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公开(公告)号：JPH10128111A
公开(公告)日：1998-05-19
申请号：JP22798397
申请日：1997-08-25
Applicant: BASF AG
Inventor： HAGEMEYER ALFRED DR , PUETTNER ANDREAS DR , TROEMEL MARTIN
Abstract: PROBLEM TO BE SOLVED: To efficiently perform preparation of C12 with improved yield at empty time by using a catalyst contg. at least one bismuth oxide compd. wherein active phase has a function of oxygen storage. SOLUTION: In this catalyst being suitable for preparation of chlorine or preparation of barium bismuth oxide compd., at least one bismuth oxide compd. wherein bismuth exists at least under partial oxidation state +5 is incorporated in the active phase of the catalyst and in addition, at least one basic metal ingredient for stabilizing the oxidation state +5 is incorporated in this bismuth oxide compd. The amt. of Bi+5 is 5-90wt.%, pref. about 20-80wt.% to the whole bismuth content. In addition, to stabilizing the high oxidation state +5, weak basic environment is provided and for this, alkali metals, alkaline earth metals and rare earth metals are used and Li, Na, K, Sr, Ba, Cs, Y and La are pref. used.
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公开(公告)号：JPH1171313A
公开(公告)日：1999-03-16
申请号：JP17505598
申请日：1998-06-22
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , RIEKER CHRISTOPHER WILLIAM DR , DEMUTH DIRK DR , HIBST HARTMUT , HAGEMEYER ALFRED DR
IPC: B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C07C67/04 , C07C69/145 , C07C69/16
Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing 1-40 wt.% calculated as oxide of zinc or cadmium-containing X-ray amorphous zinc silicate or cadmium silicate as an active ingredient and obtained by setting a zinc salt or a cadmium salt of an acidic organic compound decomposable at a temperature lower than 400 deg.C on amorphous silicic acid and forming the catalyst at 50-500 deg.C in the presence of hydrogen and a hydroxyl group-containing compound such as a
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公开(公告)号：JPH1171314A
公开(公告)日：1999-03-16
申请号：JP17505698
申请日：1998-06-22
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , DEMUTH DIRK DR , HIBST HARTMUT , HAGEMEYER ALFRED DR
IPC: B01J23/08 , B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/16 , C07C43/303
Abstract: PROBLEM TO BE SOLVED: To safely obtain the subject compound, by adding a hydroxyl group- containing compound to an alkyne, etc., in the presence of a roentgenamorph zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing a zinc silicate as an active ingredient obtained by precipitation from an aqueous solution comprising a soluble silicon compound and zinc compound to give the objective compound of formula III or formula IV ((m) is 0 or 1). The zinc silicate is X-ray amorphous zinc silicate of the formula Zna Sic Oa+2c-0.5e (OH)e .fH2 O ((e) is a value from 0 to 2a+2c; a/c is 1-3.5 and f/a is 0 to 200) and/or a crystal zinc silicate having a hemimorphite structure of the formula Zn4 Si2 O7 ) (OH)2 .H2 O. Zinc exists in a deficient amount or an excessive amount of 25% in terms of stoichiometric composition.
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公开(公告)号：JPH1081658A
公开(公告)日：1998-03-31
申请号：JP14768297
申请日：1997-06-05
Applicant: BASF AG
Inventor： HAGEMEYER ALFRED DR , HEINEKE DANIEL DR , VOIT GUIDO DR , WITZEL TOM DR
IPC: B01J23/18 , C07B61/00 , C07C245/08 , C07C291/08
Abstract: PROBLEM TO BE SOLVED: To obtain azo(oxy)benzene useful as an intermediate for chemical industry, etc., in high efficiency by the reduction coupling of nitrobenzene in vapor phase at a high temperature using heterogeneous catalytic action of a specific redox catalyst having reduced or partially reduced form. SOLUTION: Azobenzene and azoxybenzene are produced by the reduction coupling of nitrobenzene in vapor phase at a high temperature using heterogeneous catalytic action of a specific redox catalyst having reduced or partially reduced form. The reducing catalyst contains one or more active metals such as Bi, V, Cr, Mn, Fe, Co, Pb, Mo, Ce, U, Sn, Sb, Cu, La, W, Nb, Pd, Pt, Ni and In. Nitrobenzene is passed on the redox catalyst together with one or more kinds of gaseous reducing agents free from hydrogen for the deoxidization of nitrobenzene. The average oxidized state of the active metal of the redox catalyst is lower than the maximum oxidized state stable under each reaction condition by >=0.5 before introducing nitrobenzene together with the reducing agent.
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公开(公告)号：ES2133869T3
公开(公告)日：1999-09-16
申请号：ES96114467
申请日：1996-09-10
Applicant: BASF AG
Inventor： HAGEMEYER ALFRED DR , TRUBENBACH PETER DR , RIEKER CHRISTOPHER WILLIAM , WUNSCH MARTIN DR , WATZENBERGER OTTO DR
IPC: B01J23/08 , B01J23/10 , B01J23/18 , B01J23/46 , B01J23/70 , B01J27/224 , B01J27/24 , B01J35/10 , B01J37/08 , C01B7/04
Abstract: The novel feature in Cl2 prodn. by alternatingly (a) loading a catalyst with HCl at 300-420 (pref. 360-410) degrees C and then (b) regenerating the catalyst with an O2-contg. gas at 370-460 (pref. 380-420) degrees C is that the catalyst is a sintered shape made of (by wt.): (i) 2-30% oxides and/or chlorides of Cu, Fe, Ru, Ce, Bi, Ni, Co, Ga and/or Nd; (ii) 0-30% Li-, Na-, K- and/or Zn-chloride; and (iii) 98-40% ceramic-, silicate- and/or glass-carrier. This catalyst is prepd. using inorganic metal powder and/or an active component, together with a specified polymer (mixt.) and a dispersant.
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Patent Agency Ranking
公开(公告)号：DE59602232D1
公开(公告)日：1999-07-22
申请号：DE59602232
申请日：1996-09-10
Applicant: BASF AG
Inventor： HAGEMEYER ALFRED DR , TRUEBENBACH PETER DR , RIEKER CHRISTOPHER WILLIAM , WUENSCH MARTIN DR , WATZENBERGER OTTO DR
IPC: B01J23/08 , B01J23/10 , B01J23/18 , B01J23/46 , B01J23/70 , B01J27/224 , B01J27/24 , B01J35/10 , B01J37/08 , C01B7/04
Abstract: The novel feature in Cl2 prodn. by alternatingly (a) loading a catalyst with HCl at 300-420 (pref. 360-410) degrees C and then (b) regenerating the catalyst with an O2-contg. gas at 370-460 (pref. 380-420) degrees C is that the catalyst is a sintered shape made of (by wt.): (i) 2-30% oxides and/or chlorides of Cu, Fe, Ru, Ce, Bi, Ni, Co, Ga and/or Nd; (ii) 0-30% Li-, Na-, K- and/or Zn-chloride; and (iii) 98-40% ceramic-, silicate- and/or glass-carrier. This catalyst is prepd. using inorganic metal powder and/or an active component, together with a specified polymer (mixt.) and a dispersant.
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公开(公告)号：DE19616738A1
公开(公告)日：1997-10-30
申请号：DE19616738
申请日：1996-04-26
Applicant: BASF AG
Inventor： HEINEKE DANIEL DR , HAGEMEYER ALFRED DR , WULFF-DOERING JOACHIM DR , RIEKER CHRISTOPHER WILLIAM DR , SCHNURR WERNER DR
IPC: B01J21/06 , B01J23/02 , B01J35/10 , C07C5/41 , B01J23/06 , B01J23/08 , B01J23/10 , C07C5/22 , C07C15/00 , C07C15/073 , C07C15/08
Abstract: This invention concerns a catalyst, particularly for producing aromatic compounds with 6 to 8 atoms from non-aromatic hydrocarbons with straight-chained, branched and/or cyclic alkyl or alkylene chains, respectively, with 6 to 8 carbon atoms containing essentially at least one oxide of a transition metal of the IVB group of the periodic system and, optionally, one alkaline metal or alkaline earth metal compound and/or a compound of the third main or secondary group of the periodic system and/or a rare earth metal zinc compound or a mixture thereof, with the condition that the compounds change into the corresponding oxides upon calcination.
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公开(公告)号：DE19545095A1
公开(公告)日：1997-06-05
申请号：DE19545095
申请日：1995-12-04
Applicant: BASF AG
Inventor： WATZENBERGER OTTO DR , HAGEMEYER ALFRED DR
Abstract: The invention relates to a process for the preparation of styrene by dehydrogenating a mixture of ethyl benzol and at least one xylol isomer in the gas phase in the presence of a regeneratable, oxygen-carrying, metallic-oxide catalyst (redox catalyst), with a reducible active ingredient preferably consisting of at least one metallic oxide from the group of oxides of the elements Bi, Ce, Co, Cr, Cu, Fe, In, Mn, Mo, Nb, Ni, Sb, Sn, Pb and V, the xylol being at least partially oxidised.
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公开(公告)号：DE19533484A1
公开(公告)日：1997-03-13
申请号：DE19533484
申请日：1995-09-12
Applicant: BASF AG
Inventor： TRUEBENBACH PETER DR , HAGEMEYER ALFRED DR , LAUTH GUENTER PROF DR , DINGERDISSEN UWE DR , BROECKER FRANZ JOSEF DR , FLICK KLEMENS DR
IPC: C12N11/14 , B01D53/86 , B01D53/94 , B01J21/00 , B01J21/04 , B01J21/06 , B01J23/00 , B01J23/10 , B01J27/00 , B01J27/224 , B01J27/24 , B01J29/00 , B01J35/10 , B01J37/00 , B01J37/08 , C01B7/04 , C07B61/00 , C07C5/333 , C07C5/48 , C07C15/46 , C07C37/06 , C07C37/07 , C07C39/06 , C07D203/00 , B01J32/00
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公开(公告)号：DE4446384A1
公开(公告)日：1996-06-27
申请号：DE4446384
申请日：1994-12-23
Applicant: BASF AG
Inventor： POEPEL WOLFGANG JUERGEN DR , HAGEMEYER ALFRED DR , BUECHELE WOLFGANG DR , DEIMLING AXEL DR , HOFFMANN WOLFGANG DR
Abstract: The invention concerns a method of producing olefinically unsaturated compounds such as styrene by the oxidative dehydrogenation of suitable hydrocarbons, using a pre-oxidised oxygen carrier which acts as a catalyst, in the absence of molecular oxygen, and the re-oxidation of the oxygen carrier in at least two reactors in which dehydrogenation and regeneration take place alternately and which are connected thermally via heat exchangers and a common heat-carrier circulation system.
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