Method for producing polyvinyl alcohol-polyether-graft copolymer through extrusion
    2.
    发明专利
    Method for producing polyvinyl alcohol-polyether-graft copolymer through extrusion 审中-公开
    通过挤出生产聚乙烯醇 - 聚醚 - 共聚物的方法

    公开(公告)号:JP2006176777A

    公开(公告)日:2006-07-06

    申请号:JP2005368439

    申请日:2005-12-21

    CPC classification number: C08F8/12 B29C47/00 C08F283/06 C08F218/08

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polyvinyl alcohol-polyether-graft copolymer, by which the product is obtained in a form capable of being advantageously used by an injection molding method or a film extrusion method, and by which the graft copolymer containing the vinyl alcohol in a copolymerized form and having a surely adjustable hydrolysis degree can simply be produced without accompanying a complicated process, especially a steam distillation process and a spray drying process.
    SOLUTION: This method for producing the graft copolymer (P2) having repeating units originated from the vinyl alcohol and having polyether groups comprises reacting a graft copolymer (P1) having repeating units originated from a vinyl alcohol ester and having polyether groups with water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder. Namely, the method for preparing the graft copolymer having repeating units originated from the vinyl alcohol and having the polyether groups comprises reacting the corresponding graft copolymer based on the vinyl alcohol ester with the water and/or at least one 1 to 6C alkanol in the presence of a catalyst in an extruder.
    COPYRIGHT: (C)2006,JPO&NCIPI

    Abstract translation: 待解决的问题:提供一种生产聚乙烯醇 - 聚醚 - 接枝共聚物的方法,通过该方法可以通过注射成型法或薄膜挤出法有利地使用该产品,并且通过 含有共聚形式的乙烯醇并具有可确定的水解度的接枝共聚物可以简单地制备而不伴随复杂的方法,特别是蒸汽蒸馏法和喷雾干燥法。 解决方案:用于制备具有源自乙烯醇并具有聚醚基团的重复单元的接枝共聚物(P2)的方法包括使具有源自乙烯醇酯的具有聚醚基团的重复单元的接枝共聚物(P1)与水 和/或至少一种1至6C链烷醇在催化剂存在下在挤出机中进行。 也就是说,制备具有源自乙烯醇并具有聚醚基团的重复单元的接枝共聚物的方法包括使相应的乙烯醇酯接枝共聚物与水和/或至少一种1至6C链烷醇在存在下反应, 的挤出机中的催化剂。 版权所有(C)2006,JPO&NCIPI

    N-VINYLCAPROLACTAM-BASED COPOLYMERS AND THE USE THEREOF AS SOLUBILIZERS
    4.
    发明申请
    N-VINYLCAPROLACTAM-BASED COPOLYMERS AND THE USE THEREOF AS SOLUBILIZERS 审中-公开
    基于N-乙烯基己内酰胺共聚物及其作为增溶剂使用

    公开(公告)号:WO2007017452A2

    公开(公告)日:2007-02-15

    申请号:PCT/EP2006064993

    申请日:2006-08-02

    CPC classification number: C08F226/06

    Abstract: The invention relates to the use of copolymers which comprise a) 60 to 99 % by weight of N-vinylcaprolactam; b) 1 to 40 % by weight of at least one monomer b) selected from the group including: b1) C8-C30 alkyl esters of monoethylenically unsaturated C3-C8 carboxylic acids; b2) N-alkyl- or N,N-dialkyl-substituted amides of the acrylic acid or the methacrylic acid with C8 to C30 alkyl groups; b3) the vinyl esters of aliphatically unbranched C8-C30 carboxylic acids; b4) the C8-C30 alkyl-vinyl ethers, as solubilizers for substances that are difficult to dissolve in water.

    Abstract translation: 使用包括:a)60〜99重量%的N-乙烯基己内酰胺共聚物; B)1〜40重量 - 的至少一种单体B的%)选自:. b1的选择的)的不饱和C 3 monoethylensich -C 8 - 羧酸C 8 -C 30烷基酯; b2)的N-烷基或N,N-二烷基取代的丙烯酸或甲基丙烯酸与C8至C30烷基的酰胺; B3)的脂肪族无支链C8-C30羧酸的乙烯基酯; B4)的C8-C30烷基乙烯基醚,如增溶剂为水难溶性物质。

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