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公开(公告)号:WO2005044771A3
公开(公告)日:2005-07-28
申请号:PCT/EP2004012543
申请日:2004-11-05
Applicant: BASF AG , HAUK ALEXANDER , KARL JOERN , PASCHOLD JUERGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT , LETZELTER THOMAS , HEINZ ROBERT
Inventor: HAUK ALEXANDER , KARL JOERN , PASCHOLD JUERGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT , LETZELTER THOMAS , HEINZ ROBERT
CPC classification number: C07C51/412 , C07C53/06 , C07C53/02
Abstract: The invention relates to a method for the production of formic acid formates, wherein a flowing liquid (I) containing formic acid, and a flowing liquid (II) containing a metal formate, are provided. The flowing liquids (I) and (II) are guided to a rectification column such that a higher or equal guiding point for the liquid flow (II) is selected for the rectification column for the liquid flow (I). The liquid flows (I) and (II) in the rectification column are mixed by separating water via the head of the rectification column and the liquid flow is withdrawn from the rectification column, said liquid flow containing the formic acid formate. The invention is characterised in that the liquid flow is obtained as a melt containing at least 0.5 wt. % water.
Abstract translation: 公开了一种用于制备酸甲酸盐的方法,它包括:含有甲酸和(II)含有金属甲酸盐提供,液体流的液体流(I)中的液体流(I)和(II)精馏塔所以 被选择用于液体物流(II)供给具有较高或相同的进料点为液体流(I)中,液体流(I)和(II)中经由精馏柱的顶部与水分离的精馏塔混合精馏塔 和从精馏塔包含酸甲酸盐的塔底物流,减,其特征在于,一个重量%水,胜塔底流含有小于0.5的熔体。
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公开(公告)号:ZA200603539B
公开(公告)日:2008-02-27
申请号:ZA200603539
申请日:2006-05-04
Applicant: BASF AG
Inventor: HAUK ALEXANDER , KARL JOERN , LOHMANN ANNA VALESKA , LENZ ROBERT , PASCHOLD JUERGEN , GROPP STEFAN , LETZELTER THOMAS , HEINZ ROBERT
IPC: C07C20090101 , C07C51/41
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公开(公告)号:DE502004004050D1
公开(公告)日:2007-07-19
申请号:DE502004004050
申请日:2004-11-05
Applicant: BASF AG
Inventor: HAUK ALEXANDER , KARL JOERN , PASCHOLD JUERGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT , LETZELTER THOMAS , HEINZ ROBERT
Abstract: A process is proposed for preparing acid formates in which a liquid stream I comprising formic acid and a liquid stream II comprising a metal formate are prepared, the liquid streams I and II are fed to a rectification column in such a manner that a higher or identical feed point to the rectification column is chosen for the liquid stream II than for the liquid stream I, the liquid streams I and II are mixed in the rectification column, with water being removed overhead from the rectification column and a bottoms stream comprising the acid formate is taken off from the rectification column, which comprises the bottoms stream being produced as melt comprising less than 0.5% by weight of water.
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公开(公告)号:DE102005062931A1
公开(公告)日:2007-07-05
申请号:DE102005062931
申请日:2005-12-29
Applicant: BASF AG
Inventor: HAUK ALEXANDER , GROPP STEFAN , LOHMANN ANNA VALESKA , HEINZ ROBERT
Abstract: Preparation of a solid sodium formate preparation comprises (i) preparing an aqueous solution, which exhibits formic acid, sodium formate and water; (ii) subjecting the aqueous solution to crystallization and separating a solid phase from mother liquor; (iii) supplying the mother liquor during the production of the aqueous solution, to a distilling device; (iv) mixing the mother liquor with a sodium-containing base to form a mixture containing sodium formate and formic acid; (v) mixing the mixture with formic acid; and (vi) removing the water by withdrawing from the distilling device. Preparation of a solid sodium formate preparation with a content of at least 35 wt.% of formic acid, comprises: (i) at increased temperature, preparing an aqueous solution, which exhibits a molar ratio of formic acid and sodium formate of more than 1.5:1 and a molar ratio of formic acid and water of at least 1.1:1; (ii) subjecting the aqueous solution to crystallization and separating a solid phase from mother liquor; (iii) supplying the mother liquor, optionally after removal of a partial quantity of the mother liquor, during the production of the aqueous solution, to a distilling device; (iv) mixing the mother liquor with a sodium-containing base to form a mixture containing sodium formate and formic acid; (v) mixing the mixture with formic acid under receipt of the aqueous solution; and (vi) removing the water that is not needed for the production of the aqueous solution, by withdrawing from the distilling device.
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公开(公告)号:NO20045063L
公开(公告)日:2005-02-11
申请号:NO20045063
申请日:2004-11-22
Applicant: BASF AG
Inventor: HJORNEVIK LEIF , SCHONHERR MICHAEL , KARL JORN , HAUK ALEXANDER , DIEBOLD GERD , HABICH ANDREAS , LENZ ROBERT , LOHMANN ANNA VALESKA , SCHMIDT VOLKER
IPC: A23K3/03 , A23K1/00 , A23K1/16 , A23K1/175 , A23K1/18 , A23K3/00 , A23L1/00 , A23P1/04 , C05F11/00 , C05G3/00 , C05G3/60
Abstract: Coated formulation contains sodium, potassium, cesium and/or ammonium diformate(s) (I). Coated formulation contains diformate(s) of formula (I): [Image] X : Na, K, Cs, NH 4. Independent claims are also included for the following: (1) production of coated formulations by coating diformate(s) (I), optionally mixed with other constituents and/or additives, with a coating agent, optionally containing other constituents; (2) production of animal feed and/or animal feed additives by making a premix from (I) and optionally other constituents and/or additives and mixing this with the other constituents of the feed and/or additive; and (3) animal feed containing the formulation. ACTIVITY : Plant Growth Promoter; Fertilizer. MECHANISM OF ACTION : None given.
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公开(公告)号:MY136031A
公开(公告)日:2008-07-31
申请号:MYPI20044509
申请日:2004-11-01
Applicant: BASF AG
Inventor: HAUK ALEXANDER DR , KARL JORN DR , PASCHOLD JURGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT , LETZELTER THOMAS , HEINZ ROBERT
Abstract: A PROCESS IS PROPOSED FOR PREPARING ACID FORMATES IN WHICH - A LIQUID STREAM I COMPRISING FORMIC ACID AND - A LIQUID STREAM II COMPRISING A METAL FORMATE ARE PREPARED, THE LIQUID STREAMS I AND II ARE FED TO A RECTIFICATION COLUMN IN SUCH A MANNER THAT A HIGHER OR IDENTICAL FEED POINT TO THE RECTIFICATION COLUMN IS CHOSEN FOR THE LIQUID STREAM II THAN FOR THE LIQUID STREAM I,THE LIQUID STREAMS I AND II ARE MIXED IN THE RECTIFICATION COLUMN, WITH WATER BEING REMOVED OVERHEAD FROM THE RECTIFICATION COLUMN AND A BOTTOMS STREAM COMPRISING THE ACID FORMATE IS TAKEN OFF FROM THE RECTIFICATION COLUMN,WHICH COMPRISES THE BOTTOMS STREAM BEING PRODUCED AS MELT COMPRISING LESS THAN 0.5% BY WEIGHT OF WATER.(FIG 1)
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公开(公告)号:ES2286693T3
公开(公告)日:2007-12-01
申请号:ES04797653
申请日:2004-11-05
Applicant: BASF AG
Inventor: HAUK ALEXANDER , KARL JORN , PASCHOLD JURGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT
Abstract: Procedimiento para la obtención de formiatos de ácido fórmico, según el cual - se pone a disposición una corriente líquida I, que contiene ácido fórmico, y - una corriente líquida II, que contiene un formiato metálico, las corrientes líquidas I y II se alimentan a una columna de rectificación de modo que para la corriente líquida II se selecciona un punto de alimentación más elevado, o el mismo que para la corriente líquida I para la columna de rectificación, las corrientes líquidas I y II se mezclan en la columna de rectificación bajo separación de agua a través de la columna de rectificación, y de la columna de rectificación se extrae una corriente de cola que contiene el formiato de ácido fórmico, caracterizado porque se obtiene la corriente de cola como fusión, que contiene menos de un 0, 5 % en peso de agua.
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公开(公告)号:NO20074865A
公开(公告)日:2007-11-09
申请号:NO20074865
申请日:2007-09-25
Applicant: BASF AG
Inventor: HEINZ ROBERT , MACHHAMMER OTTO , HAUK ALEXANDER , LOHMANN ANNA VALESKA , GROPP STEFAN , DIEBOLD GERD , FEUERSTEIN DIETER , RUEHLE ROBERT , SCHMITT RUEDIGER
CPC classification number: C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
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公开(公告)号:AU2003246394A1
公开(公告)日:2004-02-02
申请号:AU2003246394
申请日:2003-07-07
Applicant: BASF AG
Inventor: HAUK ALEXANDER , DIEBOLD GERD , HABICH ANDREAS , LENZ ROBERT , LOHMANN ANNA VALESKA , SCHMIDT VOLKER , SCHONHERR MICHAEL , KARL JORN
Abstract: The present invention relates to preparations comprising at least one diformate of the general formula XH(COOH) 2 , where X=Na, K, Cs, NH 4 and at least one short-chain carboxylic acids and/or at least one salt of the short-chain carboxylic acid and/or at least one ester and/or at least one derivative of the short-chain carboxylic acid, and to the use of these preparations.
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公开(公告)号:DE10231895A1
公开(公告)日:2004-01-22
申请号:DE10231895
申请日:2002-07-12
Applicant: BASF AG
Inventor: SCHOENHERR MICHAEL , KARL JOERN , HAUK ALEXANDER , DIEBOLD GERD , HABICH ANDREAS , LENZ ROBERT , LOHMANN ANNA VALESKA , SCHMIDT VOLKER
IPC: A23K1/00 , A23K1/16 , A23K1/175 , A23K3/00 , A23K3/03 , A23L1/00 , C05F11/00 , C07C53/06 , A61L2/16 , B01J2/30 , C05G5/00 , C07C51/41 , C07C51/50
Abstract: Coated formulation contains sodium, potassium, cesium and/or ammonium diformate(s) (I). Coated formulation contains diformate(s) of formula (I): [Image] X : Na, K, Cs, NH 4. Independent claims are also included for the following: (1) production of coated formulations by coating diformate(s) (I), optionally mixed with other constituents and/or additives, with a coating agent, optionally containing other constituents; (2) production of animal feed and/or animal feed additives by making a premix from (I) and optionally other constituents and/or additives and mixing this with the other constituents of the feed and/or additive; and (3) animal feed containing the formulation. ACTIVITY : Plant Growth Promoter; Fertilizer. MECHANISM OF ACTION : None given.
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