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公开(公告)号:DE502004001055D1
公开(公告)日:2006-09-07
申请号:DE502004001055
申请日:2004-04-24
Applicant: BASF AG
Inventor: SAUERER WOLFGANG , HEINEMANN JOHANNES
Abstract: Thermoplastic molding compositions, comprising A) from 15 to 99.94% by weight of a polyoxymethylene homo- or copolymer B) from 0.05 to 10% by weight of a nonpolar polypropylene wax, C) from 0.01 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having from 10 to 40 carbon atoms with saturated aliphatic alcohols or amines having from 2 to 40 carbon atoms, D) from 0 to 80% by weight of other additives, where the total of the percentages by weight of components A) to D) is always 100%.
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公开(公告)号:DE102004057867A1
公开(公告)日:2006-06-01
申请号:DE102004057867
申请日:2004-11-30
Applicant: BASF AG
Inventor: ASMANN JENS , ZOELLNER KNUT , HEINEMANN JOHANNES , STOECKELMANN ELMAR , STAMMER ACHIM
IPC: C08G2/00
Abstract: Preparation of polyoxymethylene (I) comprises polymerizing their monomers in the presence of cationically active initiators and optional regulators, subsequently deactivating and separating (I), where the polymerization is carried out in tubular reactor (A) (with static mixing element) comprising mixing-, polymerizing- and deactivating zones and the diameter of (A) in the mixing zone is less than 90% of the diameter in the polymerizing zone. An independent claim is also included for polyoxymethylene homo-/co-polymer obtained by the above method, where the quotient of d 50/d 100-value (related to M w) is 2.25-5.5.
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公开(公告)号:DE10312320A1
公开(公告)日:2004-09-30
申请号:DE10312320
申请日:2003-03-19
Applicant: BASF AG
Inventor: HEINEMANN JOHANNES , EBERLE WOLFGANG
IPC: C08K5/3492 , C08L59/00 , C08L71/00 , C08J5/10
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公开(公告)号:DE19927347A1
公开(公告)日:2000-12-21
申请号:DE19927347
申请日:1999-06-16
Applicant: BASF AG
Inventor: MUELHAUPT ROLF , HEINEMANN JOHANNES , BAUMERT MARTIN , QUEISSER JOACHIM , GEPRAEGS MICHAEL
IPC: C08F4/80 , C08F210/02 , C08F255/00 , C08F255/02 , C08F265/00 , C08F271/00 , C08F283/00 , C08F290/06 , C08F291/00 , C08L51/06 , C08F4/60
Abstract: The invention relates to a method for producing graft copolymers, containing an elastic copolymer backbone. In a first stage of said method, a) ethene, as the principal monomer, is copolymerised co-ordinatively with an alpha -olefin which is substituted with an alkoxyamine group as the additional comonomer in the presence of a transition metal compound which has been complexed using a bisimin chelate ligand, into an elastomeric graft copolymer backbone. In a second stage b) the copolymer produced in a) is reacted under controlled radical polymerisation conditions in the presence of monomers, selected from the group of vinyl aromatic compounds, vinyl heteroaromatic or vinyl heteroalicyclic compounds, alkyl esters, and amides of (meth)acryl acid, acryl nitrile, methacryl nitrile, maleimide or vinyl ferrocene and optionally also reacted in the presence of conjugated organic dienes, involving the formation of covalently linked graft branches. In a further stage c) the graft copolymer obtained in b) is either directly isolated, or the alkoxyamine groups which terminate the graft polymer lateral branches are first removed under reductive reaction conditions and the graft polymer thus obtained is subsequently isolated.
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公开(公告)号:DE10319740A1
公开(公告)日:2004-11-18
申请号:DE10319740
申请日:2003-04-30
Applicant: BASF AG
Inventor: SAUERER WOLFGANG , HEINEMANN JOHANNES
Abstract: Thermoplastic molding compositions, comprising A) from 15 to 99.94% by weight of a polyoxymethylene homo- or copolymer B) from 0.05 to 10% by weight of a nonpolar polypropylene wax, C) from 0.01 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having from 10 to 40 carbon atoms with saturated aliphatic alcohols or amines having from 2 to 40 carbon atoms, D) from 0 to 80% by weight of other additives, where the total of the percentages by weight of components A) to D) is always 100%.
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公开(公告)号:DE10147712A1
公开(公告)日:2003-04-17
申请号:DE10147712
申请日:2001-09-27
Applicant: BASF AG
Inventor: HEINEMANN JOHANNES , LUINSTRA GERRIT , BOHRES EDWARD
Abstract: The invention relates to a method for producing high−molecular aliphatic polycarbonates having the following properties: the average molecular weight M w ranges from 30,000 to 1,000,000, and; the content of cyclic carbonates and polyethers equals, in total, a maximum of 5 wt. %. Said polycarbonates are produced by polymerizing carbon dioxide with at least one epoxide while using at least one catalyst selected from the group consisting of zinc carboxylates and multi−metal cyanide compounds. The invention is characterized in that the catalyst is introduced in anhydrous form, and the catalyst is firstly brought into contact with at least a partial quantity of the carbon dioxide before the epoxide is added.
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公开(公告)号:DE19812124A1
公开(公告)日:1999-09-23
申请号:DE19812124
申请日:1998-03-19
Applicant: BASF AG
Inventor: GEPRAEGS MICHAEL , MUELHAUPT ROLF , HEINEMANN JOHANNES
IPC: C08L57/00 , C08F4/60 , C08F4/70 , C08F4/80 , C08F20/00 , C08F210/02 , C08F10/00 , C08L23/02 , C08L33/00 , D01F6/30 , C08J5/18 , C09D123/02 , C09D133/00
Abstract: Preparation of copolymers from unsaturated olefinic monomers and nonpolar olefins in which none or only a very small part of homopolymer is accumulated, in the presence of transition metal catalysts. Preparation of copolymers from unsaturated olefinic monomers and nonpolar olefins in which none or only a very small part of homopolymer is accumulated. The monomers are reacted with shielded aromatic monohydroxy compounds having sterically hindered groups or with a N-oxyl radical having sterically hindered groups in the presence of a transition metal compound of formula (Ia) or (Ib). R -R = H, 1-10C alkyl, 1-10C partially or perhalogenated alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on Group IVA, VA, VIA, and VIIA elements, partially or persubstituted 1-14C aryl or 4-13C heteroaryl; X = alkylaryl, with 1-10C in alkyl and 6-14C in aryl residues, or Si(R )3, where R and R are not H. Alternatively, R and R together with Ca and Na or R and R together with Cb and Nb = a five-, six-, or seven-membered aromatic or aliphatic optionally substituted hetero ring, or R and R together with Ca and Cb = a five-, six-, or seven-membered aromatic or aliphatic optionally substituted carbo- or hetero-ring; R = H, 1-10C alkyl, 3-10C cycloalkyl, 6-14C aryl, X or Si(R )3; R = 1-10C alkyl, 3-10C cycloalkyl or X; m = 0 or 1; M = a Group VIIIB element; Q = acetonitrile, benzonitrile, , linear 1-4C alkyl ester, linear or cyclic alkyl ether, dimethylsulfoxide, dimethylformamide, hexamethylphosphoric acid triamide or halogenide; T = chloride, bromide, or iodide, or 1-20C alkyl which in the beta-position to the metal center has no H, and if necessary a 1-4C alkyl ester end or nitrile end group is available, or Q and T together form a C-3 alkylene chain with a a 1-4C linear alkyl ester or nitrile end group; A = non-coordinated or poorly coordinated anion; and n = 0, 1, 2 or 3.
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公开(公告)号:DE102004005419A1
公开(公告)日:2005-08-18
申请号:DE102004005419
申请日:2004-02-03
Applicant: BASF AG
Inventor: HEINEMANN JOHANNES
Abstract: Thermoplastic molding composition (X) comprises, by weight, 15-99.9% polyoxymethylene homo- and/or co-polymer (A); 0.05-3% amino-substituted triazine (B) having at least one aromatic substituent; 0.01-2% talc; 0.01-2% at least one stabilizer (D), i.e. sterically hindered amine, or a benzotriazole, benzophenone or benzene derivative and 0-80% other additives (E). An independent claim is also included for molded articles prepared from (X).
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公开(公告)号:DE10340778A1
公开(公告)日:2005-03-24
申请号:DE10340778
申请日:2003-09-02
Applicant: BASF AG
Inventor: DAMES BURKHARDT , HEINEMANN JOHANNES
Abstract: Aldehydes are used as co-catalysts in a method for the production of polyoxymethylenes (POM) by polymerisation of monomers (a) in presence of catalytic initiators (b), co-catalysts (c) and optionally regulators (d), followed by isolation of the polymer (optionally after deactivation).
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公开(公告)号:DE10340789A1
公开(公告)日:2005-03-17
申请号:DE10340789
申请日:2003-09-02
Applicant: BASF AG
Inventor: DAMES BURKHARDT , HEINEMANN JOHANNES
Abstract: Carboxylic acid halides are used as co-catalysts in a method for the production of polyoxymethylenes (POM) by polymerisation of monomers (a) in presence of catalytic initiators (b), co-catalysts (c) and optionally regulators (d), followed by isolation of the polymer (optionally after deactivation).
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