significantly higher reaction rate when compared to conventional esterification catalysts, such as methanesulfonic acid and sulfuric acid.
Abstract translation: 本发明公开了丙酮1,3-二磺酸作为酯化催化剂的用途。 当与常规酯化催化剂如甲磺酸和硫酸相比时，该催化剂具有显着更高的反应速率。
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7.发明公开Process for the manufacture of high purity linear c4+ alkyl mercaptans 失效Verfahren zur Herstellung von sehr reinen C4 + -Alkylmercaptanen
公开(公告)号：EP0706998A1
公开(公告)日：1996-04-17
申请号：EP95110418.1
申请日：1995-07-04
Applicant: ELF ATOCHEM NORTH AMERICA, INC.
Inventor： Gernon, Michael David , Sandler, Stanley Robert
IPC: C07C319/06 , C07C321/04
CPC classification number: C07C319/06 , C07C321/04
Abstract: Linear C₄+ alkyl mercaptans of high purity are prepared by the reaction of a di-linear(C₄+) alkyl sulfide with hydrogen sulfide at elevated temperature in the presence of an alumina material selected from gamma/eta alumina or gamma/eta alumina impregnated with up to 20% w/w of titania or rhenium oxide.
Abstract translation: 直链烷基二硫化物通过与H 2 S反应的催化剂转化成相应的硫醇，所述催化剂包含任选地浸渍有至多20重量％的二氧化钛和/或氧化铼的eta /γ氧化铝。
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8.发明公开2,4-pentanedionemonosulfonic acid and method for preparing the same 失效2,4-Pentandionmonosulfonsäureund Verfahren zu ihrer Herstellung。
公开(公告)号：EP0419796A1
公开(公告)日：1991-04-03
申请号：EP90114256.2
申请日：1990-07-25
Applicant: ATOCHEM NORTH AMERICA, INC.
Inventor： Sandler, Stanley Robert
IPC: C07C303/08 , C07C309/07
CPC classification number: C07C309/07 , C07C303/08
Abstract: 2,4-pentanedionemonosulfonic acid is prepared by reacting chlorosulfonic acid with 2,4-pentanedione, preferably in the presence of an anhydrous solvent. The method of this invention generally yields 2,4-pentanedionemonosulfonic acid in excess of about 75 percent. The novel pentanedionesulfonic acid, 2,4-pentanedionemonosulfonic acid (acetylacetone sulfonic acid) is disclosed.
Abstract translation: 通过使氯磺酸与2,4-戊二酮反应，优选在无水溶剂的存在下反应来制备2,4-戊二酮一磺酸。 本发明的方法通常产生超过约75％的2,4-戊二酮二磺酸。 公开了新戊二酸磺酸，2,4-戊二酮一磺酸（乙酰丙酮磺酸）。
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9.发明公开Process for the preparation of unsymmetrical alkyl trisulfides and products 失效一种不对称Alkyltrisulfiden的准备和产品的工艺过程。
公开(公告)号：EP0614884A1
公开(公告)日：1994-09-14
申请号：EP93111616.4
申请日：1993-07-20
Applicant: ELF ATOCHEM NORTH AMERICA, INC.
Inventor： Sandler, Stanley Robert
IPC: C07C319/22
CPC classification number: C07C319/22 , C07C321/14
Abstract: A process is disclosed for the preparation of unsymmetrical dialkyl trisulfides by the reaction of dialkyl trisulfides and olefins in the presence of an acidic-type catalyst whereby alkyl groups are exchanged. Novel mixtures of symmetrical and unsymmetrical dialkyl trisulfides are also disclosed.
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公开(公告)号：EP0293672B1
公开(公告)日：1991-10-23
申请号：EP88107950.3
申请日：1988-05-18
Inventor： Sandler, Stanley Robert
IPC: C07C309/05 , C07C303/08
CPC classification number: C07C309/00
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