2.
    发明专利
    未知

    公开(公告)号:DE59905262D1

    公开(公告)日:2003-06-05

    申请号:DE59905262

    申请日:1999-02-13

    Applicant: BASF AG

    Abstract: In the production of alcohols by gas phase hydrogenation of carboxylic acids or esters at elevated temperature and pressure in the presence of catalysts containing or consisting of group IV oxide(s) as hydrogenation-active constituent, hydrogenation is carried out (a) at 250-400 degrees C and 5-100 bar in the presence of (b) primary or secondary alcohols, using a hydrogen to alcohol molecular ratio ≤ 800.

    4.
    发明专利
    未知

    公开(公告)号:DE59803261D1

    公开(公告)日:2002-04-11

    申请号:DE59803261

    申请日:1998-11-27

    Applicant: BASF AG

    Abstract: Colloidal palladium for hydrogenating olefins, acetylene, dienes and (un)saturated nitriles consists of palladium clusters having an average particle size of 0.2-2.0 nm. At least 80% of the palladium clusters have a particle diameter which deviates not more than 0.2 nm from the average particle diameter. The clusters have protective ligands on the surface. Independent claims are also included for: (1) production of a palladium colloidal solution by reacting a palladium salt with a reductant made of 4-30 C alcohol, and a protective ligand of phosphane and/or aromatic nitrogen compound at 0-300o C; (2) production of colloidal palladium comprising forming the above palladium colloidal solution, precipitating the colloidal palladium by adding a hydrocarbon solvent, removing the colloidal palladium, and drying; and (3) production of a palladium-containing heterogeneous catalyst by forming the palladium solution as above, impregnating a carrier selected from alumina, silicon dioxide, zirconium dioxide, titanium dioxide, carbon, zeolite and silicate.

    5.
    发明专利
    未知

    公开(公告)号:DE59604938D1

    公开(公告)日:2000-05-18

    申请号:DE59604938

    申请日:1996-07-16

    Applicant: BASF AG

    Abstract: Prodn. of radiation-hardenable acrylate compsns. comprises: (i) the addn. of a cpd. (A) contg. acrylic gps. to a non-radically copolymerisable benzophenone deriv. contg. prim. or sec. amine gp(s), or OH gp. or mercapto gp.. Also claimed are: (1) radiation hardened materials contg. radiation hardenable acrylate compsns.; (2) benzophenone derivs. of formula RCOR (I) as novel cpds.; and (3) prepn. of the novel cpds. (I). R = phenyl or R ; R = a gp. of formula (II); and R -R = H, 1-4C alkyl or 1-4C alkoxy, with 1-3 of gps. R -R being a 1-30C organic gp. (X) with a prim. or sec. amine gp., OH gp. or mercapto gp..

    7.
    发明专利
    未知

    公开(公告)号:DE59608412D1

    公开(公告)日:2002-01-24

    申请号:DE59608412

    申请日:1996-07-02

    Applicant: BASF AG

    Abstract: The novel features in bulk or soln. polymerisation (esp. styrene/acrylonitrile copolymer mfr.) involving feed of the reaction components to a recycle reactor are that: (a) the reactor has at least one tubular bundle reactor (1) with straight or upright tubes sprinkled with a fluid heat-exchange medium; and (b) each tubular bundle reactor (1) consists of at least two tubular bundle heat exchangers (1A, 1B) linked to each other via at least one intermediate mixing zone, pref. a static mixer (12). The appts. is also claimed per se.

    9.
    发明专利
    未知

    公开(公告)号:DE59609686D1

    公开(公告)日:2002-10-24

    申请号:DE59609686

    申请日:1996-12-04

    Applicant: BASF AG

    Abstract: The preparation of polyolefin foam particles of bulk density 20 - 100 g / l comprises: (A) pre-foamed particles of bulk density 120 - 400 g / l are prepared by extrusion and granulation of polyolefin containing propellent ; and (B) the particles are further foamed in one or more steps without the use of propellent, by treating with 1.5 - 8 bar steam for 5 - 120 seconds at 110 - 170 degrees C.

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