3.
    发明专利
    未知

    公开(公告)号:DE3684038D1

    公开(公告)日:1992-04-09

    申请号:DE3684038

    申请日:1986-05-03

    Applicant: BASF AG

    Abstract: In the prodn. of acicular Co-contg. ferromagnetic Fe oxide, (a) gamma-FeOOH seeds are produced by the acid process in a first stage from Fe(II) salt solns. by addn. of alkali and simultaneous oxidn. by introduction of air in the presence of 0.2-1.0wt.% phosphate ions w.r.t. the amt. of gamma-FeOOH end prod.; (b) these seeds are then grown to the gamma-FeOOH end prod. in a second stage at a pH of 4-5.5; and then (c) after filtering, washing and drying, this is dehydrated at 300-600 deq.C and reduced to magnetite in the presence of organic cpds. decomposing in the presence of Fe oxide, then oxidised to gamma-Fe2O3 with gas contg. O2; then (d) modified by pptn. of Fe(OH)2 and/or Co(OH)2 in alkaline suspension, filtration, drying and tempering under inert gas at 100-350 deg.C.

    6.
    发明专利
    未知

    公开(公告)号:DE3683531D1

    公开(公告)日:1992-03-05

    申请号:DE3683531

    申请日:1986-04-23

    Applicant: BASF AG

    Abstract: Isometric magnetic Fe oxide (I) contg. 2-8 wt.% Co and 0.5-6 wt.% Ti-IV ions is produced by reacting acicular FeOOH in aq. alkaline suspension with Co-II, Fe-II and Ti-IV cpds. at pH over 8 under inert gas at temps. between 35 deg. C and the b.pt. of the suspension. The reaction prod. is (partly) oxidised with oxidising gas at 120-450 deg. C. The original gamma-FeOOH may contain Co and/or Ti, in which case addn. of Co-II and/or Ti-IV ions may not be necessary. It is pref. used in the suspension contg. salts in which it is prepd..

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