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    1.
    发明专利
    未知

    公开(公告)号：DE19960123A1

    公开(公告)日：2001-06-21

    申请号：DE19960123

    申请日：1999-12-13

    Applicant: BASF AG

    Inventor： HEINEMANN JOHANNES ,  MUELHAUPT ROLF ,  QUEISSER JOACHIM ,  LUINSTRA GERRIT ,  GEPRAEGS MICHAEL

    IPC: C08F4/42 ,  C08F4/60 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/70 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/08

    Abstract: The invention relates to a method for the homogeneous catalytic production, starting from ethene, of highly branched amorphous polyolefins which have an elastomeric characteristic profile. In a first step of said method a) ethene is oligomerized in the presence of a transition metal compound of general formula (I), whereby R and R represent C4 to C16 heteroaryl or C6 to C16 aryl with hydrogen substituents in both vicinal or ortho positions in relation to the binding site between the aryl or heteroaryl and N or N and is optionally oligomerized in the presence of a co-catalyst in an inert solvent. In a further step b), a transition metal compound of general formula (II) is added to the oligomerization mixture produced according to step a) and the reaction is continued in the presence of ethene. In a subsequent step c), the polymer product obtained is isolated.

    4.
    发明专利
    未知

    公开(公告)号：DE102007007451A1

    公开(公告)日：2007-09-06

    申请号：DE102007007451

    申请日：2007-02-15

    Applicant: BASF AG ,  UNIV ALBERT LUDWIGS FREIBURG

    Inventor： BOCK THORSTEN ,  MUELHAUPT ROLF ,  MOEHWALD HELMUT

    IPC: C08G77/30 ,  B01D71/72 ,  B01D71/82 ,  B01J31/06 ,  C08G77/38 ,  C08G77/42 ,  C08L83/08 ,  C09D5/08 ,  C09D183/08 ,  H01M8/02

    Abstract: The present invention relates to oligomeric or polymeric siloxanes comprising phosphonic acid groups, a process for preparing them, oligomeric or polymeric siloxanes comprising silyl phosphonate and/or alkyl phosphonate groups, blends comprising at least one oligomeric or polymeric siloxane according to the invention comprising polyphosphonic acid groups and/or at least one oligomeric or polymeric siloxane comprising silyl phosphonate and/or alkyl phosphonate groups and at least one further polymer, membranes, films or composites comprising at least one oligomeric or polymeric siloxane according to the invention comprising phosphonic acid groups and/or at least one oligomeric or polymeric siloxane according to the invention comprising silyl polyphosphonate and/or alkyl polyphosphonate groups or a blend according to the invention, and also various uses of oligomeric or polymeric siloxanes comprising phosphonic acid groups and/or oligomeric or polymeric siloxanes comprising silyl phosphonate and/or alkyl phosphonate groups or blends according to the invention.

    Preparation of copolymers from unsaturated olefin monomers and nonpolar unsaturated olefin compounds
    7.
    发明专利
    Preparation of copolymers from unsaturated olefin monomers and nonpolar unsaturated olefin compounds 未知

    公开(公告)号：DE19812124A1

    公开(公告)日：1999-09-23

    申请号：DE19812124

    申请日：1998-03-19

    Applicant: BASF AG

    Inventor： GEPRAEGS MICHAEL ,  MUELHAUPT ROLF ,  HEINEMANN JOHANNES

    IPC: C08L57/00 ,  C08F4/60 ,  C08F4/70 ,  C08F4/80 ,  C08F20/00 ,  C08F210/02 ,  C08F10/00 ,  C08L23/02 ,  C08L33/00 ,  D01F6/30 ,  C08J5/18 ,  C09D123/02 ,  C09D133/00

    Abstract: Preparation of copolymers from unsaturated olefinic monomers and nonpolar olefins in which none or only a very small part of homopolymer is accumulated, in the presence of transition metal catalysts. Preparation of copolymers from unsaturated olefinic monomers and nonpolar olefins in which none or only a very small part of homopolymer is accumulated. The monomers are reacted with shielded aromatic monohydroxy compounds having sterically hindered groups or with a N-oxyl radical having sterically hindered groups in the presence of a transition metal compound of formula (Ia) or (Ib). R -R = H, 1-10C alkyl, 1-10C partially or perhalogenated alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on Group IVA, VA, VIA, and VIIA elements, partially or persubstituted 1-14C aryl or 4-13C heteroaryl; X = alkylaryl, with 1-10C in alkyl and 6-14C in aryl residues, or Si(R )3, where R and R are not H. Alternatively, R and R together with Ca and Na or R and R together with Cb and Nb = a five-, six-, or seven-membered aromatic or aliphatic optionally substituted hetero ring, or R and R together with Ca and Cb = a five-, six-, or seven-membered aromatic or aliphatic optionally substituted carbo- or hetero-ring; R = H, 1-10C alkyl, 3-10C cycloalkyl, 6-14C aryl, X or Si(R )3; R = 1-10C alkyl, 3-10C cycloalkyl or X; m = 0 or 1; M = a Group VIIIB element; Q = acetonitrile, benzonitrile, , linear 1-4C alkyl ester, linear or cyclic alkyl ether, dimethylsulfoxide, dimethylformamide, hexamethylphosphoric acid triamide or halogenide; T = chloride, bromide, or iodide, or 1-20C alkyl which in the beta-position to the metal center has no H, and if necessary a 1-4C alkyl ester end or nitrile end group is available, or Q and T together form a C-3 alkylene chain with a a 1-4C linear alkyl ester or nitrile end group; A = non-coordinated or poorly coordinated anion; and n = 0, 1, 2 or 3.

    8.
    发明专利
    未知

    公开(公告)号：DE102007007452A1

    公开(公告)日：2007-11-29

    申请号：DE102007007452

    申请日：2007-02-15

    Applicant: BASF AG ,  UNIV ALBERT LUDWIGS FREIBURG

    Inventor： BOCK THORSTEN ,  MUELHAUPT ROLF ,  MOEHWALD HELMUT

    IPC: C08G79/06 ,  B01D71/72 ,  B01D71/82 ,  C08G75/20 ,  H01M8/02 ,  H01M8/10

    Abstract: The present invention relates to halogen-free, oligomeric or polymeric phosphonic acids made up of units of the general formula (I) -[(O)m-{R1(X)n(Y)o}pR1(X)q]r-[(O)s-R5(X)t]v-(I), where: X is -P=O(OH)2, Y is carbonyl or sulfonyl, R1, R5 are, independently of one another, divalent or polyvalent, substituted or unsubstituted, heteroatom-free or heteroatom- comprising aromatic radicals, m, o, s are each, independently of one another, 0 or 1, n, q, t are each, independently of one another, 0 or an integer from 1 to 8, with n and s not simultaneously being 0, r, v are each, independently of one another, from 0 to 1, with the sum of r and v being from 0.95 to 1.05, and p is 0 or an integer >=1, where the radicals X are substituents on R1 and R5 and the radicals Y are parts of polymer or oligomer chain, to a process for preparing these compounds and also to halogen-free mixtures comprising one or more compounds of the general formula (I) and a nitrogen-free solvent having a boiling point of >150° C.

    10.
    发明专利
    未知

    公开(公告)号：DE19927347A1

    公开(公告)日：2000-12-21

    申请号：DE19927347

    申请日：1999-06-16

    Applicant: BASF AG

    Inventor： MUELHAUPT ROLF ,  HEINEMANN JOHANNES ,  BAUMERT MARTIN ,  QUEISSER JOACHIM ,  GEPRAEGS MICHAEL

    IPC: C08F4/80 ,  C08F210/02 ,  C08F255/00 ,  C08F255/02 ,  C08F265/00 ,  C08F271/00 ,  C08F283/00 ,  C08F290/06 ,  C08F291/00 ,  C08L51/06 ,  C08F4/60

    Abstract: The invention relates to a method for producing graft copolymers, containing an elastic copolymer backbone. In a first stage of said method, a) ethene, as the principal monomer, is copolymerised co-ordinatively with an alpha -olefin which is substituted with an alkoxyamine group as the additional comonomer in the presence of a transition metal compound which has been complexed using a bisimin chelate ligand, into an elastomeric graft copolymer backbone. In a second stage b) the copolymer produced in a) is reacted under controlled radical polymerisation conditions in the presence of monomers, selected from the group of vinyl aromatic compounds, vinyl heteroaromatic or vinyl heteroalicyclic compounds, alkyl esters, and amides of (meth)acryl acid, acryl nitrile, methacryl nitrile, maleimide or vinyl ferrocene and optionally also reacted in the presence of conjugated organic dienes, involving the formation of covalently linked graft branches. In a further stage c) the graft copolymer obtained in b) is either directly isolated, or the alkoxyamine groups which terminate the graft polymer lateral branches are first removed under reductive reaction conditions and the graft polymer thus obtained is subsequently isolated.

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