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公开(公告)号：DE4444979A1
公开(公告)日：1996-06-20
申请号：DE4444979
申请日：1994-12-16
Applicant: BASF AG
Inventor： HAMMER HANS , HERR MANFRED , HUPFER LEOPOLD DR , BESLING BERND , PAN DONGFENG DR , ZECK SEBASTIAN DR , AUER HEINZ , SCHOENMAKERS HARTMUT DR
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公开(公告)号：DE3260698D1
公开(公告)日：1984-10-18
申请号：DE3260698
申请日：1982-03-30
Applicant: BASF AG
Inventor： FISCHER KARL DR , GRENACHER ARMIN VOLKER DR , HERR MANFRED , STROHMEYER MAX DR
IPC: B01J23/00 , B01J23/46 , C07B61/00 , C07C45/00 , C07C45/50 , C07C45/81 , C07C45/82 , C07C47/02 , C07C67/00
Abstract: Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. FIG. 2) in which (a) this gaseous product is introduced, without being cooled or depressured, into a distillation column D, (b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed, (c) the condensate is separated, in a separator A, into a gas phase and a liquid phase, (d) the gas phase from A, after waste gas has been separated off, is again brought to the hydroformylation pressure by means of a compressor P, and is returned to the reactor as a recycle gas, (e) the liquid phase from A is returned to D, and (f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.
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公开(公告)号：CA1173060A
公开(公告)日：1984-08-21
申请号：CA399835
申请日：1982-03-30
Applicant: BASF AG
Inventor： FISCHER KARL , GRENACHER ARMIN V , HERR MANFRED , STROHMEYER MAX
IPC: B01J23/00 , B01J23/46 , C07B61/00 , C07C45/00 , C07C45/50 , C07C45/81 , C07C45/82 , C07C47/02 , C07C67/00
Abstract: O. Z. OO5O/35O76 Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. Figure 2) in which a) this gaseous product is introduced, without being cooled or let down, into a distillation column D, b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed, c) the condensate is separated, in a separator A, into a gas phase and a liquid phase, d) the gas phase from A, after waste gas has been separa ted off, is again brought to the synthesis pressure by means of a compressor P, and is returned to the reactor as a recycle gas, e) the liquid phase from A is returned to D, and f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.
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公开(公告)号：ES2129744T3
公开(公告)日：1999-06-16
申请号：ES95119855
申请日：1995-12-15
Applicant: BASF AG
Inventor： HAMMER HANS , HERR MANFRED , HUPFER LEOPOLD DR , BESSLING BERND , PAN DONGFENG DR , ZECK SEBASTIAN DR
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Patent Agency Ranking
公开(公告)号：DE59505506D1
公开(公告)日：1999-05-06
申请号：DE59505506
申请日：1995-12-15
Applicant: BASF AG
Inventor： HAMMER HANS , HERR MANFRED , HUPFER LEOPOLD DR , BESSLING BERND , PAN DONGFENG DR , ZECK SEBASTIAN DR , AUER HEINZ , SCHOENMAKERS HARTMUT DR
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公开(公告)号：FI941397A
公开(公告)日：1994-09-26
申请号：FI941397
申请日：1994-03-25
Applicant: BASF AG
Inventor： ZEHNER PETER , BITTINS KLAUS , HAARDE WILHELM , EIDEN ULRICH , WOLFF DIETRICH , HERR MANFRED , HUPFER LEOPOLD
Abstract: Methyl formate is prepared by reaction of carbon monoxide and methanol at elevated pressure and elevated temperature in the presence of an alkali metal methoxide by A) mixing the starting substances in a mixing zone, partially allowing them to react, saturating the reaction solution with CO and B) carrying the reaction to completion in one or more subsequent reaction zones without addition of further starting compounds.
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公开(公告)号：DE4309731A1
公开(公告)日：1994-09-29
申请号：DE4309731
申请日：1993-03-25
Applicant: BASF AG
Inventor： ZEHNER PETER DR , BITTINS KLAUS DR , HAARDE WILHELM DR , EIDEN ULRICH DR , WOLFF DIETRICH DR , HERR MANFRED , HUPFER LEOPOLD DR
Abstract: Methyl formate is prepared by reaction of carbon monoxide and methanol at elevated pressure and elevated temperature in the presence of an alkali metal methoxide by A) mixing the starting substances in a mixing zone, partially allowing them to react, saturating the reaction solution with CO and B) carrying the reaction to completion in one or more subsequent reaction zones without addition of further starting compounds.
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公开(公告)号：FI941397A0
公开(公告)日：1994-03-25
申请号：FI941397
申请日：1994-03-25
Applicant: BASF AG
Inventor： ZEHNER PETER , BITTINS KLAUS , HAARDE WILHELM , EIDEN ULRICH , WOLFF DIETRICH , HERR MANFRED , HUPFER LEOPOLD
Abstract: Methyl formate is prepared by reaction of carbon monoxide and methanol at elevated pressure and elevated temperature in the presence of an alkali metal methoxide by A) mixing the starting substances in a mixing zone, partially allowing them to react, saturating the reaction solution with CO and B) carrying the reaction to completion in one or more subsequent reaction zones without addition of further starting compounds.
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公开(公告)号：CA1072118A
公开(公告)日：1980-02-19
申请号：CA277695
申请日：1977-05-04
Applicant: BASF AG
Inventor： HOHENSCHUTZ HEINZ , STROHMEYER MAX , HERR MANFRED , KIEFER HANS
IPC: C07C231/02 , C07C20060101 , C07C67/00 , C07C231/00 , C07C233/03 , C07C103/127
Abstract: O.Z. 32,004 Formamide is manufactured continuously from methyl formate and gaseous ammonia. The reaction is carried out in a reactor at from 30 to 90.degree.C, from 5 to 20% by volume of the reactor output is drawn off continuously and fed to the formamide working-up stage, and the remainder of the reactor output is cooled, in an external circuit maintained by means of a pump, to from 25 to 60.degree.C and is mixed with the amount of fresh methyl formate required for steady-state operation, after which the appropriate amount of gaseous ammonia is introduced into the stream of liquid through a jet, by the sucking-jet principle, and the stream of liquid is recycled to the reactor.
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