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公开(公告)号：JPS62298550A
公开(公告)日：1987-12-25
申请号：JP14931587
申请日：1987-06-17
Applicant: BASF AG
Inventor： HOELDERICH WOLFGANG , REUVERS JOHANNES G , KUMMER RUDOLF , HUPFER LEOPOLD
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公开(公告)号：HU209557B
公开(公告)日：1994-07-28
申请号：HU9201632
申请日：1992-05-15
Applicant: BASF AG
Inventor： HUPFER LEOPOLD , FRANZISCHKA WOLFGANG , KAHL THOMAS-MICHAEL , HENKELMANN JOCHEM , TROETSCH-SCHALLER IRENE , WETTLING THOMAS , KOEHLER HERMANN
IPC: B01J31/02 , C07B39/00 , C07B61/00 , C07C17/16 , C07C19/01 , C07C21/02 , C07C21/22 , C07C41/22 , C07C43/225 , C07C19/02
Abstract: Process for the preparation of alkyl, alkenyl and alkynyl chlorides by reaction of the corresponding alcohols with phosgene or thionyl chloride in the presence of a phosphine oxide as a catalyst, by using aliphatic, cycloaliphatic or cyclic-aliphatic phosphine oxides as catalyst.
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公开(公告)号：CA1319150C
公开(公告)日：1993-06-15
申请号：CA545305
申请日：1987-07-03
Applicant: BASF AG
Inventor： SPIEGLER WOLFGANG , HOELDERICH WOLFGANG , GOETZ NORBERT , HUPFER LEOPOLD , WILD JOCHEN
IPC: A01N43/18 , B01J29/40 , B01J29/70 , B01J29/83 , B01J29/85 , B01J29/86 , C07D309/04 , C07D309/06 , C07D309/10 , C07D405/04 , C07D407/04 , C07D409/04 , C07D411/04
Abstract: - 25 - O.Z. 0050/38673 4-Formyltetrahydropyrans of the general formula I (I) where R1 is hydrogen, C1-C12-alkyl, C2-C12-alkenyl, C1-C6-alkoxy-substituted C1-C12-alkyl, C4-C12-cycloalkyl, unsubstituted or substituted aryl, hetaryl or aralkyl, or an unsubsituted or substituted, saturated or unsaturated 5membered or 6-membered ring which may be interrupted by N, O or S, are prepared by a process in which a pyran derivative of the general formula II (II) where R1 is as defined above, R2 and R3 are each OH or together are an oxygen atom and thus form an oxirane ring, and R4 is hydrogen where R2 and R3 are each OH, and is hydrogen or tert-butoxycarbonyl where R2 and R3 together are an oxygen atom, is treated at elevated temperatures with a catalyst selected from the group consisting of zeolites, phosphates, boric acid on a carrier and silica or mixtures of these. Novel 4-formyltetrahydropyrans are also proposed.
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公开(公告)号：HU9201632D0
公开(公告)日：1992-08-28
申请号：HU9201632
申请日：1992-05-15
Applicant: BASF AG
Inventor： HENKELMANN JOCHEM , TROETSCH-SCHALLER IRENE , WETTLING THOMAS , KAHL THOMAS-MICHAEL , HUPFER LEOPOLD , FRANZISCHKA WOLFGANG , KOEHLER HERMANN
IPC: B01J31/02 , C07B39/00 , C07B61/00 , C07C17/16 , C07C19/01 , C07C21/02 , C07C21/22 , C07C41/22 , C07C43/225
Abstract: Process for the preparation of alkyl, alkenyl and alkynyl chlorides by reaction of the corresponding alcohols with phosgene or thionyl chloride in the presence of a phosphine oxide as a catalyst, by using aliphatic, cycloaliphatic or cyclic-aliphatic phosphine oxides as catalyst.
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公开(公告)号：FR2540105A1
公开(公告)日：1984-08-03
申请号：FR8400782
申请日：1984-01-19
Applicant: BASF AG
Inventor： WICKENHAEUSER GERHARD , HEIDA BERND , GRAF FRITZ , HUPFER LEOPOLD
IPC: C07C47/127 , C07C45/00 , C07C45/80 , C07C45/85 , C07C67/00
Abstract: Aqueous solutions of glyoxal which contain acids are purified by treatment with a solution which contains from 20 to 60% by weight of a tertiary amine and from 80 to 40% by weight of an alcohol which is not infinitely miscible with water, the treatment being carried out by mixing the two solutions during a residence time of less than 5 minutes.
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Patent Agency Ranking
公开(公告)号：GB1132865A
公开(公告)日：1968-11-06
申请号：GB1050866
申请日：1966-03-10
Applicant: BASF AG , METALLGESELLSCHAFT AG
Inventor： HUPFER LEOPOLD , RALL WOLFGANG , TRIEBSKORN BRUNO , BARON GERHARD , GROSS HANS WERNER , EHRHARDT ERWIN
Abstract: 1,132,865. Making combustible gas. BADISCHE ANILIN - & SODA - FABRIK A.G., and METALLGESELLSCHAFT A.G. 10 March, 1966 [11 March, 1965], No. 10508/66. Heading C5E. A cracked gas of high CH 4 content is made by cracking C 2 to C 30 hydrocarbons with steam at atmospheric or superatmospheric pressure at a temperature of from 350‹ to 550‹ C. The catalyst comprises 35 to 50% b.w. Ni, a carrier material, e.g. alumina, magnesia, zirconium dioxide or titanium dioxide, and an hydraulic binder, e.g. calcium aluminate, and the inner surface area of the catalyst must be at least 15 m 2 /gm. An alkali metal compound or a chromium compound may be added to the carrier. Pressures up to 100 atmos. are mentioned, but 20 to 60 atmos. are preferred, and catalyst surface areas up to 200 m 2 /gm are mentioned, with 15 to 40 preferred. The cracked gas may be further catalytically cracked at above 550‹ C. to increase the H 2 content, or at below 350‹ C. to increase the CH 4 content, and the initial cracked gas may be mixed with a cracked gas rich in H 2 and CO to provide town's gas. Three specific examples are described, in one of which, see Fig. (not shown), steam at 500‹ C. enters at (4) a reactor (1) to heat catalyst-filled tubes (2) externally, the steam leaving at (5) for delivery to a line (6) through which a mixture of desulphurized gasoline and hydrogen is delivered to the tubes (2). Examples of feedstocks are given.
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公开(公告)号：CA1340432C
公开(公告)日：1999-03-16
申请号：CA525487
申请日：1986-12-16
Applicant: BASF AG
Inventor： HOELDERICH WOLFGANG , GOETZ NORBERT , HUPFER LEOPOLD , KROPP RUDOLF , THEOBALD HANS , WOLF BERND
IPC: C07C47/228 , C07C45/00 , C07C45/41 , C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58 , C07C45/65 , C07C47/24 , C07C47/277 , C07C67/00 , C07C313/00 , C07C323/01 , C07C323/22 , C07C47/20
Abstract: Disclosed are processes for preparing phenylacetaldehydes of the structure (I) (see fig. I) where the substituents X are 2,4-dichloro, difluoro, tri-fluoro, tetrafluoro, p-trifluoromethyl, 2-methyl-4-fluoro, haloalkoxy or haloalkylthio radicals or are adjacent CL, F, CF3, alkyl, alkoxy, haloalkoxy and/or haloalkylthio radicals. Some of these compounds which are useful as intermediates for the preparation of insecticides, are new.
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公开(公告)号：FI941397A
公开(公告)日：1994-09-26
申请号：FI941397
申请日：1994-03-25
Applicant: BASF AG
Inventor： ZEHNER PETER , BITTINS KLAUS , HAARDE WILHELM , EIDEN ULRICH , WOLFF DIETRICH , HERR MANFRED , HUPFER LEOPOLD
Abstract: Methyl formate is prepared by reaction of carbon monoxide and methanol at elevated pressure and elevated temperature in the presence of an alkali metal methoxide by A) mixing the starting substances in a mixing zone, partially allowing them to react, saturating the reaction solution with CO and B) carrying the reaction to completion in one or more subsequent reaction zones without addition of further starting compounds.
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公开(公告)号：FI931487A
公开(公告)日：1993-10-04
申请号：FI931487
申请日：1993-04-01
Applicant: BASF AG
Inventor： KIEFER HANS , HUPFER LEOPOLD , LIPPERT FERDINAND
Abstract: A process for preparing formic acid by thermal cleavage of quaternary ammonium formates of the general formula I (* CHEMICAL STRUCTURE *) (I) where R1, R2 and R3 are C1- to C14-alkyl, C3- to C8-cycloalkyl, aryl or C7- to C16-aralkyl, or together are 1,4- or 1,5-alkylene which is unsubstituted or substituted one to four times by C1-to C4-alkyl, with the proviso that the sum of the carbon atoms of R1, R2 and R3 in the quaternary ammonium formates I is 7 to 40, comprises carrying out the cleavage in the presence of secondary formamides of the general formula II (* CHEMICAL STRUCTURE *) (II) where R4 and R5 are C2- to C10-alkyl, C3- to C8-cycloalkyl, aryl or C7- to C16-aralkyl, or together are 1,4- or 1,5-alkylene which is unsubstituted or substituted one to four times by C1- to C4-alkyl, which formamides boil 30 degrees to 150 degrees C. lower than the tertiary amine of the general formula III (* CHEMICAL STRUCTURE *) (III) where R1, R2 and R3 have the abovementioned meanings, contained in the formate I.
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公开(公告)号：DE3620581A1
公开(公告)日：1987-12-23
申请号：DE3620581
申请日：1986-06-19
Applicant: BASF AG
Inventor： HOELDERICH WOLFGANG , REUVERS JOHANNES G , KUMMER RUDOLF , HUPFER LEOPOLD
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