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公开(公告)号:DE2232363A1
公开(公告)日:1974-01-31
申请号:DE2232363
申请日:1972-07-01
Applicant: BASF AG
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公开(公告)号:DE3882086D1
公开(公告)日:1993-08-05
申请号:DE3882086
申请日:1988-04-27
Applicant: BASF AG
Inventor: OSTERMAYER BERTRAM DR , SEILER ERHARD DR , WAGNER DANIEL DR , BRONSTERT KLAUS DR , LADENBERGER VOLKER DR
Abstract: 1. Thermoplastic mouldingmaterials (I) comprise 20-79 pts. wt. polyphenylene ether (PPE), 1-20 pts. wt. A-B-A' block copolymer comprising two vinylaromatic blocks A, A' and a partly hydrogenated rubber block B (II), 0-70 pts.wt. of a polyvinylaromatic (III) and 0-40 pts.wt. usual additives; the novelty is that mol. wts. of A and A' differ by a factor of 2-20, shorter block (A) has mol.wt. 2000-4000 and A+A' constitute 35-50 wt.% of (II). 2. (I) are mfd. by mixing at 250-320 deg.C for 0.5-30 mins. Specifically, A+A' make up 35-40 wt.% of (II), mol. wts. of A and A' differ by a factor of 4-8 and A has mol.wt. 3000-3800; block B still contains 10-20 wt.% of the double bonds originally present.
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公开(公告)号:DE3714710A1
公开(公告)日:1988-11-17
申请号:DE3714710
申请日:1987-05-02
Applicant: BASF AG
Inventor: OSTERMAYER BERTRAM DR , SEILER ERHARD DR , WAGNER DANIEL DR , BRONSTERT KLAUS DR , LADENBERGER VOLKER DR
Abstract: The thermoplastic moulding compositions contain… a) from 20 to 80 parts by weight of a polyphenylene ether,… b) from 1 to 20 parts by weight of a block copolymer of the formula A-B-A' comprising two polyvinylaromatic blocks A and A' and one partially hydrogenated rubber block B,… c) from 0 to 70 parts by weight of a polyvinylaromatic compound and… d) from 0 to 40 parts by weight of conventional additives,… the sum of a) to d) giving 100 parts by weight and… - the mean molecular weights of A + A' differing by a factor of from 2 to 20,… - the shorter block A having a mean molecular weight of from 2000 to 4000 and… - blocks A and A' together making up from 35 to 50% by weight of b).
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公开(公告)号:DE3628994A1
公开(公告)日:1988-03-03
申请号:DE3628994
申请日:1986-08-26
Applicant: BASF AG
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公开(公告)号:DE3106959A1
公开(公告)日:1982-09-09
申请号:DE3106959
申请日:1981-02-25
Applicant: BASF AG
Inventor: GERBERDING KARL DR , LADENBERGER VOLKER DR , MUELLER WOLFGANG F DR , SCHMITT BURGHARD DR , VOGEL HANS-HENNING
IPC: C08F4/48 , C08F212/08 , C10M143/12 , C08F236/10 , C10M1/18 , C10M3/12
Abstract: A process for the preparation of copolymers by polymerising from 52 to 54% by weight of styrene and 48 to 46% by weight of butadiene with alkyllithium initiators in the presence of tetrahydrofuran, where certain maximum temperatures are not exceeded, and subsequently hydrogenating the copolymer, and the use of the hydrogenated copolymers as viscosity index improvers for lubricant oils.
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公开(公告)号:DE2111966A1
公开(公告)日:1972-09-21
申请号:DE2111966
申请日:1971-03-12
Applicant: BASF AG
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公开(公告)号:DE19724914A1
公开(公告)日:1998-12-17
申请号:DE19724914
申请日:1997-06-12
Applicant: BASF AG
Inventor: MEHLER CHRISTOF DR , GRUBER FREDDY DR , LADENBERGER VOLKER DR
IPC: C08F297/04 , C10L1/16 , C10M143/12 , C08F297/00
Abstract: A hydrogenated star-shaped polymer (I) has (a) a nucleus of a poly(polyalkenyl aromatic coupling agent) (II) and (b) a number of arms consisting of hydrogenated polymer chains comprising cone shaped copolymers of 4-12C conjugated dienes and 8-12 C monoalkenyl aromatics. The hydrogenated polymer chains comprise a multi-block copolymer with at least 2 blocks of the cone shaped copolymer of the diene and monoalkenyl aromatic. Also claimed is a process for the production of (I) by (i) solution polymerisation of a 4-12C conjugated diene and a monoalkenyl aromatic in the presence of an anionic polymerisation initiator to form a living cone shaped copolymer, (ii) reaction of the resulting product with a 10-20C polyalkenyl aromatic coupling agent (II) or a mixture of (II) with a 8-12C alkenyl aromatic to form a star shaped polymer and (iii) deactivation and hydrogenation of the resulting polymer.
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公开(公告)号:DE1768206A1
公开(公告)日:1971-10-14
申请号:DE1768206
申请日:1968-04-13
Applicant: BASF AG
Inventor: KNIESE WILHELM DR , NIENBURG HANS DR , TAVS PETER DR , KASTNING ERNST-GUENTHER DR , LADENBERGER VOLKER DR
IPC: C07C45/50
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公开(公告)号:DE2201243A1
公开(公告)日:1973-08-02
申请号:DE2201243
申请日:1972-01-12
Applicant: BASF AG
Inventor: BRONSTERT KLAUS DR , HOFMANN ALFRED DR , LADENBERGER VOLKER DR , FAHRBACH GERHARD DR , GLASER RUDOLF DR
Abstract: Parent patent compsn. comprising opt. impact resistant modified (co)polymer of (substd) styrene, (b) alpha-olefin (co)polymer and (c) block copolymer A-B (where A is polyvinylaromatic block of mol. wt. 10,000-150,000, B is polyolefin block of mol. wt. 10,000-200,000 with 10% C-C bonds unsatd. and mole ratio A:B is 10-90 to 70-30, where wt. ratio (a):(b) is 2:1 to 1:4 and (c) content is 10-70 wt.%, is improved in that (c) content is reduced to 1-10 wt.%. Prod. is esp. suitable for prodn. of films by blowing giving a prod. with smooth fine-grained surface and good strength, which can be used as adhesive between styrene-and olefin polymer.
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公开(公告)号:DE2137274A1
公开(公告)日:1973-02-08
申请号:DE2137274
申请日:1971-07-26
Applicant: BASF AG
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