Abstract:
A process for the prodn. of reusable fibre composite materials (FCM) contg. fibres (I) bonded together with a polymeric binder is claimed. The binder consists of an aq. dispersion of a polymer (II) which is film-forming at usage temps. and which goes entirely into soln. when the pH of the dispersion medium is changed. Also claimed is (i) material (FCM) obtd. by this process, esp. in the form of non-woven fabric or paper, and (ii) a process for recycling FCM, in which the FCM is treated with an aq. medium at a pH such that polymer (II) is dissolved to give fibres and binder soln., which are then sepd. and reused.
Abstract:
Bei einem Verfahren zur Herstellung wiederverwertbarer Faserverbundwerkstoffe, bei dem Fasern mittels eines polymeren Bindemittels miteinander verbunden werden, wird als Bindemittel eine wäßrige Polymerisatdispersion eingesetzt, die einen bei Anwendungstemperatur filmbildenden Polymerisatanteil in disperser Verteilung mit der Maßgabe enthält, daß die Gesamtmenge des in der wäßrigen Polymerisatdispersion in disperser Verteilung enthaltenen, bei Anwendungstemperatur filmbildenden Polymerisatanteils bei pH-Änderung des wäßrigen Dispergiermediums in eine wäßrige Polymerisatlösung übergeht. Dabei kann der bei Anwendungstemperatur filmbildende Polymerisatanteil der wäßrigen Polymerisatdispersion protische Säuregruppen aufweisen, und seine disperse Verteilung im wäßrigen Medium kann durch Erhöhung des pH-Werts des wäßrigen Mediums in eine wäßrige Polymerisatlösung übergehen, oder er kann basische Gruppen aufweisen, insbesondere Aminogruppen, und seine disperse Verteilung kann im wäßrigen Medium durch Absenkung des pH-Werts des wäßrigen Mediums in eine wäßrige Polymerisatlösung übergehen.
Abstract:
Aqueous dispersions of copolymers of (a) from 70 to 85% by weight of nontertiary butyl (meth)acrylates, (b) from 8 to 27.2% by weight of (meth)acrylates (A) whose homopolymers have a glass transition temperature greater than that of the polybutyl (meth)acrylate up to 0 DEG C. and (meth)acrylates (B) whose homopolymers have a glass transition temperature below that of the polybutyl (meth)acrylate, the weight ratio of the (meth)acrylates (A) to the (meth)acrylates (B) being from 3:1 to 1:3, (c) from 2 to 15% by weight of methyl methacrylate, styrene and/or acrylonitrile and (d) 0.8 to 5% by weight of monoolefinically unsaturated mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their amides which are unsubstituted or substituted at the nitrogen atoms by alkyl and/or alkylol radicals of 1 to 4 carbon atoms and/or hydroxyalkyl (meth)acrylates where the alkyl groups are of 2 to 5 carbon atoms, are used for coating sheet-like substrates.
Abstract:
Resin mixt. contains (a) 55-95 wt.% urea-HCHO (UF) resin, (b) 1-20 wt.% melamine, (c) 1-20 wt.% dicyandiamide, (d) 1-30 wt.% aliphatic 2-4 C alkanol with at least 2 alcoholic OH gps. (polyol A) or an ether contg. at least 2 alcoholic OH gps. with 2-10 units derived from polyol A. Also claimed are aq. solns. contg. 40-80 wt.% of the resin mixt.; and bonded fibrous laminates.
Abstract:
HCHO-free binders, impregnants or coating materials comprise (A) a polymer contg. 2-100 wt.% of an ethylenically-unsatd. acid or anhydride as a constituent monomer; and (B) a polyol which is a triazine of formula (I), a triazine-trione of formula (II), a benzene deriv. of formula (III) and/or a cyclohexyl deriv. of formula (IV). R -R = X((CmH2mO)nH) or N((CmH2mO)nH)2; R -R = ((CmH2mO)nH); R -R = (X(CmH2mO)nH; N((CmH2mO)nH)2; (Y(CmH2mO)nH); or ((CmH2mO)nH); X = NH, O or S; Y = divalent 1-6C alkyl or acyl gp.; m = 2-5; and n = 1-10.
Abstract:
A novel resin mixt comprises (by wt): (a) 55-98.8% urea-HCHO(UF) resin; (b) 0.1-20% melamine; (c) 0.1-20% dicyandiamide; and (d) 1-30% aliphatic 2-4C alkanol with at least 2 alcoholic OH gps (polyol A) or an ether contg at least 2 alcoholic OH gps and built up from 2-10 units derived form polyol A.
Abstract:
A novel resin mixt comprises (by wt): (a) 55-98.8% urea-HCHO(UF) resin; (b) 0.1-20% melamine; (c) 0.1-20% dicyandiamide; and (d) 1-30% aliphatic 2-4C alkanol with at least 2 alcoholic OH gps (polyol A) or an ether contg at least 2 alcoholic OH gps and built up from 2-10 units derived form polyol A.
Abstract:
Prodn. of packaging material comprises coating a substrate with an aq. soln. or dispersion contg.: (A) a copolymerisate prepd. from: (a) 10-100 wt.% ethylenic 3-5C mono- or di-carboxylic acid, anhydride or hemi-ester; (b) 0-50 wt.% ethylenic cpd. contg. 1 or more sulphonic acid or sulphonate gps.; (c) 0-70 wt.% other monomers; and (B) a polyester; and opt. applying additional coating layers.