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    3.
    发明专利
    未知

    公开(公告)号：FI96767B

    公开(公告)日：1996-05-15

    申请号：FI894119

    申请日：1989-09-01

    Applicant: BASF AG

    Inventor： WIDDER RUDI ,  GOUSETIS CHARALAMPOS ,  PERNER JOHANNES ,  WOLF HELMUT ,  BOCHNITSCHEK WERNER ,  OFTRING ALFRED

    IPC: C07C227/12 ,  C07C229/22

    Abstract: Preparation of the trisodium salt of isoserine-N,N-diacetic acid (I) by reaction of acrylonitrile with aqueous hydrogen peroxide to give glycidamide (II) and further reaction of II with the disodium salt of iminodiacetic acid (III) to give I, by carrying out the process continuously and, in it, successively a) reacting together acrylonitrile and aqueous hydrogen peroxide at pH 7-8 and 30-60 DEG C, b) removing unreacted acrylonitrile by distillation, c) passing the reaction mixture over a solid hydrogen peroxide-decomposing catalyst, d) reacting the aqueous solution of II, obtained in this way, with III at pH 7-9 and 40-90 DEG C, e) reacting the resulting solution with a basic sodium compound at pH 9-14 and 60-95 DEG C, f) removing the ammonia which is produced by distillation and g) if desired, working up the aqueous solution of I, obtained in this way, in a manner known per se to give solid I.

    8.
    发明专利
    未知

    公开(公告)号：FI894119A

    公开(公告)日：1990-03-03

    申请号：FI894119

    申请日：1989-09-01

    Applicant: BASF AG

    Inventor： WIDDER RUDI ,  GOUSETIS CHARALAMPOS ,  PERNER JOHANNES ,  WOLF HELMUT ,  BOCHNITSCHEK WERNER ,  OFTRING ALFRED

    IPC: C07C227/12 ,  C07C229/22 ,  C07C

    Abstract: Preparation of the trisodium salt of isoserine-N,N-diacetic acid (I) by reaction of acrylonitrile with aqueous hydrogen peroxide to give glycidamide (II) and further reaction of II with the disodium salt of iminodiacetic acid (III) to give I, by carrying out the process continuously and, in it, successively a) reacting together acrylonitrile and aqueous hydrogen peroxide at pH 7-8 and 30-60 DEG C, b) removing unreacted acrylonitrile by distillation, c) passing the reaction mixture over a solid hydrogen peroxide-decomposing catalyst, d) reacting the aqueous solution of II, obtained in this way, with III at pH 7-9 and 40-90 DEG C, e) reacting the resulting solution with a basic sodium compound at pH 9-14 and 60-95 DEG C, f) removing the ammonia which is produced by distillation and g) if desired, working up the aqueous solution of I, obtained in this way, in a manner known per se to give solid I.

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