-
公开(公告)号:JPH10298129A
公开(公告)日:1998-11-10
申请号:JP3597798
申请日:1998-02-18
Applicant: BASF AG
Inventor: FISCHER ROLF DR , SCHNURR WERNER DR , WULFF-DOERING JOACHIM DR , MERGER MARTIN DR
IPC: C07D307/12 , B01J23/10 , C07B41/06 , C07B61/00 , C07C45/41 , C07C47/02 , C07D309/06 , C07D309/08
Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially efficiently and continuously producing an aldehyde by hydrogenating an ester, while recycling the unused hydrogen and the unreacted ester, wherein the selectivity of the aldehyde is maintained at a satisfactory level. SOLUTION: This method for producing an aldehyde of the formula: R-CHO comprises hydrogenating an ester of the formula: R-COOR' (R is a non- substituted or substituted aliphatic group, alicyclic group, aromatic group or aralkyl group; R' is a group derived from a 1-10C alcohol] with excessive hydrogen in an amount of 2-200 moles per mole of the ester in the presence of a heterogeneous hydrogenation catalyst at 200-450 deg.C in a gas phase, while recycling the unreacted hydrogen and the unreacted ester. Therein, the alcohol is removed from the recycling flow in such an extent as the initial concentration of the produced alcohol: R'-OH in the reaction mixture is maximally 1 mole per mole of the carboxylic acid ester II.
-
公开(公告)号:AT287869T
公开(公告)日:2005-02-15
申请号:AT01125324
申请日:2001-10-26
Applicant: BASF AG
Inventor: ANSMANN ANDREAS DR , BENISCH CHRISTOPH DR , FUNKE FRANK DR , OHLBACH FRANK DR , MERGER MARTIN DR
IPC: C07D295/12 , B01J25/00 , B01J25/02 , B01J35/04 , B01J35/10 , B01J37/00 , C07B61/00 , C07C209/48 , C07C211/14 , C07C211/35 , C07C211/36 , C07D295/13
Abstract: Nitrite is hydrogenated to primary amine using an activated macroporous Raney catalyst comprising alpha -alumina and transition metal(s), obtained by (i) shaping kneadable composition comprising an alloy, a shaping aid, water and a pore former, (ii) calcining and activating by treating with aqueous alkali metal hydroxide solution and (iii) rinsing with aqueous alkali metal hydroxide solution and water. Hydrogenating nitrite to primary amine involves using activated macroporous Raney catalyst comprising alpha -alumina and transition metal(s), such as iron, cobalt, nickel, titanium, zirconium, chromium and manganese. The Raney catalyst is obtained by preparing a kneadable composition comprising an alloy, a shaping aid, water and a pore former, which is then shaped to form a component. The shaped component is calcined and activated by treating with aqueous alkali metal hydroxide solution. The catalyst obtained is rinsed with aqueous alkali metal hydroxide solution and water. Independent claims are also included for the following: (1) a macroporous Raney catalyst; and (2) the production of a macroporous Raney catalyst.
-
公开(公告)号:DE19704616A1
公开(公告)日:1998-08-13
申请号:DE19704616
申请日:1997-02-07
Applicant: BASF AG
Inventor: LUYKEN HERMANN , REHFINGER ALWIN DR , BASLER PETER DR , VOIT GUIDO DR , FISCHER ROLF DR , MERGER MARTIN DR , RUST HARALD
IPC: C07C209/84 , C07C211/12 , C07C211/36
Abstract: The invention relates to a method for separating 2-aminomethylcyclopentylamine from a mixture containing hexamethylene diamine and 2-aminomethylcyclopentyl-amine, characterized in that separation by distillation occurs at a pressure of 1-3,000 mbars.
-
4.
公开(公告)号:MY120584A
公开(公告)日:2005-11-30
申请号:MYPI9903707
申请日:1999-08-27
Applicant: BASF AG
Inventor: LUYKEN HERMANN , ACHHAMMER G XDCNTHER DR , OHLBACH FRANK DR , ANSMANN ANDREAS DR , BASLER PETER DR , FISCHER ROLF DR , MELDER JOHANN-PETER DR , MERGER MARTIN DR , REHFINGER ALWIN DR , VOIT GUIDO DR
IPC: C07C209/48 , C07B61/00 , C07C209/84 , C07C211/12 , C07C253/30 , C07C253/34 , C07C255/24
Abstract: A PROCESS FOR THE COPRODUCTION OF 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE STARTING FROM ADIPONITRILE BY A) HYDROGENATING ADIPONITRILE IN THE PRESENCE OF A CATALYST COMPRISING AN ELEMENT OF THE EIGHTH TRANSITION GROUP AS CATALYTICALLY ACTIVE COMPONENT, TO OBTAIN A MIXTURE COMPRISING 6-AMINOCAPRONITRILE, HEXAMETHLENEDIAMINE, ADIPONITRILE AND HIGH BOILERS, B) DISTILLATIVELY REMOVING HEXAMETHYLENEDIAMINE FROM THE MIXTURE COMPRISING 6-AMINOCAPRONITRILE, HEXAMETHYLENEDIAMINE, ADIPONITRILE AND HIGH BOILERS, AND EITHER C1) DISTILLATIVELY REMOVING 6-AMINOCAPRONITRILE, AND THEN D1) DISTILLATIVELY REMOVING ADIPONITRILE, OR C2) SIMULTANEOUSLY DISTILLATIVELY REMOVING 6-AMINOCAPRONITRILE AND ADIPONITRILE INTO SEPARATE FRACTIONS IS CHARACTERIZED BY BASE OF COLUMN TEMPERATURES BELOW 185°C IN STEPS D1) OR C2).
-
公开(公告)号:DE19646436A1
公开(公告)日:1998-05-14
申请号:DE19646436
申请日:1996-11-11
Applicant: BASF AG
Inventor: EBEL KLAUS DR , FISCHER ROLF DR , FLICK KLEMENS DR , MERGER MARTIN DR , VOIT GUIDO DR
IPC: C07C253/30 , C07C255/24 , C07C209/48 , C07C211/12 , C07C253/34
Abstract: In the production of aliphatic alpha ,w-aminonitriles (I) by partial hydrogenation of aliphatic alpha ,w-dinitriles (II), the catalyst used contains (a) iron and/or an iron-based compound, (b) 0.01-5 wt.%, with respect to (a), of a promoter based on 2, 3, 4 or 5 elements selected from aluminium (Al), silicon (Si), zirconium, titanium and vanadium (V) and (c) 0-5 wt.% with respect to (a) of an alkali(ne earth) metal salt.
-
公开(公告)号:MY118962A
公开(公告)日:2005-02-28
申请号:MYPI9903985
申请日:1999-09-14
Applicant: BASF AG
Inventor: MERGER MARTIN DR , FISCHER ROLF DR , ANSMANN ANDREAS DR
IPC: C07D223/04 , C07D223/10 , C07B61/00 , C07D201/02 , C07D207/12 , C07D211/02 , C07D295/02 , C07D295/023
Abstract: A CYCLIC LACTAM AND A CYCLIC AMINE ARE COPRODUCED BY REACTING AN ALIPHATIC ALPHA, 0MEGA-DIAMINE WITH WATER IN THE GAS PHASE IN THE PRESENCE OF A HETEROGENEOUS CATALYST
-
公开(公告)号:DE19742221A1
公开(公告)日:1999-03-25
申请号:DE19742221
申请日:1997-09-24
Applicant: BASF AG
Inventor: VOIT GUIDO DR , BOHNSACK ANDREAS DR , FISCHER ROLF DR , BASLER PETER DR , LUYKEN HERMANN , MERGER MARTIN DR , FLICK KLEMENS DR
IPC: B01J23/745 , C07B61/00 , C07C253/30 , B01J23/78 , C07C255/24 , C07C255/26
Abstract: Aliphatic alpha ,w-dinitriles with a phosphorus content of 1.0 ppm or more by weight (ppm wt.) are used for the production of alpha ,w-aminonitriles by partial hydrogenation in presence of a special iron-based catalyst containing a promoter based on aluminium, silicon, zirconium, titanium and/or vanadium. A process for the production of aliphatic alpha ,w-aminonitriles comprises the partial hydrogenation of corresponding dinitriles with a phosphorus content of 1.0 ppm wt. or more in presence of a catalyst containing (a) iron and/or an iron compound, (b) 0.01-5 wt% (based on a) of a promoter based on 2, 3, 4 or 5 elements selected from Al, Si, Zr, Ti and V, and (c) 0-0.5 wt% of an alkali or alkaline earth metal compound. An Independent claim is also included for catalysts with the above composition obtained by the reduction and optional passivation of magnetite, showing a BET surface of 3-10 m /g, a total pore volume of 0.05-0.2 ml/g and an average pore diameter of 0.03-0.1 micron, with 50-70% (by volume) of the pores in the range from 0.01 to 0.1 microns.
-
公开(公告)号:MY118963A
公开(公告)日:2005-02-28
申请号:MYPI9904024
申请日:1999-09-16
Applicant: BASF AG
Inventor: MERGER MARTIN DR , FISCHER ROLF DR , ANSMANN ANDREAS DR
IPC: C07D201/08 , C07D223/10 , C07D201/02 , C07D223/04 , C07D295/02 , C07D295/023
Abstract: A CYCLIC LACTAM AND A CYCLIC AMINE ARE COPRODUCED BY COREACTING AN ALIPHATIC ALPHA, OMEGA-DIAMINE AND AN ALIPHATIC ALPHA, OMEGA-AMINONITRILE WITH WATER IN THE GAS PHASE IN THE PRESENCE OF A HETEROGENEOUS CATALYST.
-
公开(公告)号:DE19704617A1
公开(公告)日:1998-08-13
申请号:DE19704617
申请日:1997-02-07
Applicant: BASF AG
Inventor: LUYKEN HERMANN , REHFINGER ALWIN DR , BASLER PETER DR , VOIT GUIDO DR , FISCHER ROLF DR , MERGER MARTIN DR , RUST HARALD
IPC: C07C209/86 , C07C211/12 , C07C211/36 , C07C209/84
Abstract: Separation of 2-aminomethylcyclopentyl amine (AMCPA) from a mixture also containing hexamethylene diamine (HMD) is carried out by distillation at 1-300 mbar.
-
公开(公告)号:DE19806398A1
公开(公告)日:1998-08-20
申请号:DE19806398
申请日:1998-02-17
Applicant: BASF AG
Inventor: FISCHER ROLF DR , SCHNURR WERNER DR , WULFF-DOERING JOACHIM DR , MERGER MARTIN DR
IPC: C07D307/12 , B01J23/10 , C07B41/06 , C07B61/00 , C07C45/41 , C07C47/02 , C07D309/06 , C07D309/08 , C07C47/00 , C07D315/00
Abstract: Process for producing aldehydes of formula (I) by hydrogenation of esters of formula (II), comprises gas-phase reaction of the ester with a 2-200 molar excess of hydrogen at 200-450 deg C in the presence of a heterogeneous catalyst, with recycle of unreacted hydrogen and ester. By-produced alcohol R'OH is removed from the recycle stream at least to the extent that the molar ratio of alcohol to ester in the reaction mixture is no more than 1:1. RCHO (I) RCOOR' (II) R = an aliphatic, cycloaliphatic, aromatic or araliphatic group that is optionally substituted and/or contains heteroatoms, and R' = residue of a 1-10C alcohol
-
-
-
-
-
-
-
-
-