CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1
    1.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 审中-公开
    催化剂组分对于BUTENE-1的聚合

    公开(公告)号:WO2013182474A1

    公开(公告)日:2013-12-12

    申请号:PCT/EP2013/061158

    申请日:2013-05-30

    Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

    Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法,包括(a)包含Mg,Ti和下式(I)的电子给体化合物的固体催化剂组分,其中R基团等于或不同 彼此相同的是C 1 -C 15烃基,R 1 -R 2基彼此相同或不同,是氢,卤素或C 1 -C 15烃基,任选地含有选自卤素,P,S,N的杂原子和 Si,n和m为0-3的整数,条件是它们中的至少一个不同于0; (b)烷基铝助催化剂和(c)外电子给体

    1-BUTENE TERPOLYMERS
    3.
    发明申请
    1-BUTENE TERPOLYMERS 审中-公开
    1-BOTENE TERPOLYMERS

    公开(公告)号:WO2009115402A1

    公开(公告)日:2009-09-24

    申请号:PCT/EP2009/052364

    申请日:2009-02-27

    Abstract: A terpolymer of 1-butene, ethylene and a at least a C 8 -C 12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C 8 -C 12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.

    Abstract translation: 1-丁烯,乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物,其含有0.1%至5%(摩尔)的乙烯衍生单元,和1%为20%(摩尔)的C 8 -C 12α-烯烃 具有以下性质:i)等于或等于90%的全同立构五单元mmmm; 低于4的五元组(mmrr + mrrm)和13C NMR不能检测到的五元组。 ii)在135℃的四氢化萘中测得的特性粘度(Ⅳ)为0.8至5.0dL / g; iii)通过DSC(TmI)和C8-C12α-烯烃含量测量的熔点满足以下关系:TmI -0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量,TmI是最高的熔融峰 在通过DSC测量的第一熔融转变中,不能检测到熔点Tm1。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1
    9.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 有权
    KATALYSATONOMPONENTEN ZUR POLYMERISATION VON BUTEN-1

    公开(公告)号:EP2859026A1

    公开(公告)日:2015-04-15

    申请号:EP13725706.9

    申请日:2013-05-30

    Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C
    1 -C
    15 hydrocarbon groups, the R
    1 -R
    2 groups, equal to or different from each other, are hydrogen, halogen or C
    1 -C
    15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

    Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法,包括(a)包含Mg,Ti的固体催化剂组分和下式(I)的电子给体化合物:其中R基团等于或不同于 彼此是C 1 -C 15烃基,R 1 -R 2基彼此相同或不同,是氢,卤素或C 1 -C 15烃基,任选地含有选自卤素,P ,S,N和Si,n和m是0至3的整数,条件是它们中的至少一个不同于0; (b)烷基铝助催化剂和(c)外电子给体

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