公开(公告)号：DE59610109D1

公开(公告)日：2003-03-13

申请号：DE59610109

申请日：1996-09-10

Applicant: BASF AG

Inventor： TRUEBENBACH DR ,  HAGEMEYER DR ,  LAUTH PROF DR ,  DINGERDISSEN DR ,  BROECKER DR ,  FLICK DR

IPC: C12N11/14 ,  B01D53/86 ,  B01D53/94 ,  B01J21/00 ,  B01J21/04 ,  B01J21/06 ,  B01J23/00 ,  B01J23/10 ,  B01J27/00 ,  B01J27/224 ,  B01J27/24 ,  B01J29/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  C01B7/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C15/46 ,  C07C37/06 ,  C07C37/07 ,  C07C39/06 ,  C07D203/00

公开(公告)号：DE59606334D1

公开(公告)日：2001-02-22

申请号：DE59606334

申请日：1996-06-27

Applicant: BASF AG

Inventor： DINGERDISSEN DR ,  HERRMANN JUERGEN ,  ELLER DR

IPC: B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  C07B61/00 ,  C07C209/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/01 ,  C07C211/33

Abstract: (a) Zeolites, (b) aluminosilicates, (c) phosphates prepd. hydrothermally, (d) meso-porous oxides with high surface area, (e) pillared interlayered clays, (f) amorphous oxides prepd. by the sol-gel process and/or (g) acid-treated foliated silicates are used as the heterogeneous catalyst in the prepn. of amines (I) by reacting mixt. obtd. by cracking petroleum fractions (II) with NH3 or prim. or sec. amines of formula HN(R )R (III) at 200-350 degrees C and 100-300 bar; (in which R , R = H, 1-20 C alkyl, 2-20 C alkenyl, 2-20 C alkynyl, 3-20 C cycloalkyl, 4-20 C alkyl-cycloalkyl, 4-20 C cycloalkyl-alkyl, aryl, 7-20 C alkylaryl or 7-20 C aralkyl; or R , R = a 2-12 C alkylene di-chain).

公开(公告)号：DE59610108D1

公开(公告)日：2003-03-13

申请号：DE59610108

申请日：1996-09-10

Applicant: BASF AG

Inventor： TRUEBENBACH DR ,  HAGEMEYER DR ,  LAUTH PROF DR ,  DINGERDISSEN DR ,  BROECKER DR ,  FLICK DR

IPC: C12M1/40 ,  B01J21/00 ,  B01J27/00 ,  B01J29/00 ,  B01J35/10 ,  B01J37/00

Abstract: Monomodal or polymodal catalyst or catalyst support has a BET specific surface of 0.01-250 m /g and a monomodal or polymodal pore size distribution with a mean pore dia. of 50-300000 nm (measured by the Hg pressure porosimetry method), 10-95%, 10-80%, 50-95% and/or 50-80% of the pore vol. respectively being of 0.1-3, 0.4-3, 0.1-1 and/or 0.4-1 times the mean pore dia. and the median width of the pore size distribution being /g and a pore size distribution of 50-300000 nm (measured by the Hg pressure porosimetry method).