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公开(公告)号:CH422765A
公开(公告)日:1966-10-31
申请号:CH1603263
申请日:1963-12-30
Applicant: BASF AG
Inventor: SCHEUERER GUENTER DR , DICKHAEUSER HEINER DR
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公开(公告)号:DE1720295A1
公开(公告)日:1971-06-09
申请号:DEB0094197
申请日:1967-08-29
Applicant: BASF AG
Inventor: TRIESCHMANN HANS-GEORG PROF DR , ZEITLER GERHARD DR , DICKHAEUSER HEINER DR , REUTER LOTHAR , PFANNMUELLER HELMUTH DR
Abstract: 1,228,921. Chlorinating ethylene polymers. BADISCHE ANILIN- & SODA-FABRIK A.G. 28 Aug., 1968 [29 Aug., 1967], No. 41123/68. Heading C3P. A chlorinated ethylene polymer is prepared by allowing gaseous chlorine to act on a finely particled compact ethylene polymer which has been obtained by high pressure polymerization and which has an average particle diameter with the range from 200 to 800 microns and a specific surface area of from 70 to 300 cm. 2 /g. in the absence of solvents and suspension agents. Suitable polymers are homopolymers of ethylene or copolymers of ethylene with one or more other singly unsaturated olefins e.g. propylene or n-butene. The ethylene polymer may have a molecular weight of 10,000 to 180,000 and a density of 0À880 to 0.938 g./cm. 3 . The chlorination may be carried out in a fluidized bed, a rotary kiln or a stirred vessel.
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公开(公告)号:CH481576A
公开(公告)日:1969-11-30
申请号:CH1337765
申请日:1965-09-28
Applicant: BASF AG
Inventor: DICKHAEUSER HEINER DR , SCHEUERER GUENTER DR , ADOLPHI HEINRICH DR
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公开(公告)号:DE1720296A1
公开(公告)日:1974-05-30
申请号:DE1720296
申请日:1967-08-29
Applicant: BASF AG
Inventor: TRIESCHMANN HANS-GEORG PROF DR , ZEITLER GERHARD DR , REUTER LOTHAR , DICKHAEUSER HEINER DR , PFANNMUELLER HELMUT DR
Abstract: 1,228,976. Chlorinating polyethylene. BADISCHE ANILIN- & SODA-FABRIK A.G. 28 Aug., 1968 [29 Aug., 1967], No. 41122/68. Heading C3P. Polyethylene is chlorinated in a continuous process in which finely particled polyethylene is treated with chlorine in a chlorohydrocarbon whose boiling point is in the range from 30‹ to 90‹ C., the process comprising continuously introducing a high pressure polyethylene in the form of particles having a diameter of from 2 to 6 mm., a chlorohydrocarbon and chlorine into a reaction zone which contains solid polyethylene and a solution of from 1 to 20% by weight with respect to the solution of chlorinated polyethylene in the chlorohydrocarbon, continuously withdrawing from the reaction zone a fraction of the solution which is equivalent in amount to the amount of constituents being continuously introduced, and isolating chlorinated polyethylene from the solution withdrawn. Suitable chlorohydrocarbons are carbon tetrachloride, chloroform and trichloroethane.
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公开(公告)号:CH419725A
公开(公告)日:1966-08-31
申请号:CH1589963
申请日:1963-12-24
Applicant: BASF AG
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