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公开(公告)号:DE59610109D1
公开(公告)日:2003-03-13
申请号:DE59610109
申请日:1996-09-10
Applicant: BASF AG
Inventor: TRUEBENBACH DR , HAGEMEYER DR , LAUTH PROF DR , DINGERDISSEN DR , BROECKER DR , FLICK DR
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公开(公告)号:DE59710290D1
公开(公告)日:2003-07-24
申请号:DE59710290
申请日:1997-03-24
Applicant: BASF AG
Inventor: KAIBEL DR , BROECKER DR , STROEZEL MANFRED
IPC: B01F5/06 , B01J8/00 , B01J8/06 , B01J8/18 , B01J8/20 , B01J8/22 , B01J8/34 , B01J19/24 , C07C45/62
Abstract: In carrying out reactions in a reactor containing a liquid phase in which a catalyst is suspended, and where a gaseous phase may be present, the liquid and gas phases pass, at least partly, through a device having openings or passages whose hydraulic diameter is 0.5-20 (1-3) mm. Also claimed is the reactor including a device having openings or passages in it built so that liquid or gas flow through it during the reaction.
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公开(公告)号:DE50011547D1
公开(公告)日:2005-12-15
申请号:DE50011547
申请日:2000-08-01
Applicant: BASF AG
Inventor: BROECKER DR , HAAKE DR , KAIBEL DR , ROHRBACHER GERD , SCHWAB DR , STROEZEL MANFRED
IPC: B01J23/42 , B01J8/00 , B01J10/00 , B01J19/24 , B01J19/26 , B01J32/00 , B01J35/04 , B01J35/06 , C07B61/00 , C07C5/10 , C07C13/18 , F28D9/04
Abstract: The apparatus for carrying out reactions in the gaseous, liquid and solid phases comprises a liquid stream-gas compressor for producing a reaction fluid, a reactor charged with metal braiding coated with catalyst, and a feed line. The apparatus for carrying out reactions in the gaseous, liquid and solid phases comprises a liquid stream-gas compressor (6) for producing a reaction fluid by dispersing a gas phase in a liquid phase; a reactor (1) having an inlet and an outlet and a reaction chamber limited by heat-deviating walls, the reactor being charged with a metal braiding coated with catalyst; and a line (7) feeding the reaction fluid from the compressor to the reactor inlet and is short so that the degree of dispersibility of the fluid does not change during the passage through the line. An Independent claim is also included for a process for carrying out reactions in the gaseous, liquid and solid phases comprising producing a reaction fluid by dispersion of a gaseous phase in a liquid phase; feeding the reaction fluid produced through the reactor; exchanging reaction heat on the walls of the reactor chamber; and separating the reaction fluid into a gas phase and a liquid phase.
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公开(公告)号:DE59610108D1
公开(公告)日:2003-03-13
申请号:DE59610108
申请日:1996-09-10
Applicant: BASF AG
Inventor: TRUEBENBACH DR , HAGEMEYER DR , LAUTH PROF DR , DINGERDISSEN DR , BROECKER DR , FLICK DR
Abstract: Monomodal or polymodal catalyst or catalyst support has a BET specific surface of 0.01-250 m /g and a monomodal or polymodal pore size distribution with a mean pore dia. of 50-300000 nm (measured by the Hg pressure porosimetry method), 10-95%, 10-80%, 50-95% and/or 50-80% of the pore vol. respectively being of 0.1-3, 0.4-3, 0.1-1 and/or 0.4-1 times the mean pore dia. and the median width of the pore size distribution being /g and a pore size distribution of 50-300000 nm (measured by the Hg pressure porosimetry method).
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公开(公告)号:DE59611188D1
公开(公告)日:2005-03-10
申请号:DE59611188
申请日:1996-08-16
Applicant: BASF AG
Inventor: STROEZEL MANFRED , BROECKER DR , JANSEN HELMUT , KAIBEL DR
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公开(公告)号:DE59903222D1
公开(公告)日:2002-12-05
申请号:DE59903222
申请日:1999-03-26
Applicant: BASF AG
Inventor: BROECKER DR , KAIBEL DR , AQUILA DR , FUCHS HARTWIG , WEGNER DR , STROEZEL MANFRED
IPC: B01J23/44 , B01J8/20 , B01J8/22 , B01J19/24 , B01J23/46 , C07B61/00 , C07C45/62 , C07C47/21 , C07C49/04
Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.
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公开(公告)号:DE59706719D1
公开(公告)日:2002-05-02
申请号:DE59706719
申请日:1997-04-25
Applicant: BASF AG
Inventor: RUEHL THOMAS DR , BREITSCHEIDEL DR , BROECKER DR , REIF DR , HENKELMANN DR , BRAUCH KARL HEINZ , HENNE DR
IPC: B01J23/46 , C07B35/02 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/149 , C07C29/20 , C07C35/08 , C07C209/72 , C07C211/40 , C08F8/04
Abstract: Reacting an organic compound (I) in the presence of a catalyst, in which the catalyst comprises a homogeneous ruthenium compound or a mixture of two or more such compounds, deposited in situ on a support. Also claimed is a supported catalyst which is obtained by deposition of Ru compound(s) as above, by passing a solution of Ru compound(s) through or over a support.
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