公开(公告)号：DE59711590D1

公开(公告)日：2004-06-09

申请号：DE59711590

申请日：1997-07-15

Applicant: BASF AG

Inventor： BATSCHEIDER KARL-HEINZ ,  HAHN DR ,  BRAUN DR ,  ROESCH DR

IPC: C08J9/16 ,  C08F2/44 ,  C08F255/02 ,  C08J9/20 ,  C08L25/04

Abstract: Expandable polystyrene (EPS) containing blowing agent also contains 0.1-20 wt.% of a blowing aid comprising an oligomeric aliphatic 2-20C olefin (I) and a number average degree of polymerisation (DP) of 2-200, which is liquid at room temperature. Also claimed are methods of producing expandable polystyrene beads.

公开(公告)号：DE59704106D1

公开(公告)日：2001-08-30

申请号：DE59704106

申请日：1997-05-16

Applicant: BASF AG

Inventor： ROESCH DR ,  WUENSCH DR

IPC: C08F2/14 ,  C08F2/08 ,  C08F2/20 ,  C08F4/623 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F8/00 ,  C08F8/08 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F32/00 ,  C08F110/06

Abstract: A process for the production of crystalline polymers of ethylene, propylene and/or cyclic olefin, comprises polymerisation in dispersion in presence of metallocene catalyst systems.

公开(公告)号：DE59704107D1

公开(公告)日：2001-08-30

申请号：DE59704107

申请日：1997-05-16

Applicant: BASF AG

Inventor： ROESCH DR ,  BIDELL DR ,  LANGHAUSER DR

IPC: C08F2/38 ,  C08F2/40 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/625 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F110/06

Abstract: A process for the production of polymers of 2-12C alkenes at -50 to 300 degrees C and 0.5-3000 bar in presence of a catalyst system, with the addition of a compound of formula H-M )R (I); where M = B, Al, Ga, In or Tl; R , R = H, 1-10C alkyl, 6-15C aryl, or alkaryl or aralkyl with a 1-10C alkyl and a 6-20C aryl group, or 5- to 7-membered cycloalkyl (optionally substituted with 1-10C alkyl); or R + R may form a 4-15C cyclic group. Preferably R and R together form part of a 4-15C bicyclic group; M = boron. The catalyst system contains (A) a metallocene complex and (B) a metallocenium ion-forming compound. A metal compound of formula M )r(R )s(R )t (IV) may also be added; M = alkali or alkaline earth metal, or a Sub-Group III metal, i.e. B, Al, Ga, In or Tl; R = 1-10C alkyl, 6-15C aryl, or alkaryl or aralkyl with 1-10C alkyl and 6-20C aryl groups; R , R = as for R , or also halogen or 1-10C alkoxy; r = 1-3; s, t = 0-2; r + s + t = the valency of M .

公开(公告)号：DE59604480D1

公开(公告)日：2000-03-30

申请号：DE59604480

申请日：1996-07-23

Applicant: BASF AG

Inventor： ROESCH DR ,  MUELLER DR ,  HOEHN DR ,  MUELHAUPT PROF DR ,  WOERNER CHRISTOF

IPC: C08F8/14 ,  C08F8/30 ,  C08F8/32 ,  C08F8/50 ,  C08F10/00 ,  C08F110/00 ,  C08F110/06 ,  C08G73/00 ,  C08G81/00 ,  C08G81/02

Abstract: Polymers and oligomers of formula (I), based on unsatd. 2-10C hydrocarbons and with one or two 2-oxazolinyl terminal gps., in which A = polymer or oligomer residue derived from the unsatd. hydrocarbon (A'), and R = H, 1-10C alkyl, 6-10C aryl or 3-6C cycloalkyl. Also claimed are (i) comb polymers (II) obtd. by cationic ring-opening homo- or co-polymerisation of (I); (ii) comb polymers (III) obtd. by reacting (I) with base polymers contg. reactive gps.; (iii) thermoplastic moulding materials or thermosets contg. (I), (II) or (III) or mixts. thereof; (iv) a process for the prodn. of (I) by polymerisation or oligomerisation of (A'), modification with one or two terminal ester gps., and Lewis acid-catalysed ring closure with 2-amino-1- alcohols; (v) processes for the prodn. of (II) and (III) under the above conditions; (vi) films, fibres and mouldings obtd. from the materials claimed in (iii).