公开(公告)号：JPH1180065A

公开(公告)日：1999-03-23

申请号：JP19270198

申请日：1998-07-08

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  LIANG SHELUE DR ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM DR ,  STERZEL HANS-JOSEF DR

IPC: B01J23/14 ,  B01J23/26 ,  B01J23/34 ,  B01J23/745 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02

Abstract: PROBLEM TO BE SOLVED: To produce a carried catalyst used for converting a carboxylic acid or its ester into an aldehyde by a selective hydrogenation reaction, having reasonable stability, capable of being regenerated, hardly or quite not forming a by-product, having at least comparable selectivity with the corresponding non-carried catalyst. SOLUTION: This method for producing an aldehyde of formula I (R is an aliphatic, alicyclic, aromatic or aromatic aliphatic group which may be substituted, if necessary, with one or more substituents and/or if necessary, may have more heterogeneous atom) comprises selectively hydrogenating an acid of the formula: R-COOH or an ester of the acid with a 1-10C alcohol with hydrogen in the presence of a metal oxide catalyst in a gaseous phase. Therein, the hydrogenation is carried out in the presence of the carried catalyst containing a metal oxide suitable for the selective hydrogenation of the carboxylic acid or the carboxylate ester as an essential catalyst on SiC (silicon carbide) as a carrier at a temperature of 150-450 deg.C under a pressure of 0.1-150 bars.

公开(公告)号：JPH10298129A

公开(公告)日：1998-11-10

申请号：JP3597798

申请日：1998-02-18

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  SCHNURR WERNER DR ,  WULFF-DOERING JOACHIM DR ,  MERGER MARTIN DR

IPC: C07D307/12 ,  B01J23/10 ,  C07B41/06 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07D309/06 ,  C07D309/08

Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially efficiently and continuously producing an aldehyde by hydrogenating an ester, while recycling the unused hydrogen and the unreacted ester, wherein the selectivity of the aldehyde is maintained at a satisfactory level. SOLUTION: This method for producing an aldehyde of the formula: R-CHO comprises hydrogenating an ester of the formula: R-COOR' (R is a non- substituted or substituted aliphatic group, alicyclic group, aromatic group or aralkyl group; R' is a group derived from a 1-10C alcohol] with excessive hydrogen in an amount of 2-200 moles per mole of the ester in the presence of a heterogeneous hydrogenation catalyst at 200-450 deg.C in a gas phase, while recycling the unreacted hydrogen and the unreacted ester. Therein, the alcohol is removed from the recycling flow in such an extent as the initial concentration of the produced alcohol: R'-OH in the reaction mixture is maximally 1 mole per mole of the carboxylic acid ester II.

公开(公告)号：JPH10147557A

公开(公告)日：1998-06-02

申请号：JP23665397

申请日：1997-09-02

Applicant: BASF AG

Inventor： PREISS THOMAS DR ,  HENKELMANN JOCHEM DR ,  WULFF-DOERING JOACHIM DR ,  STUTZ SUSANNE DR

IPC: C07D295/04 ,  B01J31/26 ,  C07C209/60 ,  C07C211/08 ,  C07C211/23 ,  C07C211/25 ,  C07C211/26 ,  C07C211/43 ,  C07C211/54

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound useful as an industrial intermediate by reacting an alkyne with a carbonyl compound and amine in the presence of a nonsupported copper catalyst which brings a heterogeneous catalytic function. SOLUTION: The method for producing this compound reacts a compound shown by the formula R -C≡C-H (R is H, an alkyl or the like; R and R are each H, an alkyl, haloalkyl or the like; and R and R are each H, an alkyl or the like) (e.g. acetylene) with a mixture of a compound shown by formula I (e.g. paraformaldehyde) and compound shown by formula II (e.g. diethylamine) by the heterogeneous catalytic function rendered by a nonsupported copper catalyst derived from malachite [CuCO3 .Cu(OH)2 ] at a reaction temperature of 20 to 200 deg.C, to produce the objective N-alkyl- substituted aminoalkyne shown by formula III (e.g. N,N-diethylaminopropyne).

公开(公告)号：JPH10330116A

公开(公告)日：1998-12-15

申请号：JP35288897

申请日：1997-12-22

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM DR ,  STICHERT WOLFRAM ,  SCHUETH FERDI

IPC: B01J21/06 ,  B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  C01G25/00 ,  C01G25/02

Abstract: PROBLEM TO BE SOLVED: To obtain zirconium dioxide having high monoclinic system ratio end large BET surface area. SOLUTION: This zirconium dioxide is composed of at least 80 wt.% of monoclinic system and has a BET surface area of at least 100 m /g. The production method consists of a process for forming precipitates by mixing a zirconium salt aqueous solution with ammonia, and the drying and calcination of the resultant precipitates. In this process, the precipitates formed in the aqueous solution is aged at 0-300 deg.C and calcined at 200-600 deg.C, before drying. This product can be used as a formed product, a catalyst or a catalyst support.

公开(公告)号：JPH10174875A

公开(公告)日：1998-06-30

申请号：JP29688697

申请日：1997-10-29

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM DR ,  MELDER JOHANN-PETER DR ,  SCHULZ GERHARD DR ,  VOIT GUIDO DR ,  GUTSCHOVEN FRANK ,  HARDER WOLFGANG DR

IPC: B01J23/89 ,  B01J37/18 ,  C07B61/00 ,  C07C209/16 ,  C07C211/00 ,  C07C211/10

Abstract: PROBLEM TO BE SOLVED: To provide an amination catalyst small in the content of nickel and/or cobalt and having high selectivity and high stability about ethylene diamine obtained by aminating monoethanol amine with ammonia. SOLUTION: The catalyst is obtained by carrying 6-50wt.% cobalt, nickel or the mixture, 0.001-25wt.% ruthenium, 0-10wt.% copper and 0-5wt.% accelerator per total weight of the catalyst on a porous metal oxide carrier. In such a case, the catalyst is produced by (a) impregnating the carrier with the metal and the accelerator or the compound, (b) drying and calcining and (c) reducing with hydrogen flow, where without impregnating the carrier with a halogen compound.

公开(公告)号：JPH10120633A

公开(公告)日：1998-05-12

申请号：JP28191897

申请日：1997-10-15

Applicant: BASF AG

Inventor： PREISS THOMAS DR ,  HENKELMANN JOCHEM DR ,  WULFF-DOERING JOACHIM DR ,  STUTZ SUSANNE DR ,  RUEHL THOMAS DR

IPC: B01J23/72 ,  C07B61/00 ,  C07C213/00 ,  C07C213/02 ,  C07C215/08 ,  C07C217/08

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound under low pressure by using a catalyst containing metal compounds of a first and a second subgroup elements and gaseous C2 H2 , etc., when carrying out the reaction of an alkyd with a 1-oxa-3- azaheterocycloalkane. SOLUTION: An N-hydroxyalkyl substituted aminoalkyne expressed by formula II is manufactured by reacting a mixture of a compound expressed by the formula R -C≡C-H(R is H, an alkyl, etc.) and a compound expressed by formula I (R , R are each H, an alkyl, etc.; A is a 2-5 alkylene) in the presence of a catalyst containing a metal compound of a first subgroup elements under a heterogeneous catalytic system. A suitable catalyst contains a complex of copper acetylide and Bi compound, for example, (BiO)2 CO3 , etc., the preferable catalyst contains about 40-70wt.% of Cu and about 0.1-10% of Bi. The reaction is carried out in a reactor such as a tubular reactor, etc., provided with a stirrer, generally at 0-200 deg.C, preferably at 20-120 deg.C, especially preferably at 40-120 deg.C.

公开(公告)号：DE19742911A1

公开(公告)日：1999-04-01

申请号：DE19742911

申请日：1997-09-29

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM DR ,  HESSE MICHAEL DR ,  MELDER JOHANN-PETER DR ,  VOIT GUIDO DR ,  BUSKENS PHILIPP DR ,  FUNKE FRANK DR

IPC: C07D295/02 ,  B01J23/755 ,  B01J23/889 ,  C07B61/00 ,  C07C209/16 ,  C07D295/023 ,  C07D265/28 ,  C07C211/03 ,  C07C211/35 ,  B01J23/70

Abstract: Preparation of amines from alcohols, nitrogen compounds and hydrogen is effected over a catalyst containing oxygenated compounds of zirconium, copper, nickel and optionally aluminium and/or manganese. Preparation of amines involves reacting primary or secondary alcohols, nitrogen compounds selected from ammonia and primary or secondary amines, with hydrogen at 80-250 degrees C and 0.1-40 MPa over a catalyst at least containing zirconium, copper and nickel. Specifically, the catalytically active mass contains metal oxides of Zr (20-85 wt. %, as ZrO2), Cu (1-30 wt.%, as CuO), Ni (14-70 wt.%, as NiO) and optionally aluminium and/or magnesium (0-10 wt.%, as Al2O3 and/or MnO2). The molar ratio of Ni / Cu is ≥ 1, and the catalyst is free of cobalt or molybdenum oxides. An Independent claim is also included for a catalyst formed.

公开(公告)号：DE19645047A1

公开(公告)日：1998-05-07

申请号：DE19645047

申请日：1996-10-31

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM DR ,  MELDER JOHANN-PETER DR ,  SCHULZ GERHARD DR ,  VOIT GUIDO DR ,  GUTSCHOVEN FRANK ,  HARDER WOLFGANG DR

IPC: B01J23/89 ,  B01J37/18 ,  C07B61/00 ,  C07C209/16 ,  C07C211/00 ,  C07C211/10 ,  C07C215/08 ,  C07C213/08 ,  C07C213/04

Abstract: Catalysts (I) are claimed containing, on a porous metal oxide support, more than 6-50 wt% cobalt, nickel or a mixture thereof, 0.001-25 wt% ruthenium, 0-10 wt% copper and 0-5 wt% promoter(s) selected from iron, rhodium, palladium, platinum, iridium, osmium, silver, gold, chromium, molybdenum, tungsten, rhenium zinc, cadmium, lead, manganese, tin, lithium, sodium, potassium, rubidium, caesium, phosphorus, arsenic, antimony, bismuth, tellurium and thallium. (I) are obtained by (a) impregnating the support with the metals and promoters or their compounds but using only halogen-free compounds, (b) drying and calcining, and (c) reducing the calcined catalyst in a stream of hydrogen. Also claimed is (i) the process as described above for the production of (I), and (ii) a process for the production of amination products by reacting alkylene oxides, alcohols, aldehydes or ketones with ammonia or prim. or sec. amines in presence of free hydrogen and catalyst (I).

公开(公告)号：DE4428994A1

公开(公告)日：1996-02-22

申请号：DE4428994

申请日：1994-08-16

Applicant: BASF AG

Inventor： SCHNURR WERNER DR ,  FISCHER ROLF DR ,  WULFF-DOERING JOACHIM DR ,  IRGANG MATTHIAS DR

IPC: B01J23/10 ,  C07C45/41 ,  C07C67/313 ,  C07C47/54 ,  C07C47/542 ,  C07C47/544 ,  C07C47/575 ,  C07C67/30 ,  C07C69/76

Abstract: Prodn. of an aromatic aldehyde of formula (I) comprises treating the corresp. carboxylic acid of formula (II) with hydrogen in the gas phase at 200-450 deg C, 0.1-20 bar in the presence of a catalyst (III). (III) has a catalytic mass comprising 80-99.9 wt.% zirconium oxide and 0.1-20 wt.% one or more lanthanide elements. R1, R2 = H, 1-6C alkyl, 3-8C cycloalkyl, aryl, OH, 1-4C alkoxy, phenoxy, 7-12C alkylphenyl, 7-12C phenylalkyl, NH2, NHMe, NMe2 or halo; R3 = as R, or COOR4; R' = as R3 or formyl; R4 = H, 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkyl phenyl or 7-12C phenyl alkyl.

公开(公告)号：AT272605T

公开(公告)日：2004-08-15

申请号：AT00124609

申请日：2000-11-10

Applicant: BASF AG

Inventor： NOUWEN JAN DR ,  HOEHN ARTHUR DR ,  NEUHAUSER HORST DR ,  FUNKE FRANK DR ,  SCHUNK STEPHAN ANDREAS ,  MELDER JOHANN-PETER DR ,  EGER KNUT DR ,  HESSE MICHAEL DR ,  WULFF-DOERING JOACHIM DR

IPC: B01J23/755 ,  C07B61/00 ,  C07C209/26 ,  C07C211/27 ,  C07C211/35 ,  C07C211/38 ,  C07C211/42 ,  C07C213/02 ,  C07C217/58

Abstract: Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst, wherein the catalytically active mass of the catalyst contains, after its preparation and before the treatment with hydrogen,22 to 45% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2,1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO,5 to 50% by weight of oxygen-containing compounds of nickel, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,5 to 50% by weight of oxygen-containing compounds of cobalt, calculated as CoO,0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2.