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公开(公告)号:DE2800149A1
公开(公告)日:1979-07-12
申请号:DE2800149
申请日:1978-01-03
Applicant: BASF AG
Inventor: HORN PETER DIPL CHEM DR , LEPPMEIER FRANZ DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , FISCHER KARL , REIMANN HORST DIPL CHEM DR
Abstract: The parent patent concerns copolyamides (I) with K values of 35-70 (1% soln. in 96% H2SO4 at 20 degrees C), obtd. by melt condensn. at 180-300 degrees C from 5-18 (wt.)% hexamethylenediamine adipate (II) and 95-82% salt (III) of piperazine and mixts. of decane-1,10-dicarboxylic acid and azelaic acid in 70:30 to 95:5 molar ratio, opt. in the presence of traces of a monocarboxylic acid as mol. wt regulator. In this patent of addn. the novel feature is that a salt (IV) of adipic acid with a 5-20, pref. 6-15C (cyclo)aliphatic prim. diamine is used instead of (II). (I) are specified for dressing artificial leather with a plasticised PVC surface. (I) form stable solns. in the usual solvent mixts., adhere firmly and permanently to the surface, have good feel, gloss and mechanical properties and retard plasticiser and dyestuff migration.
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公开(公告)号:DE3127598A1
公开(公告)日:1982-03-04
申请号:DE3127598
申请日:1981-07-13
Applicant: BASF AG
Inventor: ECKERT GUENTER DIPL CHEM DR , WUERTELE LOTHAR DIPL CHEM DR , PETERSEN HARRO DIPL CHEM DR , GOECKEL ULRICH DIPL CHEM DR , FISCHER KURT
IPC: C14C11/00
Abstract: Leather-seasoning process free of formaldehyde odour, by applying an aqueous solution of casein and methoxymethylated or ethoxymethylated urea to leather, drying, and fixing with an acid at from room temperature to 160 DEG C.
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公开(公告)号:DE2900843A1
公开(公告)日:1980-07-24
申请号:DE2900843
申请日:1979-01-11
Applicant: BASF AG
Inventor: PENZEL ERICH DIPL CHEM DR , LEY GREGOR DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , MERGER FRANZ DIPL CHEM DR , TOWAE FRIEDRICH DIPL CHEM DR
IPC: C08F2/22 , C08F220/12
Abstract: Easily crosslinkable copolymers are prepd. by the aq. emulsion copolymerisation of, by wt. w.r.t. total monomers, (a) 45-97% mono-olefinically unsatd. carboxylic acid esters, the homopolymers of which have vitreous transition temp. below 15 degrees C., (b) 1-15% mono-olefinically unsatd. aldehydes, (2) 2-30% hydroxyalkyl esters of 3-4C alpha, beta-mono-olefinically unsatd. monocarboxylic acids, (d) 0-50% styrene, acrylonitrile and/or mono-olefinically unsatd. carboxylic acid esters, the homopolymers of which have vitreous transition temps. >15 degrees C. and (e) 0-10% alpha, beta-mono-olefinically unsatd. 3-5C carboxylic acids and/or their amides. Molar ratio (b):(c) is 1:0.5 to 1:3. Pptd. opt. filled rubber-elastic polymers can be used as sealing compsns. and as heat- and hot oil-resistant hoses. The aq. dispersions are used for finishing leather, as binders for fleeces, in textile printing, paper sizing and textile coating.
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公开(公告)号:DE2626931A1
公开(公告)日:1977-12-22
申请号:DE2626931
申请日:1976-06-16
Applicant: BASF AG
Inventor: FISCHER KARL , HORN PETER DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , LEPPMEIER FRANZ DIPL CHEM DR
Abstract: A specific copolyamide and its use for finishing leather and leather substitutes, particularly those of polyurethane. A particular advantage of the copolyamide is its sealing effect counteracting the migration of dyes, plasticizers and fats, combined with other advantages such as good mechanical properties and the stability of the solutions.
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公开(公告)号:DE3207396A1
公开(公告)日:1983-09-08
申请号:DE3207396
申请日:1982-03-02
Applicant: BASF AG
IPC: C07C233/09 , C07C233/20 , C08F20/54 , C08F20/58 , C07C103/60 , C08F220/56
Abstract: N-substituted acrylamide or methacrylamide derivatives of the general formula where m is 0 or 1, n is 1, 2, 3 or 4, n-m is 1, 2, 3 or 4, X is Br or Cl, and R1 and R2 are each CH3 or H, are prepared by reacting an aromatic haloalkyl compound with N-methylolacrylamide or N-methylolmethacrylamide in the presence of a strong acid.
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公开(公告)号:DE2800150A1
公开(公告)日:1979-07-12
申请号:DE2800150
申请日:1978-01-03
Applicant: BASF AG
Inventor: HORN PETER DIPL CHEM DR , LEPPMEIER FRANZ DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , FISCHER KARL ING GRAD , REIMANN HORST DIPL CHEM DR
Abstract: The parent patents concern copolyamides (I), with K values of 35-70 (1% soln. in 96% H2SO4 at 20 degrees C), obtd. by melt condensn. at 180-300 degrees C from 5-18 (wt.%)% hexamethylene diamine adipate (II) and 95-82% salt (III) of piperazine and mixts. of decane-1,10-dicarboxylic acid and azelaic acid in 70:30 to 95:5 molar ratio, opt. in the presence of traces of monocarboxylic acid as mol.wt. regulator, according to DT 26 30 114, or from salts (IV) of adipic acid with a 5-20, pref. 6-15C (cyclo)aliphatic prim. diamine instead of (II) according to DT 28 00 149. According to DT 28 00 149, (I) is used for dressing artificial leather with a plasticised PVC surface. Improvement is that (I) is used for dressing leather or artificial leather with a polyurethane surface. (I) forms stable solns. in the usual solvent mixts., adheres firmly and permanently to the surface, has good feel, gloss and mechanical properties and retards plasticiser and dyestuff migration.
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公开(公告)号:DE2630114A1
公开(公告)日:1978-01-19
申请号:DE2630114
申请日:1976-07-05
Applicant: BASF AG
Inventor: HORN PETER DIPL CHEM DR , LEPPMEIER FRANZ DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , FISCHER KARL
Abstract: Nylon copolymer containing piperazine and a process for finishing leather and imitation leather, having a surface of polyurethane or plasticized PVC, by applying a solution of this nylon copolymer and drying it. The overall properties of the finish are better then those of conventional finishes.
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