公开(公告)号：EP0776929A3

公开(公告)日：1998-06-10

申请号：EP96118613

申请日：1996-11-20

Applicant: BASF AG

Inventor： WALTER MANFRED DR ,  KNOLL KONRAD DR ,  SCHNEIDER MICHAEL DR ,  WASSMER KARL-HEINZ DR

IPC: C08J9/16 ,  C08F212/08 ,  C08F212/32 ,  C08J9/18 ,  C08J9/228 ,  C09K21/14 ,  C08J9/14 ,  C08L25/08

CPC classification number: C08J9/228 ,  C08J9/18 ,  C08J2325/08

Abstract: Schaumstoffe auf Basis von Copolymeren des Styrols mit 2 bis 50 Mol-% 1,1-Diphenylethen weisen eine hohe Wärmeformbeständigkeit auf.

公开(公告)号：DE19701868A1

公开(公告)日：1998-07-23

申请号：DE19701868

申请日：1997-01-21

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  LOTH WOLFGANG DR ,  GAUSEPOHL HERMANN DR

IPC: C08F297/02 ,  C08L25/06 ,  C08L25/08 ,  C08L53/00 ,  C08L53/02

Abstract: The invention concerns a mixture of a copolymer (A) comprising between 50 and 99 mol % polymerized-in styrene units and between 1 and 50 mol % polymerized-in units of 1,1-diphenylethylene and/or a block copolymer comprising at least one polystyrene block and at least one poly(styrene/diphenylethylene) block of the above composition. The invention further concerns a process for preparing this mixture by the anionic block (co)polymerization of styrene or styrene and diphenylethylene, and an impact-resistant modified polystyrene (B).

公开(公告)号：DE19737959A1

公开(公告)日：1999-03-04

申请号：DE19737959

申请日：1997-08-30

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  GOTTSCHALK AXEL DR ,  GAUSEPOHL HERMANN DR

IPC: C08L25/08 ,  C08L51/00 ,  C08L51/04 ,  C08L53/02 ,  C08L71/12 ,  C08L77/00 ,  C08L77/02 ,  C08J5/00 ,  C08J5/18 ,  C08L23/08 ,  C08L25/04 ,  D01F8/12

Abstract: The invention relates to thermoplastic moulding materials containing: A) 15 to 84 wt. % of a thermoplastic polyamide; B) 15 to 84 wt. % of a copolymer composed of vinylaromatic monomers and of 1,1-diphenylethylene or derivatives thereof which are eventually substituted at the aromatic rings with alkyl groups containing up to 22 carbon atoms; C) 1 to 30 wt. % of a polymer modified by polar groups or of polymer mixtures; D) 0 to 69 wt. % of other additives and ancillary treatment agents. The total percentage of the constituents A) to D) is equal to 100 %.

公开(公告)号：DE19705828A1

公开(公告)日：1998-08-20

申请号：DE19705828

申请日：1997-02-15

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  FISCHER MICHAEL DR ,  GAUSEPOHL HERMANN DR

IPC: C08F285/00 ,  C08L51/04 ,  C08L53/00 ,  C08L71/12 ,  C08F210/14 ,  C08F297/02 ,  C08L23/24

Abstract: The invention relates to a mixture containing 50-90 wt. % of a styrene-diphenyl ethylene copolymer obtained by anionic block (co) polymerization of styrene and 1,1-diphenyl-ethylene or a block copolymer (A) and 10-50 wt. % of a particle-shaped graft copolymer (B) with a transition temperature (Tg) of less than -10 DEG C and at least 3, preferably 4 layers or shells whereby at least one shell or the graft nucleus (B1) has a transition temperature (Tg) of more than 25 DEG C and at least one shell or graft nucleus has a transition temperature (Tg) of less than 25 DEG C, preferably below O DEG C wherein any spatial sequence of the graft shells is possible.

公开(公告)号：DE19728542A1

公开(公告)日：1999-01-07

申请号：DE19728542

申请日：1997-07-04

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  GOTTSCHALK AXEL DR ,  KNOLL KONRAD DR ,  MEHLER CHRISTOF DR ,  WARZELHAN VOLKER DR

IPC: C08L53/00 ,  C08L25/08 ,  C08J5/00 ,  C08L9/06 ,  C08L53/02

Abstract: Impact resistant thermoplastic moulding compound (I) containing (A) \- 50 wt% copolymer of 15-63 wt% 1,1-diphenylethylene (DPE) and 37-85 wt% styrene; (B) 5-35 wt% of a tri-block copolymer of (b 1) a block consisting mainly of the comonomer units in copolymer (A), (b 2) an elastomeric block and (b 3) a polystyrene block; (C) \- 5 wt% polystyrene and/or a polymer which is miscible with polystyrene; and (D) 0-40 wt% rubber.

公开(公告)号：DE19713878A1

公开(公告)日：1998-10-08

申请号：DE19713878

申请日：1997-04-04

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  GOTTSCHALK AXEL DR ,  KNOLL KONRAD DR ,  MEHLER CHRISTOF DR ,  WARZELHAN VOLKER DR

IPC: C08L21/00 ,  C08L25/06 ,  C08L53/02 ,  C08L25/04 ,  C08L9/00 ,  C08L23/04 ,  C08L25/08

Abstract: A toughened thermoplastic moulding composition (I) contains: (A) 50-80 wt.% of a copolymer comprising (with respect to (A)) polymerised units of (A1) 15-63 wt.% 1,1-diphenylethylene and (A2) 37-85 wt.% styrene; (B) 5-35 wt.% of a tri-block copolymer comprising blocks (B1), block composed of comonomers of (A), (B2) an elastomeric block and, (B3) polystyrene; (C) at least 5 wt.% polystyrene and/or a polymer miscible with polystyrene and; (D) 0.1-40 wt.% of a rubber.

公开(公告)号：DE19700306A1

公开(公告)日：1998-07-16

申请号：DE19700306

申请日：1997-01-09

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  WUENSCH JOSEF DR ,  GAUSEPOHL HERMANN DR

IPC: C08J5/18 ,  C08L25/04 ,  C08L25/06 ,  D01F6/22 ,  C08L25/16 ,  C08L25/18 ,  C08J5/00

Abstract: The invention concerns thermoplastic moulding compounds containing (A) between 5 and 95 wt % of a vinylaromatic polymer having a syndiotactic structure, and (B) between 5 and 95 wt % of a copolymer of a vinylaromatic monomer and 1,1-diphenyl ethylene or its derivatives substituted at the aromatic rings optionally with alkyl groups having up to 22 carbon atoms.

公开(公告)号：DE19700305A1

公开(公告)日：1998-07-16

申请号：DE19700305

申请日：1997-01-09

Applicant: BASF AG

Inventor： WUENSCH JOSEF DR ,  SCHNEIDER MICHAEL DR

IPC: C08F2/12 ,  C08F2/08 ,  C08F4/602 ,  C08F4/64 ,  C08F12/00 ,  C08F12/04

Abstract: The invention concerns a process for preparing polymers from vinylaromatic compounds in dispersion, characterized in that polymerization is carried out in the presence of a dispersing aid and a catalyst obtained from: (A) a transition metal complex of the second or eighth subgroup; (B) a cation-forming agent; and (C) optionally an aluminium compound.

公开(公告)号：DE19728541A1

公开(公告)日：1999-01-07

申请号：DE19728541

申请日：1997-07-04

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  GOTTSCHALK AXEL DR ,  KNOLL KONRAD DR ,  MEHLER CHRISTOF DR ,  WARZELHAN VOLKER DR

IPC: C08L53/00 ,  C08L25/08 ,  C08J5/00 ,  C08L9/06 ,  C08L53/02

Abstract: Impact resistant thermoplastic moulding compound (I) containing (A) \- 50 wt% copolymer of 15-63 wt% 1,1-diphenylethylene (DPE) and 37-85 wt% styrene; (B) 5-35 wt% of a tri-block copolymer of (b 1) a block consisting mainly of the comonomer units in copolymer (A), (b 2) an elastomeric block and (b 3) a polystyrene block; (C) \- 5 wt% polystyrene and/or a polymer which is miscible with polystyrene; and (D) 0-40 wt% rubber.

公开(公告)号：DE19715821A1

公开(公告)日：1998-10-22

申请号：DE19715821

申请日：1997-04-16

Applicant: BASF AG

Inventor： SCHNEIDER MICHAEL DR ,  MAC KEE GRAHAM EDMUND DR

IPC: C08F297/02 ,  C08L25/08 ,  C08L51/04 ,  C08L53/00 ,  C08L25/10 ,  C08J5/00

Abstract: The invention relates to a molding material comprising 45 to 95 wt. % styrene and 1.1-diphenylethylene copolymer(S/DPE copolymer) with 37 to 85 wt. % polymerized styrene units and 15 to 63 wt. % polymerized 1.1-diphenylethylene units or a styrene-S/DPE double block copolymer whose S/DPE block has the above-mentioned composition. The inventive molding material also contains 5 to 55 wt. % of a rubber-elastic microsuspension graft polymer consisting of particles with a diameter d50 of 30 mu m or less with a rubber-elastic graft core consisting of units of one or several C2-36-alkyl-acrylic esters with a glass transmission temperature Tg lower than -10 DEG C and a graft shell made of at least 50 wt. % polymerized styrene units.