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公开(公告)号:BR9608801A
公开(公告)日:1999-02-17
申请号:BR9608801
申请日:1996-05-17
Applicant: BASF AG
Inventor: HAHN KLAUS , KOEGEL WOLFRAM , FISCHER JOACHIM , GRAVE ISIDOOR DE
Abstract: PCT No. PCT/EP96/02116 Sec. 371 Date Nov. 24, 1997 Sec. 102(e) Date Nov. 24, 1997 PCT Filed May 17, 1996 PCT Pub. No. WO96/37541 PCT Pub. Date Nov. 28, 1996Expanded polyolefin particles are produced by impregnation of polyolefin granules with a volatile blowing agent in suspension under pressure and subsequent decompression. The blowing agent used is ammonia.
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公开(公告)号:DE19729123A1
公开(公告)日:1999-01-14
申请号:DE19729123
申请日:1997-07-08
Applicant: BASF AG
Inventor: FINK GUENTER , KOEGEL WOLFRAM
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公开(公告)号:NO970804L
公开(公告)日:1997-04-21
申请号:NO970804
申请日:1997-02-21
Applicant: BASF AG
Inventor: SCHWEINZER JUERGEN , FISCHER JOACHIM , GRAVE ISIDOOR DE , KOEGEL WOLFRAM
Abstract: PCT No. PCT/EP95/03190 Sec. 371 Date Feb. 24, 1997 Sec. 102(e) Date Feb. 24, 1997 PCT Filed Aug. 11, 1995 PCT Pub. No. WO96/06129 PCT Pub. Date Feb. 29, 1996The invention relates to a process for the production of expanded polyolefin beads by impregnating polyolefin particles with volatile blowing agents in a fluidized bed.
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公开(公告)号:DE59106179D1
公开(公告)日:1995-09-14
申请号:DE59106179
申请日:1991-04-05
Applicant: BASF AG
Inventor: DE GRAVE ISIDOOR DR , FISCHER JOACHIM DR , KOEGEL WOLFRAM , TATZEL HERMANN , GRAALMANN ONNO DR , KERTH JUERGEN DR , WERNER RAINER ALEXANDER DR
Abstract: Novel foams having a density of from 0.01 to 0.1 g/cm3, based on a copolymer comprising ethylene, propylene and a C4- to C8- alpha -olefin, and having a torsion modulus of from 100 to 800 N/mm2 have high tensile, compressive and flexural strengths and at the same time high elongation at break.
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公开(公告)号:DE4012239A1
公开(公告)日:1991-10-17
申请号:DE4012239
申请日:1990-04-14
Applicant: BASF AG
Inventor: DE GRAVE ISIDOOR DR , FISCHER JOACHIM DR , KOEGEL WOLFRAM , TATZEL HERMANN , GRAALMANN ONNO DR , KERTH JUERGEN DR , WERNER RAINER ALEXANDER DR
Abstract: Novel foams having a density of from 0.01 to 0.1 g/cm3, based on a copolymer comprising ethylene, propylene and a C4- to C8- alpha -olefin, and having a torsion modulus of from 100 to 800 N/mm2 have high tensile, compressive and flexural strengths and at the same time high elongation at break.
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6.
公开(公告)号:DE2331306A1
公开(公告)日:1975-01-23
申请号:DE2331306
申请日:1973-06-20
Applicant: BASF AG
Inventor: TATZEL HERMANN , KOEGEL WOLFRAM , BECK GILBERT DIPL CHEM , ZUERN LUDWIG DIPL CHEM DR , CAESAR ARNDT
Abstract: Foamed articles are made by compressing a mixt. of finely divided polyolefin with 0.3-4.0 g, per l, polyolefin, of a solvent-free curable blinder to 40-80% of the original bulk vol. of the mixt., whilst treating it with a gas of greater permeability coefft. than air. The polyolefin specif. has a crystallinity of >20 wt% at 25 degrees C and MFI 0.1-200 g/10 mins (190 degrees C/2.16 Kg, ASTM-D 1238-65T) and pref. is high pressure polyethylene of 0.918-0.935 g/cm3. The granules have an ave. dia. of 1-35 mm, pref. 3-20 mm and have a bulk density of 5-200 g/l, pref. 10-60 g/l. The binder is esp. a polyester or an epoxy resin, pref. in an amt. 0.6-2 g/l. The gas, (permeability coefft. measured to ASTM D 1434-63), is pret. ammonia or CO2, though (halogenated) hydrocarbons (b.pt. is not >15 degrees C) or CO may also be used. Compression is pref. to 50-70 vol%.
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7.
公开(公告)号:DE2331303A1
公开(公告)日:1975-01-23
申请号:DE2331303
申请日:1973-06-20
Applicant: BASF AG
Inventor: TATZEL HERMANN , KOEGEL WOLFRAM , BECK GILBERT DIPL CHEM , ZUERN LUDWIG DIPL CHEM DR , CAESAR ARNDT CHRISTIAN
Abstract: Foamed polyolefin articles are made by heating and compressing foamed cross-linked polyolefin granules in moulds which are not gas-tight while treating them with a gas whose permeability coefficient is greater than that of air. The polyolefin has a crystallinity of >20 wt% at 25 degrees C and MFI of 0.1-200 g/10 mins (190 degrees C/2.16 Kg) and is pref. high pressure polyethylene of 0.918-0.935 g/cm3. The granules have an ave. dia. of 1-35 mm, pref. 3-20 mm and a bulk density of 5-200 g/l, pref. 10-60 g/l. The gas, (permeability coeff. measured to D/N 53380 or ASTM D 1434-63), is pref. ammonia or CO2. The granules, heated to 40-80 degrees C in the presence of the gas are transferred to the mould and sintered at 5-150 degrees C, pref. 10-100 degrees C above their crystalline m.pt., i.e. at 90-250 degrees C, pref. 110-180 degrees C. After heating, the granules are compressed to 40-80% pref. 50-70% of their original vol.
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公开(公告)号:DE2331301A1
公开(公告)日:1975-01-23
申请号:DE2331301
申请日:1973-06-20
Applicant: BASF AG
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公开(公告)号:DE19638039A1
公开(公告)日:1998-03-19
申请号:DE19638039
申请日:1996-09-18
Applicant: BASF AG
Inventor: HAHN KLAUS DR , BEUERMANN ILKA RENATE DR , GRAVE ISIDOOR DE DR , KOEGEL WOLFRAM
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公开(公告)号:DE19519336A1
公开(公告)日:1996-11-28
申请号:DE19519336
申请日:1995-05-26
Applicant: BASF AG
Inventor: KOEGEL WOLFRAM , ISIDOOR GRAVE DE DR , HAHN KLAUS DR , FISCHER JOACHIM DR
Abstract: The invention concerns a process for preparing expanded polyolefin particles by impregnation under pressure of polyolefin granulates with a volatile expanding agent in suspension and subsequent relaxation, ammonia being used as the expanding agent.
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