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    2.
    发明专利
    未知

    公开(公告)号：DE59007079D1

    公开(公告)日：1994-10-13

    申请号：DE59007079

    申请日：1990-05-30

    Applicant: BASF AG

    Inventor： LICHT ULRIKE ,  FUCHS HARALD ,  FUNHOFF DIRK ,  SCHREPP WOLFGANG ,  SCHUPP HANS

    IPC: C08F220/36 ,  B05D1/20 ,  C08F20/34 ,  C08F20/52 ,  C08F220/34 ,  C08F220/60 ,  C09K19/38 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

    Abstract: PCT No. PCT/EP90/00866 Sec. 371 Date Nov. 12, 1991 Sec. 102(e) Date Nov. 12, 1991 PCT Filed May 30, 1990 PCT Pub. No. WO90/15087 PCT Pub. Date Dec. 13, 1990.Novel (meth)acrylate copolymers which contain, as polymerized units, A) one or more (meth)acrylates and/or (meth)acrylamides having second order nonlinear optical properties and of the general formula I (I) where R is hydrogen or methyl, X is a flexible spacer, which may or may not be present, Y is a divalent group having electron donor activity and Z is a noncentrosymmetric radical containing an easily polarizable conjugated pi -electron system and one or more electron acceptor groups, and B) one or more (meth)acrylates of alkanols where the alkyl radical is of 10 to 30 carbon atoms in a molar ratio of (A) to (B) of from 1:0.5 to 1:5 are very suitable as nonlinear optical materials for nonlinear optical arrangements and for the production of Langmuir-Blodgett films. The novel (meth)acrylate copolymers which contain terminal nitro, trifluoromethyl, cyano or fulven-6-yl groups as electron acceptors and have molar ratios A to B differing from those mentioned above are also suitable for intended uses outside nonlinear optics.

    3.
    发明专利
    未知

    公开(公告)号：FI923755A

    公开(公告)日：1993-02-24

    申请号：FI923755

    申请日：1992-08-20

    Applicant: BASF AG

    Inventor： KELLER HARALD ,  SCHREPP WOLFGANG ,  FUCHS HARALD

    IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

    Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

    (METH)ACRYLATE COPOLYMERIZATES AND THEIR USE IN NON-LINEAR OPTICS AND IN THE PRODUCTION OF LANGMUIR-BLODGETT COATINGS
    6.
    发明专利
    (METH)ACRYLATE COPOLYMERIZATES AND THEIR USE IN NON-LINEAR OPTICS AND IN THE PRODUCTION OF LANGMUIR-BLODGETT COATINGS 未知

    公开(公告)号：AU5736690A

    公开(公告)日：1991-01-07

    申请号：AU5736690

    申请日：1990-05-30

    Applicant: BASF AG

    Inventor： LICHT ULRIKE ,  SCHREPP WOLFGANG ,  SCHUPP HANS ,  FUCHS HARALD ,  FUNHOFF DIRK

    IPC: C08F220/36 ,  B05D1/20 ,  C08F20/34 ,  C08F20/52 ,  C08F220/34 ,  C08F220/60 ,  C09K19/38 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

    Abstract: PCT No. PCT/EP90/00866 Sec. 371 Date Nov. 12, 1991 Sec. 102(e) Date Nov. 12, 1991 PCT Filed May 30, 1990 PCT Pub. No. WO90/15087 PCT Pub. Date Dec. 13, 1990.Novel (meth)acrylate copolymers which contain, as polymerized units, A) one or more (meth)acrylates and/or (meth)acrylamides having second order nonlinear optical properties and of the general formula I (I) where R is hydrogen or methyl, X is a flexible spacer, which may or may not be present, Y is a divalent group having electron donor activity and Z is a noncentrosymmetric radical containing an easily polarizable conjugated pi -electron system and one or more electron acceptor groups, and B) one or more (meth)acrylates of alkanols where the alkyl radical is of 10 to 30 carbon atoms in a molar ratio of (A) to (B) of from 1:0.5 to 1:5 are very suitable as nonlinear optical materials for nonlinear optical arrangements and for the production of Langmuir-Blodgett films. The novel (meth)acrylate copolymers which contain terminal nitro, trifluoromethyl, cyano or fulven-6-yl groups as electron acceptors and have molar ratios A to B differing from those mentioned above are also suitable for intended uses outside nonlinear optics.

    8.
    发明专利
    未知

    公开(公告)号：DE59703240D1

    公开(公告)日：2001-05-03

    申请号：DE59703240

    申请日：1997-07-30

    Applicant: BASF AG

    Inventor： FUCHS HARALD ,  FRIEDRICH THOMAS ,  SCHREPP WOLFGANG

    IPC: G01N33/543 ,  G01Q60/20

    Abstract: Verfahren zum Wirkstoff-Screening, wobei man den Wirkstoff über die mittels einer rasteroptischen Nahfeldmikroskopiervorrichtung (SNOM-Vorrichtung) beobachtbare Änderung eines Signals (S) nachweist, sowie dafür geeignete Einrichtung, umfassend die SNOM-Vorrichtung, eine Einzel- oder Mehrfachprobenaufnahmevorrichtung und eine Steuereinrichtung.

    9.
    发明专利
    未知

    公开(公告)号：DE59603697D1

    公开(公告)日：1999-12-30

    申请号：DE59603697

    申请日：1996-05-17

    Applicant: BASF AG

    Inventor： VOLKERT OTTO ,  BRANDT PETER ,  FUCHS HARALD

    IPC: A43B13/04 ,  C08G18/12 ,  C08G18/32 ,  C08G18/66

    Abstract: A process for producing moldings containing ester and urethane groups and having a cellular core and a compacted surface zone, preferably shoe soles, comprises reacting a) isocyanate semiprepolymers containing ester groups and having an isocyanate content of from 10 to 26% by weight, which in turn are prepared by reacting ai) 4,4'-MDI or mixtures of 4,4'-MDI and modified or unmodified MDI isomers, with aii) difunctional to trifunctional polyester polyols having molecular weights of from 600 to 3000 and aiii) at least one branched-chain dihydroxy compound containing at least one bonded ester unit as bridge and having a molecular weight of up to 500, with b) at least one relatively high molecular weight polyhydroxyl compound and, if desired, c) low molecular weight chain extenders and/or crosslinkers in the presence of d) blowing agents, e) catalysts and, if desired, f) additives in a closed mold with compaction. The isocyanate semiprepolymers containing ester groups which can be used in this process are liquid at room temperature.

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