公开(公告)号：JP2000073035A

公开(公告)日：2000-03-07

申请号：JP24009599

申请日：1999-08-26

Applicant: BASF AG

Inventor： KIELHORN-BAYER SABINE DR ,  DAMES BURKHARDT DR ,  SCHUMACHER KARL-HEINZ DR

IPC: B32B27/00 ,  B32B7/12 ,  C08F8/44 ,  C09J4/00 ,  C09J133/02 ,  C09J151/00

Abstract: PROBLEM TO BE SOLVED: To obtain an adhesive capable of being used for laminating lustous films by adding the aqueous dispersion of a polymer comprising a main monomer, an ethylenic unsaturated acid having a metal salt, and one or more other monomers in a specific ratio. SOLUTION: This adhesive contains the aqueous dispersion of a polymer formed from radically polymerizable compounds as a binder. Therein, a monomer in an amount of 0.1-20 wt.% based on the total amount of the monomers is an ethylenic unsaturated acid, and at least 20 mol.% of the acid group exist in the form of at least divalent metal (preferably Ca, Zn of Mg) salt. The polymer preferably comprises (A) 20-99.9 wt.% of a main monomer selected from 1-20C alkyl (meth)acrylates,

公开(公告)号：JPH11140409A

公开(公告)日：1999-05-25

申请号：JP24503698

申请日：1998-08-31

Applicant: BASF AG

Inventor： DAMES BURKHARDT DR ,  SCHUMACHER KARL-HEINZ DR ,  FRICKE HANS-JOACHIM

IPC: B32B27/30 ,  B32B7/12 ,  B32B27/10 ,  C09J133/08

Abstract: PROBLEM TO BE SOLVED: To obtain a laminated product composed of e.g. a high-gloss film and a paper with good adhesiveness by using an aqueous dispersion of a polymer made from a main monomer such as specific alkyl acrylate or alkyl methacrylate, a submonomer such as ethylenic unsaturated acid, and other monomer(s). SOLUTION: This laminated product by mutually bending large-area base materials is obtained by using a polymer as an adhesive which is prepared from (A) 5-95 wt.% of a 4C alkyl acrylate, (B) 5-95 wt.% of a 1-2C alkyl acrylate, (C) 0-50 wt.% of a main monomer selected from 1-2C alkyl methacrylates, 4C alkyl methacrylates, 3C and 5-16C alkyl (meth)acrylates, and vinyl aromatic compounds and others, (D) 0-20 wt.% of a submonomer selected from ethylenic unsaturated acids, acids anhydrides, ethylenically unsaturated nitriles or amido-and hydroxyl-contg. ethylenically unsaturated compounds, and (E) 0-20 wt.% of other monomer(s).

公开(公告)号：DE19801442A1

公开(公告)日：1999-07-22

申请号：DE19801442

申请日：1998-01-16

Applicant: BASF AG

Inventor： GERST MATTHIAS DR ,  SCHULER BERNHARD DR ,  DAMES BURKHARDT DR

IPC: C08F2/26 ,  C08F2/44 ,  C08J3/00 ,  C08J3/03 ,  C08K5/36 ,  C08K5/42 ,  C08L33/06 ,  C08L57/00 ,  C08L101/00 ,  C08F12/00 ,  C08F18/02 ,  C08F20/10 ,  C08F22/10 ,  C08F36/06 ,  C08F14/06 ,  C08F14/08 ,  C08F10/00 ,  C08K5/10

Abstract: A method for improving the thermal and/or mechanical stability of aqueous polymer dispersions by adding salt(s) of bis-(4-18C alkyl esters) of sulfonated 4-8C dicarboxylic acids to the dispersion.

公开(公告)号：DE19741185A1

公开(公告)日：1999-03-25

申请号：DE19741185

申请日：1997-09-18

Applicant: BASF AG

Inventor： RUPANER ROBERT DR ,  BAUER GERHARD DR ,  LAWRENZ SVEN ,  HEIBEL CLAUDIA DR ,  DOBBELAAR JOHANNES DR ,  DAMES BURKHARDT DR

IPC: C08F6/00 ,  C08F6/06

Abstract: The residual monomer content of aqueous polymer dispersions is reduced by generating radicals in the dispersion with a redox initiator system in presence of a 1-20 C carboxylic acid with a mol. wt. of not more than 300 and with no polymerisable carbon-carbon double bonds.

公开(公告)号：DE19738185A1

公开(公告)日：1999-03-04

申请号：DE19738185

申请日：1997-09-02

Applicant: BASF AG

Inventor： DAMES BURKHARDT DR ,  SCHUMACHER KARL-HEINZ DR ,  FRICKE HANS-JOACHIM

IPC: B32B27/30 ,  B32B7/12 ,  B32B27/10 ,  C09J133/08 ,  C09J133/20 ,  C08J5/12

Abstract: Laminates are produced by bonding substrates of large area with an aqueous adhesive dispersion of a polymer of 5-95 wt.% 4C alkyl acrylate, 5-95 wt.% 1 or 2C alkyl acrylate and optionally other monomer(s). The other monomers are 0-50 wt.% primary monomers, selected from 1-2C alkyl methacrylate, 4C alkyl methacrylates, 3 and 5-16C alkyl (meth)acrylates, vinyl aromatics and ester esters of carboxylic acids containing ≤ 20C; 0-20 wt.% secondary monomers, selected from ethylenically unsaturated acids, anhydrides, nitriles, amides and hydroxyl compounds; and 0-20 wt.% other monomers. An Independent claim is also included for (a) the production of the laminates by bonding with this adhesive.

公开(公告)号：DE19628142A1

公开(公告)日：1998-01-15

申请号：DE19628142

申请日：1996-07-12

Applicant: BASF AG

Inventor： DAMES BURKHARDT DR ,  MATHAUER KLEMENS DR ,  MAECHTLER WALTER DR

IPC: C08F2/22 ,  C08F2/24

Abstract: In the production of aqueous polymer dispersions by free radical emulsion polymerisation of monomers, a mini-emulsion (I) is added before or during polymerisation. (I) is an aqueous emulsion, stabilised with a surfactant, which contains emulsified monomer droplets with a particle size of 10-500 nm and a co-stabiliser, dissolved in the monomer, which is at least twice as soluble in the monomer as it is in water. Also claimed are polymer dispersions obtained in this way.

公开(公告)号：DE19727060A1

公开(公告)日：1999-01-07

申请号：DE19727060

申请日：1997-06-25

Applicant: BASF AG

Inventor： GERST MATTHIAS DR ,  SCHULER BERNHARD DR ,  DAMES BURKHARDT DR ,  URBAN DIETER DR ,  WIESE HARM DR ,  MORRISON BRADLEY RONALD DR

IPC: C08F2/22 ,  C08F4/40 ,  C08F110/06 ,  C08F257/02 ,  C08F291/00 ,  C09K3/10 ,  C09D157/00 ,  D06M15/21 ,  C08J3/03 ,  C09J9/00 ,  C14C9/00

Abstract: Preparation of aqueous polymer dispersions of wt. average particle diameter above 400 nm comprises radically polymerising ethylenically unsaturated monomers in the presence of a surface active agent (emulsifier) and 0.001-1 wt.% seed polymer of monomodal particle size where, when 1% monomer conversion has been achieved, a redox initiator system is added, comprising an organic or inorganic (hydro)peroxide(s) and ascorbic acid, and polymerisation is undertaken in the presence of this system or another initiator system. Also claimed are the obtained aqueous dispersions comprising at least 60 wt.% polymer particles of dmax above 800 nm and half width h1/2 below 1/2 dmax, with the remainder being of diameter d below dmax.

公开(公告)号：DE19649383A1

公开(公告)日：1998-06-04

申请号：DE19649383

申请日：1996-11-29

Applicant: BASF AG

Inventor： DAMES BURKHARDT DR ,  SCHUMACHER KARL-HEINZ DR ,  BARWICH JUERGEN DR ,  FRICKE HANS-JOACHIM

IPC: B32B27/30 ,  B32B7/12 ,  C08F2/22 ,  C08F220/12 ,  C08F220/18 ,  C09J4/00 ,  C09J133/08

Abstract: Polymer composed of 5 - 95 wt% of a mixture of at least one C2-C4alkyl acrylate and at least one C6-C12 alkyl acrylate (monomers a); 5 - 30 wt% ethylenically unsaturated compounds with a glass transition temperature above 0 DEG C which, apart from the ethylenically unsaturated group, have no further functional groups (monomers b); 0 - 10 wt% ethylenically unsaturated compounds with at least one acid group or acid anhydride group (monomers c); and 0 - 60 wt% of additional ethylenically unsaturated compounds (monomers d). The indications of weight are given with reference to the emulsion polymer.

公开(公告)号：DE19642762A1

公开(公告)日：1998-04-23

申请号：DE19642762

申请日：1996-10-16

Applicant: BASF AG

Inventor： DAMES BURKHARDT DR

IPC: C08F2/22 ,  C08F220/12 ,  C09D133/06 ,  C09J133/06 ,  C14C11/00 ,  C08F220/04 ,  C08F220/08 ,  C08F220/18 ,  C08F222/02 ,  C08F222/04 ,  C09D133/02 ,  C09D135/00 ,  C09J133/08 ,  C09J133/10

Abstract: The present invention relates to a method for the manufacture of low viscosity aqueous polymer dispersions with a polymer content of more than 50 vol. % and a polymodal distribution of polymer particle sizes by radical, aqueous emulsion polymerization of ethylenically unsaturated monomers, comprising at least one monomer (A) selected from monomers having a neutral functional group, which can be converted, according to Ph-value of reaction mixture, into a charged functional group and C1-C2 alkyl esters of monoethylenely unsaturated monocarboxylic or dicarboxylic acids. The invention also relates to polymer dispersions obtained according to this method.

公开(公告)号：DE4321205A1

公开(公告)日：1995-01-05

申请号：DE4321205

申请日：1993-06-25

Applicant: BASF AG

Inventor： EKKEHARD JAHNS DR ,  DAMES BURKHARDT DR

IPC: B01J13/02 ,  A01N25/28 ,  B01J13/14 ,  B41M5/165 ,  C08F2/00 ,  C08F2/22 ,  C08F2/32 ,  C08F20/00 ,  C08F20/04 ,  C08F265/04 ,  C08F283/12 ,  C09K23/00 ,  C08F20/08 ,  C08F22/04 ,  C08F12/22 ,  A61K9/50 ,  C09D11/00

Abstract: Microcapsules which are composed of a core and of a shell of a polymer, the core containing at least one oil which can be emulsified in water, and which are obtainable by polymerization of oil-soluble monomer mixtures which contain (a) 1-100% by weight of acrylic anhydride, methacryic anhydride, itaconic anhydride, citraconic anhydride, dimethylmaleic anhydride, 4-vinylbenzoic anhydride, mixed carboxylic anhydrides, mixtures of the said anhydrides and/or more than 40% by weight of maleic anhydride, (b) 0-99% by weight of at least one monoethylenically unsaturated monomer which is different from the monomers of group (a), (c) 0-80% by weight of crosslinking monomers which have at least two monoethylenically unsaturated non-conjugated double bonds in the molecule, and (d) 0-20% by weight of water-soluble monoethylenically unsaturated monomers in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, a process for producing the microcapsules by polymerization of the abovementioned monomer mixtures in the oil phase of a stable oil-in-water emulsion in the presence of polymerization initiators which form free radicals, where the temperature of the polymerizing reaction mixture may be continuously or periodically increased during the polymerization, and the use of the microcapsules for the controlled release of the core material of the microcapsules as active substance by destruction of their shell, in particular by the action of bases.