公开(公告)号：DE19807561A1

公开(公告)日：1998-08-27

申请号：DE19807561

申请日：1998-02-23

Applicant: BASF AG

Inventor： CLAASEN PETER ,  SCHUMACHER GERHARD DR ,  HUMMERICH RAINER DR

IPC: C08C1/04 ,  C08F6/00 ,  C08F236/12 ,  C14C9/00 ,  C08F236/04 ,  C08F220/42 ,  C08F220/54 ,  C08F222/38 ,  D06M15/227 ,  D06M15/248 ,  D06M15/285 ,  D06M15/31

Abstract: Use is claimed of alpha , beta -ethylenically unsaturated carboxylic acids in reducing the residual monomer content in aqueous radical emulsion polymerisation of mixtures comprising (A) 4-8C diene(s); (B) nitrile(s) of alpha , beta -ethylenically unsaturated carboxylic acids; (C) amide(s) and/or N-methylolamide(s) of alpha , beta -ethylenically unsaturated 3-6C mono- or 4-6C di-carboxylic acids; and optionally also (D) comonomers comprising vinyl aromatics, esters of alpha , beta -ethylenically 3-6C mono- or 4-6C di-carboxylic acids with 1-12C alkanols and/or esters of vinyl alcohol with 1-20C monocarboxylic acids. The unsaturated acid is added in an amount of 0.05-2.5 (especially 0.2-1)wt.% based on monomers (A) - (D) before or during the polymerisation or before an optional post-polymerisation. Aqueous polymer dispersions thus obtained are claimed, as is also their use in impregnating textiles, leather or (especially) fleeces.

公开(公告)号：DE19805122A1

公开(公告)日：1999-04-22

申请号：DE19805122

申请日：1998-02-09

Applicant: BASF AG

Inventor： MORRISON BRADLEY RONALD DR ,  KIRCHNER WERNER DR ,  SCHUMACHER GERHARD DR

IPC: C08F2/22 ,  C08F6/00 ,  C09D5/02 ,  C09D17/00 ,  C09D125/00 ,  C09D127/04 ,  C09D131/02 ,  C09D133/04 ,  C09D133/18 ,  C09D135/00 ,  D06M15/233 ,  D06M15/248 ,  D06M15/263 ,  D06M15/327

Abstract: An aqueous polymer dispersion (I) having a low residual monomer content is prepared by radical aqueous emulsion polymerisation of an ethylenically unsaturated monomer whereby (a) the monomer(s) and an initiator system (II) are mixed and (b) optionally allowed to react for up to one hour and (c) addition of a different initiator system (III) with full conversion of the monomer(s).

公开(公告)号：DE19524586A1

公开(公告)日：1996-01-18

申请号：DE19524586

申请日：1995-07-06

Applicant: BASF AG

Inventor： SCHUMACHER GERHARD DR ,  MORRISON BRADLEY RONALD DR ,  SCHLARB BERNHARD DR ,  KNOLL KONRAD DR

IPC: C08L9/08 ,  C08L25/14 ,  C08J3/07 ,  C08F257/00 ,  C08F265/00 ,  C08F279/00 ,  C08L9/00 ,  C08L25/00 ,  C08L27/00 ,  C08L31/02 ,  C08L33/06 ,  C08L33/18 ,  C08L51/06 ,  C09D5/02

Abstract: Aq. dispersions (I) contain (A) a radically polymerised polymer contg. 5-50 wt.% ethylenically unsatd. acid monomer units (A1) and (B) an anionically polymerised polymer. Also claimed is a process for the prodn. of (I), by producing polymer (A) or (B) in organic solvent in the presence of (B) or (A), or producing (A) and (B) in soln. separately and mixing the solns. or dispersions obtd., then dispersing the mixt. in water and removing organic solvent as required. Also claimed are substrates coated with (I).

公开(公告)号：ES2153511T3

公开(公告)日：2001-03-01

申请号：ES96105407

申请日：1994-05-02

Applicant: BASF AG

Inventor： SCHUMACHER GERHARD DR ,  DITTRICH UWE DR ,  ZETTL ALEXANDER

IPC: C08F265/06 ,  B41M5/52 ,  C08F265/00 ,  C08F265/04 ,  C09J151/00 ,  D04H1/587 ,  D04H1/64 ,  D06M15/227 ,  D06M15/233 ,  D06M15/263 ,  D06N3/04 ,  D06N3/10 ,  D21H19/20 ,  D21H19/58

公开(公告)号：DE59409636D1

公开(公告)日：2001-02-15

申请号：DE59409636

申请日：1994-05-02

Applicant: BASF AG

Inventor： SCHUMACHER GERHARD DR ,  DITTRICH DR ,  ZETTL ALEXANDER

IPC: C08F265/06 ,  B41M5/52 ,  C08F265/00 ,  C08F265/04 ,  C09J151/00 ,  D04H1/587 ,  D04H1/64 ,  D06M15/227 ,  D06M15/233 ,  D06M15/263 ,  D06N3/04 ,  D06N3/10 ,  D21H19/20 ,  D21H19/58

公开(公告)号：DE19741184A1

公开(公告)日：1999-03-25

申请号：DE19741184

申请日：1997-09-18

Applicant: BASF AG

Inventor： RUPANER ROBERT DR ,  LAWRENZ SVEN ,  DOBBELAAR JOHANNES DR ,  BAUER GERHARD DR ,  MUESELER FRANZ-JOSEF DR ,  KIRCHNER WERNER DR ,  MORRISON BRADLEY RONALD DR ,  NAHSTOLL JUERGEN DR ,  MEISTER MARTIN DR ,  BAECHER REINHARD DR ,  HUEBINGER WOLFGANG DR ,  SCHUMACHER GERHARD DR

IPC: C08F6/00

Abstract: Post-polymerisation reduction of the residual monomer content of a liquid solution, mixture, melt, suspension or dispersion obtained by free radical polymerisation is effected by adding a redox initiator system at a suitable temperature, the liquid in the reactor being mixed for the least possible time and at least one of the components of the initiator being added gradually to the liquid for a dose time which is 10-250 times the mixing time of the liquid.

公开(公告)号：DE59500830D1

公开(公告)日：1997-11-27

申请号：DE59500830

申请日：1995-04-25

Applicant: BASF AG

Inventor： KNOLL KONRAD DR ,  SCHUMACHER GERHARD DR ,  DITTRICH UWE DR

IPC: C09J109/06 ,  C08F297/02 ,  C08F297/04 ,  C09J121/02 ,  C09J153/00 ,  C09J153/02

Abstract: Adhesives (I) are claimed, contg. a copolymer (II) with an average Mn of 2000-250,000 and opt. less than 40 wt.% homopolymer blocks with a mol. wt. greater than 1/20 of Mn, obtd. by anionic polymerisation of (a) 10-90 wt.% vinylaromatic cpd., (b) 10-90 wt.% conjugated diene and (c) 0-30 wt.% other comonomers. Also claimed are substrates coated with (I).

公开(公告)号：DE4415448A1

公开(公告)日：1995-11-09

申请号：DE4415448

申请日：1994-05-03

Applicant: BASF AG

Inventor： KNOLL KONRAD DR ,  SCHUMACHER GERHARD DR ,  DITTRICH UWE DR

IPC: C09J109/06 ,  C08F297/02 ,  C08F297/04 ,  C09J121/02 ,  C09J153/00 ,  C09J153/02 ,  C09J125/10 ,  C09J125/16 ,  C09J125/18 ,  C09J125/08 ,  C09J125/02

Abstract: Adhesives (I) are claimed, contg. a copolymer (II) with an average Mn of 2000-250,000 and opt. less than 40 wt.% homopolymer blocks with a mol. wt. greater than 1/20 of Mn, obtd. by anionic polymerisation of (a) 10-90 wt.% vinylaromatic cpd., (b) 10-90 wt.% conjugated diene and (c) 0-30 wt.% other comonomers. Also claimed are substrates coated with (I).

公开(公告)号：DE4315881A1

公开(公告)日：1994-11-17

申请号：DE4315881

申请日：1993-05-12

Applicant: BASF AG

Inventor： SCHUMACHER GERHARD DR ,  DITTRICH UWE DR ,  ZETTL ALEXANDER

IPC: C08F265/06 ,  B41M5/52 ,  C08F265/00 ,  C08F265/04 ,  C09J151/00 ,  D04H1/587 ,  D04H1/64 ,  D06M15/227 ,  D06M15/233 ,  D06M15/263 ,  D06N3/04 ,  D06N3/10 ,  D21H19/20 ,  D21H19/58 ,  C09D151/06 ,  C09J151/06