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公开(公告)号:CA1097314A
公开(公告)日:1981-03-10
申请号:CA311193
申请日:1978-09-13
Applicant: BASF AG
Inventor: HEINZ GERHARD , DIKOW HERMANN , JARRE WOLFGANG , NISSEN DIETMAR , MATTHIAS KLAUS , KAEPPEL HANSHELMUT
IPC: C08G18/10
Abstract: PROCESS FOR THE MANUFACTURE OF ORGANIC POLYMER POLYOL A process for the manufacture of partially dehydrated organic polymer polyol dispersions from the reaction of polyhydroxyl compounds and aqueous polymer dispersions wherein the problem of excessive viscosity is overcome by mixing the reactants with a recycled partially dehydrated polyol polymer dispersion, removing water from the reaction mixture, removing a portion of the partially dehydrated polyol polymer dispersion, and recycling the remainder.
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公开(公告)号:CA1136349A
公开(公告)日:1982-11-23
申请号:CA325402
申请日:1979-04-10
Applicant: BASF AG
Inventor: JARRE WOLFGANG , MUELLER GERHARD , ZIPP OTMAR , ROPTE ECKHARD
IPC: C08G18/00 , C08G18/38 , C08G18/72 , C08G18/76 , C08J9/00 , C08K5/29 , C08L75/04 , C08G18/14 , C08K5/34
Abstract: The invention concerns a process for the manufacture of flame resistant flexible polyurethane foams by reacting a mixture of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyanates having a functionality greater than 2 containing 40 to 90 percent by weight diphenylmethane diisocyanate based on the total weight of said mixture; polyols, cyanic acid derivatives such as cyanamide, dicyandiamide, guanidine, biguanidine, melamine, cyanuric alkyl esterhydrazides and -amides as flame inhibitors, and blowing agents; as well as, possibly, chain extenders and other additives. The flexible polyurethane foams are suited for the familiar areas of applications, but especially as sound-insulation material for the construction industry.
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公开(公告)号:MX149926A
公开(公告)日:1984-02-09
申请号:MX17724479
申请日:1979-04-09
Applicant: BASF AG
Inventor: JARRE WOLFGANG , MUELLER GERHARD , ZIPP OTMAR , ROPTE ECKHARD
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公开(公告)号:CA1129599A
公开(公告)日:1982-08-10
申请号:CA325401
申请日:1979-04-10
Applicant: BASF AG
Inventor: JARRE WOLFGANG , STUTZ HERBERT , SCHOEN ERNST
Abstract: MANUFACTURE OF FLEXIBLE FOAMS of the Invention This invention concerns a process for the manufacture of flexible polyurethane foams from urethane-modified aromatic polyisocyanates having an NCO content of 15 to 30 percent by weight and a viscosity of 100 to 2000 centipoises at 20.degree.C, which are obtained by reaction of a mixture of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyanates containing 55 to 85 percent by weight of diphenylmethane diisocyanate based on the total weight of the polyisocyanate mixture and a hydroxyl compound with 2 to 4 Zerewitinoff active hydrogen atoms and a molecular weight of 60 to 1500, in an equivalency ratio of NCO groups to active hydrogen atoms of the hydroxyl compound of 2:1 to 60:1, polyols, catalysts, blowing agents, and optionally, chain extenders, auxiliaries, and additives.
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5.
公开(公告)号:CA1161996A
公开(公告)日:1984-02-07
申请号:CA379138
申请日:1981-06-05
Applicant: BASF AG
Inventor: HORACEK HEINRICH , MARX MATTHIAS , BUETHE INGOLF , JARRE WOLFGANG , SCHOEN ERNST
Abstract: PROCESS FOR THE PREPARATION OF FLEXIBLE POLYURETHANE FOAMS INVOLVING THE USE OF ALIPHATIC MONOAMINES The invention relates a process for the preparation of a polyurethane foam by reacting an organic polyisocyanate, polyol, and primary or secondary aliphatic monoamine in the presence of a blowing agent and catalyst. The amines are used in quantities of 0.1 part to 10 parts by weight per 100 parts per weight of polyol. The highly elastic polyurethane flexible foams are suited for the manufacture of upholstered furniture, matresses, automobile seats and head supports, as well as particularly for molded foams. The semi-rigid polyurethane foams are used as foam backing of dashboards in automobiles, thermal and sound insulation in buildings and vehicles, and for impact absorption in packaging materials.
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公开(公告)号:CA1152685A
公开(公告)日:1983-08-23
申请号:CA357779
申请日:1980-08-07
Applicant: BASF AG
Inventor: NISSEN DIETMAR , MARX MATTHIAS , JARRE WOLFGANG , SCHOEN ERNST , DECKER WALTER
Abstract: Stable melamine-polyoxyalkylene polyether polyol dispersions are prepared by the in situ reduction of melamine particles wherein 90 percent of the melamine particles have a particle size of less than 10 microns. Stabilizers for the melanine-polyol dispersion are selected from the group eonsisting of a) silicic acids and silicates, b) salts of perfluorinated alkyl carboxylic acids having 4 to 20 carbon atoms, salts of alkyl sulfonic acids and perfluorinated alkylsulfouic acids having 4 to 20 carbon atoms and polyperfluoroether polyols having molecular wights of 300 to 6000, and c) salts of fatty alcohol sulfates having 6 to 30 carbon atoms. These dispersions are useful for the preparation of polyurethane foams.
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公开(公告)号:CA1129598A
公开(公告)日:1982-08-10
申请号:CA325400
申请日:1979-04-10
Applicant: BASF AG
Inventor: JARRE WOLFGANG , WEYLAND PETER , MUELLER GERHARD
Abstract: The invention concerns a process for the manufacture of flexible polyurethane foams by reaction of a mixture consisting of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyantes having a functionality greater than 2 containing 55 to 85 percent by weight diphenylmethane diisocyanate based on the total weight of the isocyanate mixture with polyester polyols or mixtures of polyester polyols and polyether polyols having a polyester polyol content of more than 60 percent by weight based on the weight of the polyol mixture, and optionally chain extenders, auxiliaries, and additives, in the presence of catalysts and, in particular, water as a blowing agent. The special selection of starting compounds results in the production of flexible polyurethane foams having a high resistance to hydrolysis, high load-bearing capacity, and high energy absorption upon impact.
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公开(公告)号:CA1270093A
公开(公告)日:1990-06-05
申请号:CA510519
申请日:1986-05-30
Applicant: BASF AG
Inventor: MUELLER GERHARD , MARX MATTHIAS , JARRE WOLFGANG , BAUMANN EDWIN , BUETHE INGOLF
Abstract: PROCESS FOR THE PREPARATION OF ELASTIC POLYURETHANE FLEXIBLE FOAMS USABLE IN COLD-MOLD TECHNIOUES TO PRODUCE MOLDED ARTICLES The invention is a process for the preparation of elastic polyurethane flexible foams having densities from approximately 25 to 60 kg/m3, and producing molded articles in closed molds at temperatures from 25 to 80.degree.C, comprising reacting A) an organic polyisocyanate prepolymer having an isocyanate content from 6 to 20 percent by weight prepared by reacting a toluene diisocyanate and/or a diphenylmethane diisocyanate with a di- to tetrafunctional polyether polyol having a hydroxyl number from 20 to 50 and oxyethylene terminal group content of at least 10 to 30 percent by weight B) a mixture of compounds containing reactive hydrogen atoms, comprising a mixture of a) from 55 to 89.5 parts by weight of at least one dito tetrafunctional polyether polyol having a hydroxyl number of from 20 to 80 and less than 10 percent by weight terminal oxyethylene groups, b) from 0.5 to 20 parts by weight of at least one alkanolamine, and c) from 10 to 25 parts by weight water, in the presence of C) a blowing agent, D) a catalyst, and optionally E) auxiliaries and/or additives.
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9.
公开(公告)号:CA1164149A
公开(公告)日:1984-03-20
申请号:CA379129
申请日:1981-06-05
Applicant: BASF AG
Inventor: HORACEK HEINRICH , MARX MATTHIAS , BUETHE INGOLF , JARRE WOLFGANG , SCHOEN ERNST
Abstract: PROCESS FOR THE PREPARTIAON OF FLEXIBLE POLYURETHANE FOAMS INVOLVING THE USE OF AROMATIC MONOAMINES The invention relates a process for the preparation of a polyurethane foam by reacting an organic polyisocyanate, polyol, and primary or secondary aromatic monoamine in the presence of a blowing agent and catalyst. The amines are used in quantities of 0.1 part to 4 parts by weight per 100 parts per weight of polyol. The highly elastic polyurethane flexible foams are suited for the manufacture of upholstered furniture, matresses, automobile seats and head supports, as well as particularly for molded foams. The semi-rigid polyurethane foams are used as foam backing of dashboards in automobiles, thermal and sound insulation in buildings and vehicles, and for impact absorption in packaging materials.
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公开(公告)号:MX149927A
公开(公告)日:1984-02-09
申请号:MX17724879
申请日:1979-04-09
Applicant: BASF AG
Inventor: JARRE WOLFGANG , STUTZ HERBERT , SCHOEN ERNST
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