3.
    发明专利
    未知

    公开(公告)号:DE59608701D1

    公开(公告)日:2002-03-21

    申请号:DE59608701

    申请日:1996-11-22

    Applicant: BASF AG

    Inventor: HOEHN DR WOLF DR

    Abstract: Bis(dimenthylphosphino)methane (IA), (dimenthylphosphino)(diphenylphosphino)methane (IB) and (dimenthylphosphino)(di-tert.-butylphosphino)methane (IC) are claimed. Also claimed is a method of preparing methylene-bridged compounds of formula (R X)(R X)E CH2E )(XR ) (I) with di:organyl-phosphino, -arsino and/or -stibino groups.

    6.
    发明专利
    未知

    公开(公告)号:DE59904437D1

    公开(公告)日:2003-04-10

    申请号:DE59904437

    申请日:1999-12-16

    Applicant: BASF AG

    Abstract: 2,2'-Dimorpholinodiethyl ether is produced by reacting diethylene glycol with ammonia under pressure at elevated temperature in the presence of hydrogen. The active hydrogenation catalyst, before reduction with hydrogen, contains 20-85 wt.% alumina, zirconium dioxide, titanium dioxide and/or silica, 1-70 wt.% copper oxide (CuO), less than 20 wt.% nickel oxide with respect to CuO and 0-50 wt.% other metal oxide(s). In the production of 2,2'-dimorpholinodiethyl ether (DMDEE) by reacting diethylene glycol with ammonia under pressure at elevated temperature in the presence of hydrogen and a hydrogenation catalyst, the active catalyst, before reduction with hydrogen, contains 20-85 wt.% aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silica (SiO2), 1-70 wt.% copper oxide (expressed as CuO), 0-50 wt.% magnesium, chromium, zinc, barium and/or calcium oxide (expressed as MgO, Cr2O3, ZnO, BaO and CaO) and less than 20 wt.% nickel oxide (expressed as NiO) with respect to CuO.

    7.
    发明专利
    未知

    公开(公告)号:DE59606111D1

    公开(公告)日:2000-12-14

    申请号:DE59606111

    申请日:1996-08-16

    Applicant: BASF AG

    Abstract: The novel feature in carboxylic acid prodn. from olefins and CO in presence of water at 30-200 degrees C/30-200 bar is that the halogen-free catalyst system comprises a mixt. of (A) Rh (or Rh cpd.) and (B) an N-contg. heterocyclic cpd.

    8.
    发明专利
    未知

    公开(公告)号:DE59604480D1

    公开(公告)日:2000-03-30

    申请号:DE59604480

    申请日:1996-07-23

    Applicant: BASF AG

    Abstract: Polymers and oligomers of formula (I), based on unsatd. 2-10C hydrocarbons and with one or two 2-oxazolinyl terminal gps., in which A = polymer or oligomer residue derived from the unsatd. hydrocarbon (A'), and R = H, 1-10C alkyl, 6-10C aryl or 3-6C cycloalkyl. Also claimed are (i) comb polymers (II) obtd. by cationic ring-opening homo- or co-polymerisation of (I); (ii) comb polymers (III) obtd. by reacting (I) with base polymers contg. reactive gps.; (iii) thermoplastic moulding materials or thermosets contg. (I), (II) or (III) or mixts. thereof; (iv) a process for the prodn. of (I) by polymerisation or oligomerisation of (A'), modification with one or two terminal ester gps., and Lewis acid-catalysed ring closure with 2-amino-1- alcohols; (v) processes for the prodn. of (II) and (III) under the above conditions; (vi) films, fibres and mouldings obtd. from the materials claimed in (iii).

    9.
    发明专利
    未知

    公开(公告)号:DE50203537D1

    公开(公告)日:2005-08-11

    申请号:DE50203537

    申请日:2002-01-04

    Applicant: BASF AG

    Abstract: Mixtures of primary amines of the formula (I)and secondary amines of the formula (II)whereX is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonylare prepared by reacting nitriles of the formula (III)with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.

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