公开(公告)号：JP2007051142A

公开(公告)日：2007-03-01

申请号：JP2006216786

申请日：2006-08-09

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

Inventor： JOEDECKE MICHAEL ,  LANG ORTMUND ,  CAUWENBERGE GUNTHER VAN ,  FRAUENKRON MATTHIAS

IPC: C07D295/02 ,  C07C209/86 ,  C07C211/10

CPC classification number: C07D295/00

Abstract: PROBLEM TO BE SOLVED: To improve qualities of piperazine, especially its color and color stability in a method for continuously distilling and removing piperazine from a mixture of ethylenediamine and piperazine by distilling the mixture under high-pressure at elevated temperature, discharging ethylenediamine from the top of a distillation column and piperazine from the bottom of the distillation column. SOLUTION: The method for continuously distilling and removing piperazine from a mixture of ethylenediamine and piperazine comprises a process of direct circulation treatment in which piperazine discharged from the bottom of the distillation column is transported through an evaporation apparatus operated at about 160-about 170°C and returned to the distillation apparatus and a process in which piperazine is retained in a system for the circulation treatment for 30-about 60 minutes and then discharged in a state of vapor from a side discharge port at the bottom of the distillation column. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：为了提高哌嗪的质量，特别是在高温下通过在高温下蒸馏混合物从乙二胺和哌嗪的混合物中连续蒸馏除去哌嗪的方法中的颜色和颜色稳定性，将乙二胺 从蒸馏塔的顶部和来自蒸馏塔底部的哌嗪。 解决方案：从乙二胺和哌嗪的混合物中连续蒸馏除去哌嗪的方法包括直接循环处理的方法，其中从蒸馏塔底部排出的哌嗪通过在约160-约 170℃，返回到蒸馏装置中，并且在循环处理体系中保留哌嗪30〜约60分钟，然后以蒸气状态从蒸馏塔底部的侧排出口排出的方法 。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：WO2006114417A2

公开(公告)日：2006-11-02

申请号：PCT/EP2006061823

申请日：2006-04-25

Applicant: BASF AG ,  EVERS HOLGER ,  MELDER JOHANN-PETER ,  HIMMEL WALTER ,  KRUG THOMAS ,  GERLACH TILL ,  JOEDECKE MICHAEL ,  NOUWEN JAN ,  ROETTGER RODERICH

Inventor： EVERS HOLGER ,  MELDER JOHANN-PETER ,  HIMMEL WALTER ,  KRUG THOMAS ,  GERLACH TILL ,  JOEDECKE MICHAEL ,  NOUWEN JAN ,  ROETTGER RODERICH

IPC: C07C209/16

CPC classification number: C07D295/033 ,  C07C209/16 ,  C07C209/60 ,  C07C213/04 ,  C07C211/10 ,  C07C211/14 ,  C07C215/08 ,  C07C215/12 ,  C07C215/14

Abstract: Disclosed is a method for producing ethyleneamines, in which ethylene oxide (EO) is continuously reacted with ammonia on an inorganic ion exchanger as a heterogeneous catalyst in anhydrous conditions in a first reaction stage, the obtained reaction product containing monoethanolamine (MEOA), diethanolamine (DEOA), and triethanolamine (TEOA) at a weight ratio MEOA: DEOA: TEOA = 80 - 94: 5.9 - 15: 0.1 - 5, and the reaction product is then continuously reacted with ammonia in the presence of hydrogen and a heterogeneous hydrogenation catalyst in a second reaction stage.

Abstract translation: 一种用于制备Ethyienaminen得到（EO）作为非均相催化剂的方法进行反应在第一反应步骤中环氧乙烷与无水的条件下氨，连续的无机离子交换剂，一乙醇胺的所得反应产物（MEOA），在重量比的二乙醇胺（DEOA）和三乙醇胺（TEOA） MEOA：DEOA：TEOA = 80-94：5.9至15：0,1 - 5包括，并将该反应产物然后在氢气存在下和非均相氢化催化剂与氨的第二反应步骤连续进行反应。

公开(公告)号：DE502006000360D1

公开(公告)日：2008-04-03

申请号：DE502006000360

申请日：2006-03-15

Applicant: BASF AG ,  T & R ENGINEERING GMBH

Inventor： TUESHAUS RUEDIGER ,  ROESSLER PETER ,  FRIESE THORSTEN ,  JOEDECKE MICHAEL

IPC: B01J19/32

公开(公告)号：DE102004038107A1

公开(公告)日：2006-03-16

申请号：DE102004038107

申请日：2004-08-05

Applicant: BASF AG

Inventor： EVERS HOLGER ,  JOEDECKE MICHAEL ,  MELDER JOHANN-PETER ,  CAUWENBERGE GUNTHER VAN ,  NOUWEN JAN

IPC: C07D295/023

公开(公告)号：DE102005019373A1

公开(公告)日：2006-11-02

申请号：DE102005019373

申请日：2005-04-26

Applicant: BASF AG

Inventor： EVERS HOLGER ,  MELDER JOHANN-PETER ,  HIMMEL WALTER ,  KRUG THOMAS ,  GERLACH TILL ,  JOEDECKE MICHAEL ,  NOUWEN JAN ,  ROETTGER RODERICH

IPC: C07C209/24 ,  C07C211/10 ,  C07C213/04 ,  C07C215/18

Abstract: Preparation of ethylenamine comprises continuous reaction of ethylene oxide with ammonia on an inorganic ion-exchanger as a heterogeneous catalyst in an anhydrous condition, where the obtained reaction product consists of monoethanolamine, diethanolamine and triethanolamine in a weight ratio of 80-94:5.9-15:0.1-5, respectively, and continuous reaction of the reaction product with ammonia in the presence of hydrogen and a heterogeneous hydrogenation catalyst.

公开(公告)号：DE102005038376A1

公开(公告)日：2007-02-15

申请号：DE102005038376

申请日：2005-08-13

Applicant: BASF AG

Inventor： JOEDECKE MICHAEL ,  LANG ORTMUND ,  CAUWENBERGE GUNTHER VAN ,  FRAUENKRON MATTHIAS

IPC: C07D295/023 ,  B01D3/14 ,  C07C211/10

Abstract: Continuous distillative separation of piperazine from ethylenediamine-piperazine mixture comprises subjecting the piperazine mixture into a cyclic motion, introducing the piperazine mixture into an evaporator unit at 160-170[deg]C, recycling the piperazine mixture into a distillation column and removing the piperazine from the sump of the distillation column after a retention time of approximately 30-60 minutes, where the ethylene diamine is discharged at the upper portion of the distillation column.