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公开(公告)号:DE2831263A1
公开(公告)日:1980-01-31
申请号:DE2831263
申请日:1978-07-15
Applicant: BASF AG
Inventor: FISCHER MARTIN DIPL CHEM DR , KUESTERS WERNER DIPL CHEM DR , PENZEL ERICH DIPL CHEM DR , REHDER WOLFGANG DIPL CHEM DR , TRAUTMANN WALTER DIPL CHEM DR
IPC: C07D295/10 , C07D295/104 , C08F2/50 , C07C97/02
Abstract: Quaternary ammonium compounds of the formula where R1 and R2 are identical or different and each is H, halogen, phenyl, alkyl, alkoxy or alkylthio, R3 is H or alkyl, hydroxyalkyl, cycloalkyl or aralkyl, R4 and R5 are identical or different and each is alkyl, phenyl, cycloalkyl or aralkyl or R4 and R5 together are a -(CH2)4- bridge, a -(CH2)5- bridge or a -(CH2)2-O-(CH2)2- bridge, R6 is alkyl and X(-) is Cl(-), Br(-), I(-), CH3SO4(-) or C2H5SO4(-), a process for their preparation from Mannich bases of the formula and alkylating agents, and the use of these quaternary ammonium compounds as initiators for the photopolymerization of polymerizable mixtures containing olefinically unsaturated compounds, especially for the preparation of aqueous polymer dispersions or polymer solutions.
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公开(公告)号:DE3207396A1
公开(公告)日:1983-09-08
申请号:DE3207396
申请日:1982-03-02
Applicant: BASF AG
IPC: C07C233/09 , C07C233/20 , C08F20/54 , C08F20/58 , C07C103/60 , C08F220/56
Abstract: N-substituted acrylamide or methacrylamide derivatives of the general formula where m is 0 or 1, n is 1, 2, 3 or 4, n-m is 1, 2, 3 or 4, X is Br or Cl, and R1 and R2 are each CH3 or H, are prepared by reacting an aromatic haloalkyl compound with N-methylolacrylamide or N-methylolmethacrylamide in the presence of a strong acid.
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公开(公告)号:DE2819092A1
公开(公告)日:1979-11-08
申请号:DE2819092
申请日:1978-04-29
Applicant: BASF AG
IPC: C08F8/00 , C08F8/30 , C08F8/32 , C08L33/12 , C09D5/00 , C09D133/04 , C09D133/12 , C09D157/04 , C09D3/80 , C09D3/81 , C09D3/74 , C09D3/76
Abstract: Binders which comprise (A) an aqueous emulsion of a copolymer A, having a glass transition temperature of 0-50 DEG C., of monoolefinically unsaturated carboxylic acid esters, with or without styrene, vinyl acetate, vinyl chloride and acrylonitrile, which copolymer contains, as copolymerized units, small amounts of monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids and/or their amides (of which the nitrogen atoms may or may not be alkyl-substituted and/or alkylol-substituted) and small amounts of monomers containing carbonyl groups, (B) from 0.05 to 1 mole, per mole of carbonyl groups present in the copolymer A, of a water-soluble aliphatic dihydrazine compound and (C) from 0 to 0.02 mole, per mole of dihydrazine compound, of a water-soluble zinc, manganese, cobalt and/or lead salt, or particularly suitable for use in paints and pebble dash renderings, since they give films which adhere particularly well to alkyd resin primers and which show particularly little tendency to whitening.
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公开(公告)号:DE2735765A1
公开(公告)日:1979-02-22
申请号:DE2735765
申请日:1977-08-09
Applicant: BASF AG
Inventor: STRICKLER RAINER DIPL CHEM DR , OPPENLAENDER KNUTZ DIPL CHEM D , MERKEL KARL DR , PENZEL ERICH DIPL CHEM DR , FISCHER ROBERT DIPL CHEM DR
IPC: C07D303/36 , C07D301/00 , C08J3/24
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公开(公告)号:DE2900843A1
公开(公告)日:1980-07-24
申请号:DE2900843
申请日:1979-01-11
Applicant: BASF AG
Inventor: PENZEL ERICH DIPL CHEM DR , LEY GREGOR DIPL CHEM DR , ECKERT GUENTER DIPL CHEM DR , MERGER FRANZ DIPL CHEM DR , TOWAE FRIEDRICH DIPL CHEM DR
IPC: C08F2/22 , C08F220/12
Abstract: Easily crosslinkable copolymers are prepd. by the aq. emulsion copolymerisation of, by wt. w.r.t. total monomers, (a) 45-97% mono-olefinically unsatd. carboxylic acid esters, the homopolymers of which have vitreous transition temp. below 15 degrees C., (b) 1-15% mono-olefinically unsatd. aldehydes, (2) 2-30% hydroxyalkyl esters of 3-4C alpha, beta-mono-olefinically unsatd. monocarboxylic acids, (d) 0-50% styrene, acrylonitrile and/or mono-olefinically unsatd. carboxylic acid esters, the homopolymers of which have vitreous transition temps. >15 degrees C. and (e) 0-10% alpha, beta-mono-olefinically unsatd. 3-5C carboxylic acids and/or their amides. Molar ratio (b):(c) is 1:0.5 to 1:3. Pptd. opt. filled rubber-elastic polymers can be used as sealing compsns. and as heat- and hot oil-resistant hoses. The aq. dispersions are used for finishing leather, as binders for fleeces, in textile printing, paper sizing and textile coating.
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公开(公告)号:DE2538282A1
公开(公告)日:1977-03-10
申请号:DE2538282
申请日:1975-08-28
Applicant: BASF AG
Inventor: MERGER FRANZ DIPL CHEM DR , WENDEL KURT DIPL CHEM DR , PENZEL ERICH DIPL CHEM DR , DISTLER DIETER DIPL CHEM DR , FOUQUET GERD DIPL CHEM DR
IPC: C08F220/22 , C08F230/02 , D06M15/267 , D06M15/285
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